(+/-)-9-Methylgermacrone | 929699-36-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (+/-)-9-Methylgermacrone
• CAS: 929699-36-5
• 化学式: C₁₆H₂₄O
• 分子量: 232.366
• InChiKey: KLILOJFDOUVLJN-GHEQENTPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  17.0
• 可旋转键数：
  0.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  17.07
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  (+/-)-9-Methylgermacrone 在 platinum(IV) oxide 氢气 作用下， 以 溶剂黄146 为溶剂， 生成 Hexahydro-9-methylgermacrone
  参考文献：
  名称：

  9-Methylgermacrene-B; proposed structure for novel homosesquiterpene from the sex pheromone glands ofLutzomyia longipalpis (Diptera: Psychodidae) from Lapinha, Brazil

  摘要：

  The principal volatile component (99 + %) of the sex pheromone glands of Lutzomyia longipalpis from Lapinha, Brazil, has been isolated and characterized as a novel homosesquiterpene with the specific structure proposed as 9-methylgermacrene-B, (E,E)-8-(1-methylethylidenyl)-1,5,10-trimethyl-1,5-cyclodecadiene .

  DOI：

  10.1007/bf02027726
• 作为产物：
  描述：

  吉马酮 、 碘甲烷 在 N,N-二甲基丙烯基脲 、 lithium diisopropyl amide 作用下， 以 乙二醇二甲醚 为溶剂， 生成 (+/-)-9-Methylgermacrone
  参考文献：
  名称：

  9-Methylgermacrene-B; proposed structure for novel homosesquiterpene from the sex pheromone glands ofLutzomyia longipalpis (Diptera: Psychodidae) from Lapinha, Brazil

  摘要：

  The principal volatile component (99 + %) of the sex pheromone glands of Lutzomyia longipalpis from Lapinha, Brazil, has been isolated and characterized as a novel homosesquiterpene with the specific structure proposed as 9-methylgermacrene-B, (E,E)-8-(1-methylethylidenyl)-1,5,10-trimethyl-1,5-cyclodecadiene .

  DOI：

  10.1007/bf02027726