ziza-6(13)-en-3α-ol | 28102-79-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: ziza-6(13)-en-3α-ol
• 英文别名: zizanol；(1R,2R,3R,5S,8R)-2,7,7-trimethyl-6-methylidenetricyclo[6.2.1.01,5]undecan-3-ol
• CAS: 28102-79-6
• 化学式: C₁₅H₂₄O
• 分子量: 220.355
• InChiKey: JZLOTPMXLYBVOH-BGPZULBFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.87
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  ziza-6(13)-en-3α-ol 在 lithium aluminium tetrahydride 作用下， 以 吡啶 、 乙醚 为溶剂， 反应 21.0h， 生成 (+/-)-zizaene
  参考文献：
  名称：

  Revised structure of zizanol

  摘要：

  DOI：

  10.1021/jo00194a031
• 作为产物：
  描述：

  ziza-6(13)-en-3-one 在 sodium tetrahydroborate 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 反应 5.0h， 以24%的产率得到3-epizizanol
  参考文献：
  名称：

  Revised structure of zizanol

  摘要：

  DOI：

  10.1021/jo00194a031

文献信息

• BIOTECHNOLOGICAL MANUFACTURE OF VETIVERYL ESTERS
  申请人：CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE - CNRS

  公开号：US20180148666A1

  公开（公告）日：2018-05-31

  The invention relates to a vetiveryl ester comprising at least 0.5 weight percent of secondary alcohol compounds with respect to the total weight of the vetiveryl ester and to a process for the preparation a vetiveryl ester, the process comprising: providing a vetiver oil, at least one enzyme preparation and at least one acylating compound; and allowing sufficient time for the enzyme preparation to esterify the alcohol compounds of the vetiver oil with the acylating compound. The invention also relates to a vetiveryl ester obtainable by the above process, a fragrance composition comprising an above-mentioned vetiveryl ester and the use of an above-mentioned vetiveryl ester for the preparation of a perfumed product.
• [EN] BIOTECHNOLOGICAL MANUFACTURE OF VETIVERYL ESTERS<br/>[FR] FABRICATION BIOTECHNOLOGIQUE D'ESTERS DE VÉTIVER
  申请人：CENTRE NAT DE LA RECH SCIENT (CNRS)

  公开号：WO2016193208A1

  公开（公告）日：2016-12-08

  The invention relates to a vetiveryl ester comprising at least 0.5 weight percent of secondary alcohol compounds with respect to the total weight of the vetiveryl ester and to a process for the preparation a vetiveryl ester, the process comprising: providing a vetiver oil, at least one enzyme preparation and at least one acylating compound; and allowing sufficient time for the enzyme preparation to esterify the alcohol compounds of the vetiver oil with the acylating compound. The invention also relates to a vetiveryl ester obtainable by the above process, a fragrance composition comprising an above-mentioned vetiveryl ester and the use of an above-mentioned vetiveryl ester for the preparation of a perfumed product.
• Revised structure of zizanol
  作者：Sung Ho Kang、Stephen A. Monti

  DOI：10.1021/jo00194a031

  日期：1984.10