(3aR,5R,6R,6aR)-6-(benzyloxy)-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyl-6-vinyltetrahydrofuro[2,3-d][1,3]dioxole | 96212-44-1

分子结构分类

有机化合物 - 苯类化合物 - 苯和取代衍生物

中文名称

——

中文别名

——

英文名称

(3aR,5R,6R,6aR)-6-(benzyloxy)-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyl-6-vinyltetrahydrofuro[2,3-d][1,3]dioxole

英文别名

(3aR,5R,6R,6aR)-5-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-6-ethenyl-2,2-dimethyl-6-phenylmethoxy-5,6a-dihydro-3aH-furo[2,3-d][1,3]dioxole

(3aR,5R,6R,6aR)-6-(benzyloxy)-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyl-6-vinyltetrahydrofuro[2,3-d][1,3]dioxole化学式

CAS

96212-44-1

化学式

C₂₁H₂₈O₆

mdl

——

分子量

376.45

InChiKey

UTTJNSGLORKNEQ-ZIKOTGLESA-N

BEILSTEIN

——

EINECS

——

物化性质

沸点：

476.7±45.0 °C(predicted)
密度：

1.19±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

辛醇/水分配系数(LogP)：

2.4
重原子数：

27
可旋转键数：

5
环数：

4.0
sp3杂化的碳原子比例：

0.62
拓扑面积：

55.4
氢给体数：

0
氢受体数：

6

上下游信息

上游原料

中文名称	英文名称	CAS号	化学式	分子量
——	(3aR,5R,6R,6aR)-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyl-6-vinyltetrahydrofuro[2,3-d][1,3]dioxol-6-ol	51996-47-5	C₁₄H₂₂O₆	286.325
——	1,2:5,6-diacetone-D-glucose	582-52-5	C₁₂H₂₀O₆	260.287
1,2:5,6-二异亚丙基-alpha-D-异呋喃糖	Diacetone D-glucose	2595-05-3	C₁₂H₂₀O₆	260.287
双丙酮葡萄糖	1,2:5,6-di-O-isopropylidene-α-D-glucofuranose	582-52-5	C₁₂H₂₀O₆	260.287

下游产品

中文名称	英文名称	CAS号	化学式	分子量
——	(R)-2-((3aR,5R,6R,6aR)-6-Benzyloxy-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2-methoxy-ethanol	96212-48-5	C₁₉H₂₆O₆	350.412
——	3-O-benzyl-1,2-O-isopropylidene-3-C-vinyl-α-D-allofuranose	96212-45-2	C₁₈H₂₄O₆	336.385
——	(5R)-3-O-Benzyl-6,7-dideoxy-1,2-di-O-isopropylidene-3-C-vinyl-α-D-ribo-hept-6-enofuranose	352422-86-7	C₁₉H₂₄O₅	332.397
——	(5S)-3-O-Benzyl-6,7-dideoxy-1,2-di-O-isopropylidene-3-C-vinyl-α-D-ribo-hept-6-enofuranose	352422-85-6	C₁₉H₂₄O₅	332.397
——	(S)-((3aR,5R,6R,6aR)-6-Benzyloxy-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-methoxy-acetaldehyde	96212-49-6	C₁₉H₂₄O₆	348.396
——	(1R,2R,6R,8R,9R)-1-Benzyloxy-9-hydroxy-4,4-dimethyl-3,5,7-trioxatricyclo[6.3.0.0^2.6]undec-10-ene	352422-88-9	C₁₇H₂₀O₅	304.343
——	(1R,2R,6R,8R,9S)-1-Benzyloxy-9-hydroxy-4,4-dimethyl-3,5,7-trioxatricyclo[6.3.0.0^2.6]undec-10-ene	352422-87-8	C₁₇H₂₀O₅	304.343
——	(1R,2R,6R,8R,9R)-1,9-Bis(benzyloxy)-4,4-dimethyl-3,5,7-trioxatricyclo[6.3.0.0^2.6]undec-10-ene	352422-83-4	C₂₄H₂₆O₅	394.467
——	(3aR,5R,6R,6aR)-6-Benzyloxy-5-((Z)-(R)-1-methoxy-3-nitro-allyl)-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxole	96212-50-9	C₂₀H₂₅NO₇	391.421
——	3,5-di-O-benzyl-4-C-(hydroxymethyl)-1,2-di-O-isopropylidene-3-C-vinyl-α-D-ribofuranose	879546-88-0	C₂₅H₃₀O₆	426.51
——	(R)-1-((3aR,5R,6R,6aR)-6-Benzyloxy-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2-(tert-butyl-dimethyl-silanyloxy)-ethanol	96212-46-3	C₂₄H₃₈O₆Si	450.648
——	3-O-benzyl-4-C-(hydroxymethyl)-1,2-di-O-isopropylidene-3-C-vinyl-α-D-ribofuranose	879546-87-9	C₁₈H₂₄O₆	336.385
——	[(R)-2-((3aR,5R,6R,6aR)-6-Benzyloxy-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2-methoxy-ethoxy]-tert-butyl-dimethyl-silane	96212-47-4	C₂₅H₄₀O₆Si	464.674
——	3-O-benzyl-1,2;5,6-bis-O-isopropylidene-3-C-hydroxymethyl-α-D-allofuranose	754978-65-9	C₂₀H₂₈O₇	380.438
——	(3aR,4aR,5R,7aR,7bR)-7a-(benzyloxy)-2,2-dimethylhexahydro-5H-cyclopenta[4,5]furo[2,3-d][1,3]dioxol-5-ol	1227269-86-4	C₁₇H₂₂O₅	306.359
——	1-((3aR,5S,6S,6aR)-6-(benzyloxy)-dihydro-2,2-dimethyl-6-vinyl-5H-furo[3,2-d][1,3]dioxol-5yl)prop-2-en-1-one	1123212-76-9	C₁₉H₂₂O₅	330.381
——	((3aR,4aR,5R,8S,8aR,8bR)-8a-Benzyloxy-5-methoxy-2,2,6-trimethyl-3a,4a,5,8,8a,8b-hexahydro-benzo[4,5]furo[2,3-d][1,3]dioxol-8-yl)-methanol	96227-27-9	C₂₁H₂₈O₆	376.45
——	(3R/S,1R,4R,5R,8R)-3,4-Diacetoxy-5,8-bis(benzyloxy)-2-oxabicyclo[3.3.0]oct-6-ene	352422-90-3	C₂₅H₂₆O₇	438.477
——	(3aR,4aR,5R,8S,8aR,8bR)-8a-Benzyloxy-5-methoxy-2,2,6-trimethyl-8-trityloxymethyl-3a,4a,5,8,8a,8b-hexahydro-benzo[4,5]furo[2,3-d][1,3]dioxole	96212-56-5	C₄₀H₄₂O₆	618.77
——	(3aR,4aS,7aS,7bR)-7a-(benzyloxy)-2,2-dimethylhexahydro-5H-cyclopenta[4,5]furo[2,3-d][1,3]dioxol-5-one	136153-00-9	C₁₇H₂₀O₅	304.343
——	3,5-di-O-benzyl-1,2-O-isopropylidene-4-C-(p-toluenesulfonyloxymethyl)-3-C-vinyl-α-D-ribofuranose	879546-89-1	C₃₂H₃₆O₈S	580.699
——	2,2-Dimethyl-propionic acid (3S,3aS,4S,7R,7aR)-3a-benzyloxy-3-hydroxy-7-methoxy-6-methyl-2,3,3a,4,7,7a-hexahydro-benzofuran-4-ylmethyl ester	96212-59-8	C₂₃H₃₂O₆	404.503
——	3,5-Di-O-benzyl-3-C-hydroxyethyl-1,2-O-isopropylidene-4-C-(p-toluenesulfonyloxymethyl)-α-D-ribofuranose	457068-02-9	C₃₂H₃₈O₉S	598.714
——	1,2-di-O-acetyl-3-C-acetoxyethyl-3,5-di-O-benzyl-4-C-(p-toluenesulfonyloxymethyl)-D-ribofuranose	457068-03-0	C₃₅H₄₀O₁₂S	684.761
——	2,2-Dimethyl-propionic acid (1S,4R,5R,6S)-6-benzyloxy-6-((S)-1,2-dihydroxy-ethyl)-5-hydroxy-4-methoxy-3-methyl-cyclohex-2-enylmethyl ester	96212-58-7	C₂₃H₃₄O₇	422.519

反应信息

作为反应物：

描述：

(3aR,5R,6R,6aR)-6-(benzyloxy)-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyl-6-vinyltetrahydrofuro[2,3-d][1,3]dioxole 在盐酸、甲醇、 bis(norbornadiene)rhodium(l)tetrafluoroborate 、 sodium tetrahydroborate 、正丁基锂、三丁基膦、 10 wt% Pd(OH)2 on carbon 、 1,2-双(二苯基膦基)苯、