exo-8,exo-11-bis(2'-phenylethynyl)pentacyclo[5.4.0.0^2,6.0^3,10.0^5,9]undecane-endo-8,endo-11-diol | 461703-09-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: exo-8,exo-11-bis(2'-phenylethynyl)pentacyclo[5.4.0.0^2,6.0^3,10.0^5,9]undecane-endo-8,endo-11-diol
• CAS: 461703-09-3
• 化学式: C₂₇H₂₂O₂
• 分子量: 378.47
• InChiKey: YTKOOYFXHABSRF-YXNRJIODSA-N

反应信息

• 作为反应物：
  描述：

  exo-8,exo-11-bis(2'-phenylethynyl)pentacyclo[5.4.0.0^2,6.0^3,10.0^5,9]undecane-endo-8,endo-11-diol 在 potassium permanganate 、 苄基三丁基溴化铵 、 对甲苯磺酸 、 溶剂黄146 作用下， 以 二氯甲烷 、 苯 为溶剂， 反应 8.33h， 生成
  参考文献：
  名称：

  摘要：

  The synthesis and X-ray crystal structure of a novel, cage-functionalized bis(alpha-diketone), 4, is described. A molecular cleft is formed by two parallel planar aromatic diketone units bridged by a polycarbocyclic cage. Crystal data: T 100(l) K, monoclinic, C2/c, a = 35,6383(2), b = 11.8110(l), c = 15.6319(2) Angstrom, beta = 110.7745(2)degrees, V = 6152.04(9) Angstrom(3), Z = 12, R = 0.0691. Compound 4 is of potential interest as a new type of "host" molecule for the study of host-guest interactions in solution.

  DOI：

  10.1023/a:1014311703618
• 作为产物：
  描述：

  pentacyclo[5.4.0.0^2,6.0^3,10.0^5,9]undecane-8,11-dione 、 苯乙炔 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 24.0h， 以62%的产率得到exo-8,exo-11-bis(2'-phenylethynyl)pentacyclo[5.4.0.0^2,6.0^3,10.0^5,9]undecane-endo-8,endo-11-diol
  参考文献：
  名称：

  摘要：

  The synthesis and X-ray crystal structure of a novel, cage-functionalized bis(alpha-diketone), 4, is described. A molecular cleft is formed by two parallel planar aromatic diketone units bridged by a polycarbocyclic cage. Crystal data: T 100(l) K, monoclinic, C2/c, a = 35,6383(2), b = 11.8110(l), c = 15.6319(2) Angstrom, beta = 110.7745(2)degrees, V = 6152.04(9) Angstrom(3), Z = 12, R = 0.0691. Compound 4 is of potential interest as a new type of "host" molecule for the study of host-guest interactions in solution.

  DOI：

  10.1023/a:1014311703618