| 891184-48-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• CAS: 891184-48-8
• 化学式: C₁₈H₁₉CeN₄O₇*H₂O
• 分子量: 561.507
• InChiKey: WJVCDNJLQBXWNQ-SJMBVUPTSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 neat (no solvent) 为溶剂， 生成 cerium(IV) oxide 、 cerium(III) oxide
  参考文献：
  名称：

  Synthesis, Characterization, and Electrochemical Studies of Ternary Complexes of Lanthanum(III) and Cerium(III) with Some Naphthylideneamino Acids and Imidazoles

  摘要：

  A new series of ternary lanthanium(III) and cerium(III) complexes containing Schiff bases derived from some amino acids, viz: glycine; alanine; phenylalanine; valine and leucine with 2-hydroxy-1-naphthaldehyde as primary ligands, and 1-methylimidazole & 1,2-dimethylimidazole as secondary ligands were synthesized. The complexes were characterized on the bases of microanalyses, electrical conductance, IR & H-1 NMR spectra, thermal analysis and cyclic voltammetric data. All complexes were found to be non-electrolytes with the general formula of [ML(NO3 )Im center dot nH(2)O] (where M = La(III) or Ce(III), L = naphthylideneamino acids, Im = 1-methylimidazole or 1,2-dimethylimidazole and n = 1 or 2). The redox properties of some of the ternary complexes of La(III) and Ce(III) were examined using cyclic voltammetry in 0.1 mol dm(-3) TBAP/DMSO solutions. The reduction potentials of the investigated complexes showed a dependence upon the nature of the amino acid of the ligand. The stability of the complexes is discussed on the basis of the thermal and electrochemical data.

  DOI：

  10.1080/15533170500359711
• 作为产物：
  描述：

  N-甲基咪唑 、 cerium(III) nitrate hexahydrate 、 DL-丙氨酸 、 2-羟基-1-萘甲醛 在 Na₂CO₃ 作用下， 以 乙醇 、 水 为溶剂， 以47%的产率得到
  参考文献：
  名称：

  Synthesis, Characterization, and Electrochemical Studies of Ternary Complexes of Lanthanum(III) and Cerium(III) with Some Naphthylideneamino Acids and Imidazoles

  摘要：

  A new series of ternary lanthanium(III) and cerium(III) complexes containing Schiff bases derived from some amino acids, viz: glycine; alanine; phenylalanine; valine and leucine with 2-hydroxy-1-naphthaldehyde as primary ligands, and 1-methylimidazole & 1,2-dimethylimidazole as secondary ligands were synthesized. The complexes were characterized on the bases of microanalyses, electrical conductance, IR & H-1 NMR spectra, thermal analysis and cyclic voltammetric data. All complexes were found to be non-electrolytes with the general formula of [ML(NO3 )Im center dot nH(2)O] (where M = La(III) or Ce(III), L = naphthylideneamino acids, Im = 1-methylimidazole or 1,2-dimethylimidazole and n = 1 or 2). The redox properties of some of the ternary complexes of La(III) and Ce(III) were examined using cyclic voltammetry in 0.1 mol dm(-3) TBAP/DMSO solutions. The reduction potentials of the investigated complexes showed a dependence upon the nature of the amino acid of the ligand. The stability of the complexes is discussed on the basis of the thermal and electrochemical data.

  DOI：

  10.1080/15533170500359711