N-(2-acryloxyethyl)-2,2,4-trimethyldecahydroquinoline | 71828-27-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: N-(2-acryloxyethyl)-2,2,4-trimethyldecahydroquinoline
• 英文别名: 2-(2,2,4-trimethyl-3,4,4a,5,6,7,8,8a-octahydroquinolin-1-yl)ethyl prop-2-enoate
• CAS: 71828-27-8
• 化学式: C₁₇H₂₉NO₂
• 分子量: 279.423
• InChiKey: LGQYSWQWWGWVSM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  29.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  1-(2-Hydroxyethyl)-2,2,4-triethyldecahydroquinoline 、 丙烯酸甲酯（MA） 、 吩噻嗪 在 zinc(II) carbonate 作用下， 以 甲醇 为溶剂， 反应 96.0h， 生成 N-(2-acryloxyethyl)-2,2,4-trimethyldecahydroquinoline
  参考文献：
  名称：

  Polymeric ultraviolet light stabilizers containing hindered alkyl amines

  摘要：

  一种紫外光敏聚合物组合物，其中通过加入具有以下结构单元的稳定剂聚合物来增强其抗光降解性能。其中R.sub.a，R.sub.b和R.sub.c分别选自含有1至约12个碳原子的烷基，环己基或含有7至约14个碳原子的环己基烷基；A选自含有1至约24个碳原子的烷基，含有1至约18个碳原子的羟基烷基，含有1至约12个碳原子的烷氧基，含有总共2至约24个碳原子的酯基，环己基，含有7至约14个碳原子的环己基烷基，羟基，氨基和氨基烷基以及其中烷基含有1至约12个碳原子的烷基取代的氨基和氨基烷基；Z是由烯烃单体衍生的聚合物骨架的一段；x为0、1、2或3，B为氢，含有1至约12个碳原子的烷基，环己基或含有7至约14个碳原子的环己基烷基；m至少为2。上述稳定剂聚合物可以简单地与紫外光敏聚合物混合或嫁接。稳定剂聚合物也可以与其他聚合物材料共聚或嫁接，从而增强其与紫外光敏聚合物的相容性。在某些情况下，也可能共聚合从中得到紫外光敏聚合物和稳定剂聚合物的单体。

  公开号：

  US04292237A1

文献信息

• Polymeric composition having enhanced resistance to photodegradation and method of enhancing the resistance of an ultra-violet light-sensitive polymer to photodegradation
  申请人：The B.F. GOODRICH Company

  公开号：EP0006684A1

  公开（公告）日：1980-01-09

  This invention provides a composition comprising a polymer which is sensitive to photodegradation by ultra- violet light and, in an amount sufficient to substantially stabilize said polymer against such photodegradition, a mixture containing at least one substituted decahydroquinoline functional polymer of the formula wherein R , R , and R are independently selected from alkyl groups containing 1 to 12 carbon atoms, a cyclohexyl group, or cyclohexylalkyl groups containing 7 to 14 carbon atoms; A is selected from the group consisting of alkyl groups containing 1 to 18 carbon atoms, alkoxy groups containing 1 to 12 carbon atoms in the group, ester groups containing a total of from 2 to 24 carbon atoms in the group, a cyclohexyl group, cyclohexylalkyl groups containing 7 to 14 carbon atoms in the group, hydroxy groups, amino groups and aminoalkyl groups and alkyl-substituted amino and aminoalkyl groups wherein the alkyl contains 1 to 12 carbon atoms; Z is a segment of the polymer backone derived from an olefinic monomer; x is 0, 1, 2 or 3; and B is hydrogen, an alkyl group containing 1 to 12 carbon atoms, a cyclohexyl group, or a cyclohexylalkyl group of 7 to 14 carbon atoms in the group; and m is at least 2 and at least one UV absorbing compound selected from the group consisting of benzotriazoles, benzoates and nickel phenolate complexes. It also provides a method of enhancing the resistance of an ultra-violet light sensitive polymer to photodegradation which comprises incorporating therein a stabilizer of the general formula given above in an amount sufficient to substantially stabilise the polymer.

  这项发明提供了一种组合物，包括一种对紫外光光降解敏感的聚合物，以及足以在很大程度上稳定该聚合物免受光降解的混合物，该混合物包含至少一种取代的十氢喹啉官能聚合物，其化学式为其中R，R和R分别选自含有1至12个碳原子的烷基基团，环己基基团，或含有7至14个碳原子的环己基烷基基团；A选自含有1至18个碳原子的烷基基团，在羟基基团中含有1至12个碳原子，酯基团中总共含有2至24个碳原子，在环己基基团中含有7至14个碳原子的环己基烷基基团，羟基基团，氨基团和氨基烷基基团以及含有1至12个碳原子的烷基取代的氨基和氨基烷基基团；Z是从烯烃单体衍生的聚合物骨架段；x为0,1,2或3；B为氢，含有1至12个碳原子的烷基基团，环己基基团，或含有7至14个碳原子的环己基烷基基团；m至少为2，并且至少选择一种来自苯并三唑，苯甲酸酯和镍酚酸盐复合物的紫外线吸收化合物。它还提供了一种增强对紫外光敏感聚合物抗光降解性能的方法，其中包括将上述通用式的稳定剂掺入其中，以足够稳定聚合物。
• Polymeric ultraviolet light stabilisers containing hindered alkyl amines and polymer compositions containing them
  申请人：The B.F. GOODRICH Company

  公开号：EP0002022A1

  公开（公告）日：1979-05-30

  An ultraviolet light sensitive polymer composition wherein resistance to photodegradation is enhanced by the inclusion therein of a stabilizer polymer having structural units corresponding to the following formula wherein Ra, Rb, and Rc are independently selected from alkyl groups containing 1 to about 12 carbon atoms, a cyclohexyl group, or cyclohexylalkyl groups containing 7 to about 14 carbon atoms; A is selected from the group consisting of alkyl groups containing 1 to about 24 carbon atoms, hydroxyalkyl groups containing 1 to about 18 carbon atoms, alkoxy groups containing 1 to about 12 carbon atoms in the group, ester groups containing a total of from 2 to about 24 carbon atoms in the group, a cyclohexyl group, cyclohexylalkyl groups containing 7 to about 14 carbon atoms in the group, hydroxy groups, amino groups and aminoalkyl groups and alkyl-substituted amino and aminoalkyl groups wherein the alkyl contains 1 to about 12 carbon atoms; Z is a segment of the polymer backbone derived from an olefinic monomer; x is 0, 1, 2 or 3 and B is hydrogen, an alkyl group containing 1 to about 12 carbon atoms, a cyclohexyl group, or a cyclohexylalkyl group of 7 to about 14 carbon atoms in the group; and m is at least 2. The above stabilizer polymer can be simply combined with, or engrafted upon, the ultraviolet light sensitive polymer. The stabilizer polymer may also be copolymerized with, or grafted upon other polymeric materials thereby enhancing its phase compatibility with the ultraviolet light sensitive polymer. In certain instances, it is also possible to copolymerize the monomers from which are derived the ultraviolet light sensitive polymer and the stabilizer polymer.

  一种紫外线光敏聚合物组合物，其中的抗光降解性能可通过加入一种稳定剂聚合物而增强，该稳定剂聚合物具有与下式相对应的结构单元 其中 Ra、Rb 和 Rc 分别独立地选自含有 1 至约 12 个碳原子的烷基、环己基或含有 7 至约 14 个碳原子的环己基烷基；A 选自由含 1 至约 24 个碳原子的烷基、含 1 至约 18 个碳原子的羟烷基、基团中含 1 至约 12 个碳原子的烷氧基、基团中总计含 2 至约 24 个碳原子的酯基、环己基、基团中含 7 至约 14 个碳原子的环己基烷基、羟基、氨基和氨基烷基以及烷基取代的氨基和氨基烷基（其中烷基含 1 至约 12 个碳原子）组成的组；Z 是聚合物骨架的一段，由烯烃单体衍生而来；x 是 0、1、2 或 3，B 是氢、含有 1 至约 12 个碳原子的烷基、环己基或基团中含有 7 至约 14 个碳原子的环己基烷基；m 至少为 2。 上述稳定剂聚合物可以简单地与紫外线光敏聚合物结合或接枝在紫外线光敏聚合物上。稳定剂聚合物也可以与其他聚合物材料共聚或接枝，从而增强其与紫外光敏感聚合物的相容性。在某些情况下，还可以将紫外线光敏聚合物和稳定剂聚合物的单体进行共聚。
• US4292237A
  申请人：——

  公开号：US4292237A

  公开（公告）日：1981-09-29