| 198222-01-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮
• CAS: 198222-01-4
• 化学式: C₂₈H₂₄N₂NiO₄*H₂O
• 分子量: 529.215
• InChiKey: CWFRYKLBKPGBJA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel(II) nitrate hexahydrate 、 ALPHA-安息香肟 以 戊醇 、 水 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and Characterization of High Oxidation State Nickel α-Benzoinoxime Complexes Generated by Ligand-Metal Redox Reaction

  摘要：

  The complexes of nickel alpha-benzoinoxime were prepared and isolated in the solid state with or without potassium persulfate. The complexes are noted, respectively, as complex B and complex A. They were characterized by elemental analyses, conductometry, polarography, infrared spectroscopy, W-Visible spectrometry, nuclear magnetic reasonance (H-1 NMR) and electronic paramagnetic reasonance (EPR). These techniques have shown the existence of the higher oxidation states of nickel complexed by alpha-benzoinoxime. The oxidation of nickel was due to an electronic exchange between the metal and the ligand. From these investigations, the formulas of these complexes were found to be (A):Ni(C14H11NO)(2)(OH)(2) . H2O and (B): Ni(C14H12NO2)(2)(OH)(2) . 1.5 H2O. Two separate synthese led to the same oxidation state for nickel, i.e. +IV. In the absence of the oxidant, the ligand was involved in a redox reaction which leads to differences in the physico-chemical properties (color, melting point, IR and H-1 NMR spectra) of the products.

  DOI：

  10.1080/00945719708000160