2-methyl-1,2,3,4,4a,5,8,8a-octahydro-1,4;5,8-dimethano-naphthalene-2-carbaldehyde | 87621-10-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 2-methyl-1,2,3,4,4a,5,8,8a-octahydro-1,4;5,8-dimethano-naphthalene-2-carbaldehyde
• 英文别名: 2-Methyl-1,2,3,4,4a,5,8,8a-octahydro-1,4;5,8-dimethano-naphthalin-2-carbaldehyd；4-Methyltetracyclo[6.2.1.13,6.02,7]dodec-9-ene-4-carbaldehyde
• CAS: 87621-10-1
• 化学式: C₁₄H₁₈O
• 分子量: 202.296
• InChiKey: SJCVEWSCCKRTEM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  一氧化碳 、 2-methyl-1,2,3,4,4a,5,8,8a-octahydro-1,4;5,8-dimethano-naphthalene-2-carbaldehyde 在 亚磷酸三苯酯 、 [Rh(acac)(CO)2] 、 氢气 作用下， 以 甲苯 为溶剂， 100.0 ℃ 、2.0 MPa 条件下， 反应 6.0h， 生成 、
  参考文献：
  名称：

  TW2016/5789

  摘要：

  公开号：
• 作为产物：
  描述：

  2-甲基丙烯醛 、 环戊二烯 生成 2-methyl-1,2,3,4,4a,5,8,8a-octahydro-1,4;5,8-dimethano-naphthalene-2-carbaldehyde
  参考文献：
  名称：

  Structures of the Adducts of Cyclopentadiene and Methacrylic Acid and Some of its Derivatives¹

  摘要：

  DOI：

  10.1021/ja01571a076

文献信息

• Bifunctional compound having norbornane skeleton and method for producing same
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US10343973B2

  公开（公告）日：2019-07-09

  A method for producing a bifunctional compound of formula (3) wherein R2 represents H, CH3 or C2H5, the method comprising reducing a bifunctional compound of formula (1): wherein R1 represents COOCH3, COOC2H5, COOC3H7, COOC4H9, or CHO; and R2 represents H, CH3 or C2H5, provided that when R1 represents CHO, R2 represents C2H5, in the presence of a catalyst having hydrogenation activity and hydrogen.

  一种生产式（3）双官能团化合物的方法 其中 R2 代表 H、CH3 或 C2H5、 该方法包括还原式（1）的双官能团化合物： 其中 R1 代表 COO 、COO 、COOC3H7、COOC4H9 或 CHO；R2 代表 H、 或 ，条件是当 R1 代表 CHO 时，R2 代表 ，在具有氢化活性的催化剂和氢的存在下。
• NORBORNENE DERIVATIVE, NORBORNENE POLYMER PRODUCED BY RING-OPENING (CO)POLYMERIZATION, AND PROCESS FOR PRODUCING THE POLYMER BY RING-OPENING (CO)POLYMERIZATION
  申请人：Miyamoto Yoshikazu

  公开号：US20090247798A1

  公开（公告）日：2009-10-01

  The norbornene derivative of the present invention is represented by the following formula (Im). According to the present invention, a novel norbornene derivative that is useful as a precursor monomer for preparing a cycloolefin polymer exhibiting excellent transparency, heat resistance and low-water absorption properties and having been freely controlled in the birefringence properties and the wavelength dispersion properties can be provided. According to the present invention, further, a norbornene ring-opened (co)polymer having excellent transparency and heat resistance, exhibiting high solubility in organic solvents and having specific birefringence properties and wavelength dependence, and a process for preparing the ring-opened (co)polymer can be provided.
• RESIST UNDERLAYER FILM COMPOSITION AND PATTERNING PROCESS USING THE SAME
  申请人：OGIHARA Tsutomu

  公开号：US20120108071A1

  公开（公告）日：2012-05-03

  There is disclosed a resist underlayer film composition, wherein the composition contains a polymer obtained by condensation of, at least, one or more compounds represented by the following general formula (1-1) and/or (1-2), and one or more kinds of compounds and/or equivalent bodies thereof represented by the following general formula (2). There can be provided an underlayer film composition, especially for a trilayer resist process, that can form an underlayer film having reduced reflectance, namely, an underlayer film having optimum n-value and k-value, excellent filling-up properties, high pattern-antibending properties, and not causing line fall or wiggling after etching especially in a high aspect line that is thinner than 60 nm, and a patterning process using the same.
• BIFUNCTIONAL COMPOUND HAVING NORBORNANE SKELETON AND METHOD FOR PRODUCING SAME
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US20170088504A1

  公开（公告）日：2017-03-30

  The present invention is able to provide a bifunctional compound represented by formula (1). (In the formula, R 1 represents COOCH 3 , COOC 2 H 5 , COOC 3 H 7 , COOC 4 H 9 or CHO; and R 2 represents H, CH 3 or C 2 H 5 .)
• POLYCARBONATE RESIN AND OPTICAL LENS
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US20170276837A1

  公开（公告）日：2017-09-28

  The present invention addresses the problem of providing a resin having a high Abbe number and a small difference in hygroscopic expansion coefficient with respect to a polycarbonate resin having a low Abbe number and a high refractive index. The above problem can be solved by a polycarbonate resin including structural units represented by general formula (1). In general formula (1), R represents H, CH 3 , or C 2 H 5 .