(S)-1-((2R,4a'R,5R,6'S,7'S,8'R,8a'R)-7'-(benzyloxy)-5-(((tert-butyldiphenylsilyl)oxy)methyl)-8'-(methoxymethoxy)octahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-6'-yl)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)butan-1-one | 104307-04-2

分子结构分类

有机化合物 - 苯类化合物 - 苯和取代衍生物

中文名称

——

中文别名

——

英文名称

(S)-1-((2R,4a'R,5R,6'S,7'S,8'R,8a'R)-7'-(benzyloxy)-5-(((tert-butyldiphenylsilyl)oxy)methyl)-8'-(methoxymethoxy)octahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-6'-yl)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)butan-1-one

英文别名

——

(S)-1-((2R,4a'R,5R,6'S,7'S,8'R,8a'R)-7'-(benzyloxy)-5-(((tert-butyldiphenylsilyl)oxy)methyl)-8'-(methoxymethoxy)octahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-6'-yl)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)butan-1-one化学式

CAS

104307-04-2

化学式

C₅₁H₇₀O₁₀Si

mdl

——

分子量

871.196

InChiKey

JWFBTRQNOUULTO-HWLQWPFNSA-N

BEILSTEIN

——

EINECS

——

计算性质

辛醇/水分配系数(LogP)：

8.27
重原子数：

62.0
可旋转键数：

15.0
环数：

8.0
sp3杂化的碳原子比例：

0.63
拓扑面积：

100.14
氢给体数：

0.0
氢受体数：

10.0

上下游信息

上游原料

中文名称	英文名称	CAS号	化学式	分子量
——	(6R)-7-[tert-butyl(diphenyl)silyl]oxy-6-hydroxy-1-[(2R,3R,4R,5R,6R)-5-hydroxy-6-(hydroxymethyl)-4-(methoxymethoxy)-3-phenylmethoxyoxan-2-yl]heptan-3-one	115369-32-9	C₃₈H₅₂O₉Si	680.911

下游产品

中文名称	英文名称	CAS号	化学式	分子量
——	(1S,3S)-1-((2R,4a'R,5R,6'R,7'R,8'R,8a'R)-7'-(benzyloxy)-5-(((tert-butyldiphenylsilyl)oxy)methyl)-8'-(methoxymethoxy)octahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-6'-yl)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)butan-1-ol	104307-05-3	C₅₁H₇₂O₁₀Si	873.212
——	(((2R,4a'R,5R,6'S,8'R,8a'R)-8'-(benzyloxy)-6'-((1S,3S)-1-(benzyloxy)-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)butyl)-7'-methyleneoctahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-5-yl)methoxy)(tert-butyl)diphenylsilane	104307-07-5	C₅₇H₇₄O₈Si	915.295
——	(2R,4a'R,5R,6'S,8'R,8a'S)-5-(((tert-butyldiphenylsilyl)oxy)methyl)-6'-((1S,3S)-1-hydroxy-3-((2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl)butyl)-7'-methyleneoctahydro-3H,3'H-spiro[furan-2,2'-pyrano[3,2-b]pyran]-8'-ol	104307-06-4	C₄₃H₆₂O₈Si	735.046
三苄基冈田酸	tribenzyl okadaic acid	104307-13-3	C₆₅H₈₆O₁₃	1075.39
——	[(2S,2'R,4R,4aR,6R,8aR)-2-[(1S,3S)-3-[(2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl]-1-phenylmethoxybutyl]-3-methylidene-4-phenylmethoxyspiro[4a,7,8,8a-tetrahydro-4H-pyrano[3,2-b]pyran-6,5'-oxolane]-2'-yl]methanol	104307-08-6	C₄₁H₅₆O₈	676.891
——	(2R)-3-[(2S,6R,8S,11R)-2-[(E,2R)-4-[(2S,2'R,4R,4aR,6R,8aR)-2-[(1S,3S)-3-[(2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl]-1-phenylmethoxybutyl]-3-methylidene-4-phenylmethoxyspiro[4a,7,8,8a-tetrahydro-4H-pyrano[3,2-b]pyran-6,5'-oxolane]-2'-yl]but-3-en-2-yl]-4-methyl-11-phenylmethoxy-1,7-dioxaspiro[5.5]undec-4-en-8-yl]-2-methylpropane-1,2-diol	115352-20-0	C₆₅H₈₈O₁₂	1061.41
——	(2S,4R,4aR,5'R,6R,8aR)-2-[(1S,3S)-3-[(2S,3R,6S)-3-methyl-1,7-dioxaspiro[5.5]undecan-2-yl]-1-phenylmethoxybutyl]-3-methylidene-5'-[(E,3R)-3-[(2S,6R,8S,11R)-4-methyl-11-phenylmethoxy-8-[[(4R)-2,2,4-trimethyl-1,3-dioxolan-4-yl]methyl]-1,7-dioxaspiro[5.5]undec-4-en-2-yl]but-1-enyl]-4-phenylmethoxyspiro[4a,7,8,8a-tetrahydro-4H-pyrano[3,2-b]pyran-6,2'-oxolane]	104307-11-1	C₆₈H₉₂O₁₂	1101.47