hexadecyl phenyl ether | 35021-70-6

• 物质功能分类: 有机原料 - 烃类化合物及其衍生物 - 芳香烃
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: hexadecyl phenyl ether
• 英文别名: hexadecyloxybenzene；hexadecyl-phenyl ether；Hexadecyl-phenyl-aether；1-Phenoxy-hexadecan；Hexadecyloxy-benzol；Cetyl-phenyl-aether；Benzene, (hexadecyloxy)-；hexadecoxybenzene
• CAS: 35021-70-6
• 化学式: C₂₂H₃₈O
• 分子量: 318.543
• InChiKey: FQKWHGOHXVHGMR-UHFFFAOYSA-N

物化性质

• 熔点：
  41.8°C
• 沸点：
  417.68°C (rough estimate)
• 密度：
  0.8434

计算性质

• 辛醇/水分配系数(LogP)：
  9.8
• 重原子数：
  23
• 可旋转键数：
  16
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2909309090

反应信息

• 作为反应物：
  描述：

  hexadecyl phenyl ether 在 1,4-二氧六环 、 镍 作用下， 190.0 ℃ 、19.61 MPa 条件下， 生成 cyclohexyl-hexadecyl ether
  参考文献：
  名称：

  The Selective Hydrogenation of Derivatives of Naphthalene and Diphenyl

  摘要：

  DOI：

  10.1021/ja01270a049
• 作为产物：
  描述：

  potassium phenolate 、 溴代十六烷 在 乙醇 作用下， 生成 hexadecyl phenyl ether
  参考文献：
  名称：

  186.一些对烷氧基苯磺酰胺及其N-氯衍生物

  摘要：

  DOI：

  10.1039/jr9460000865

文献信息

• Oxidation of N-alkyl-N′-tosylhydrazines with Hg(OAc)2. A new synthesis of ethers
  作者：F. Gasparrini、L. Caglioti、D. Misiti、G. Palmieri、R. Ballini

  DOI：10.1016/0040-4020(82)80068-9

  日期：1982.1

  N-Alkyl-N′-tosylhydrazines with Hg(OAc)2 in the presence of alcohols or phenol give high yields of corresponding ethers. Reactions in the presence of acetic acid are also examined.

  在醇或苯酚的存在下，带有Hg（OAc）2的N-烷基-N'-甲苯磺酰肼的收率很高。还检查了在乙酸存在下的反应。
• Recyclable heterogeneous copper oxide on alumina catalyzed coupling of phenols and alcohols with aryl halides under ligand-free conditions
  作者：Kokkirala Swapna、Sabbavarapu Narayana Murthy、Mocharla Tarani Jyothi、Yadavalli Venkata Durga Nageswar

  DOI：10.1039/c1ob05411b

  日期：——

  various aryl as well as heteroaryl halides under ligand-free conditions are reported. This protocol provides a variety of diaryl ether and bis-diaryl ether motifs by reacting different aryl/aliphatic halides with differently substituted phenols and saturated alcohols in the presence of a catalytic amount of CuO on alumina and KOH as a base at moderate temperature under nitrogen atmosphere. The described methodology

  据报道，在无配体条件下，一种有效的氧化铝负载的CuO催化的苯酚和脂族醇与各种芳基以及杂芳基卤化物的CuO催化的O-芳基化。该方案通过在催化量的CuO存在下，使不同的芳基/脂肪族卤化物与不同取代的酚和饱和醇反应，从而提供了各种二芳基醚和双二芳基醚基序。氧化铝 和 酸值氮气氛下，在中等温度下作为碱。所描述的方法是简单，直接和有效的，以在无配体的条件下以高收率提供交叉偶联的产物。探索的催化剂便宜，空气稳定并且最多可循环使用三个周期。
• Dialky alkoxy phenyl sulfonium salt cationic initiators
  申请人：ISP Investments, Inc.

  公开号：US05274148A1

  公开（公告）日：1993-12-28

  This invention relates to C.sub.14 to C.sub.20 alkoxy monophenyl sulfonium salt initiators having the formula ##STR1## wherein R is C.sub.14 to C.sub.20 alkyl; R.sub.1 and R.sub.2 are each independently C.sub.4 to C.sub.20 alkyl and X.sup.- is a non-basic, nonnucleophilic anion, which initiators are employed in the polymerization of mono- and poly- functional glycidyl ethers, alpha-olefin oxides and vinyl monomers or oligomers.

  本发明涉及具有以下结构式的C.sub.14到C.sub.20烷氧基单苯基磺酸盐引发剂：##STR1## 其中R为C.sub.14到C.sub.20烷基；R.sub.1和R.sub.2各自独立为C.sub.4到C.sub.20烷基，X.sup.-是非碱性、非亲核的负离子。这些引发剂用于单官能团和多官能团的环氧乙烷、α-烯烃氧化物和乙烯单体或寡聚物的聚合。
• CATALYST COMPOSITION AND PROCESS FOR PRODUCTION OF OLEFIN POLYMERS USING THE CATALYST COMPOSITION
  申请人：Yabukami Minoru

  公开号：US20130102745A1

  公开（公告）日：2013-04-25

  The present invention provides a catalyst composition and a method for producing an olefin polymer using the catalyst composition. The catalyst composition is prepared by bringing (A) a transition metal compound, (B) a solid boron compound capable of forming an ion pair with the component (A), (C) an organometallic compound and (D) a compound represented by the following general formula (XIV) and/or the following general formula (XV) into contact with each other in a hydrocarbon solvent, and enables a high catalyst concentration. Z 5 R 14 R 15 (XIV) Z 6 R 14 R 15 R 16 (XV) [In the formulae, Z 5 represents an oxygen atom, etc.; Z 6 represents a nitrogen atom, etc.; R 14 to R 16 each independently represent an organic group, and at least one of those organic groups is an organic group having at least 3 carbon atoms, and R 14 to R 16 may bond to each other to form a ring.]

  本发明提供了一种催化剂组合物及使用该催化剂组合物生产烯烃聚合物的方法。该催化剂组合物是通过将（A）过渡金属化合物，（B）固体硼化合物与组分（A）形成离子对的固体硼化合物，（C）有机金属化合物和（D）由下列一般式（XIV）和/或下列一般式（XV）所表示的化合物在烃溶剂中接触而制备的，并能够实现高催化剂浓度。 Z5R14R15（XIV） Z6R14R15R16（XV） [在公式中，Z5代表氧原子等；Z6代表氮原子等；R14到R16各自独立地代表有机基团，其中至少有一个有机基团是具有至少3个碳原子的有机基团，且R14到R16可以相互结合形成环。]
• Photographic material suited for use in diffusion transfer photography
  申请人：AGFA-GEVAERT naamloze vennootschap

  公开号：EP0038092A1

  公开（公告）日：1981-10-21

  A photographic material for diffusion transfer photography containing a quinonoid compound, which is capable in reduced state and under alkaline conditions of releasing a photographically useful group and corresponds to one of the following general formulae: wherein: each of (Nuox)' and (Nuox)2 (same or different) represents an oxidized nucleophilic group, Z represents a bivalent atom or bivalent atomic group, which is electro-negative, Q together with the group Z represents a releasable photographically useful group, Y' and Y2 together represent the necessary atoms to close a p-quinonoid ring substituted with (a) directly linked monovalent organic ring or ring system substituent(s) having aromatic character, Y' represents the necessary atoms to close a o-quinonoid ring substituted with (a) directly linked monovalent organic ring or ring system substituent(s) having aromatic character, and each of R' and R' (same or different) represents hydrogen or a (substituted) hydrocarbon group, and at least one of R', R' and a substituent on the quinonoid ring being or carrying a ballasting group.

  一种用于扩散转移摄影的感光材料，含有醌类化合物，在还原状态和碱性条件下能释放出对摄影有用的基团，并符合以下通式之一： 其中 (Nuox)'和 (Nuox)2（相同或不同）中的每一个代表一个氧化亲核基团、 Z 代表负电性的二价原子或二价原子团、 Q 与基团 Z 一起代表可释放的摄影用基团、 Y'和 Y2 共同代表关闭被（a）具有芳香特性的直接相连的一价有机环或环系取代基取代 的对醌环所需的原子、 Y' 代表关闭被具有芳香性质的（a）直接相连的一价有机环或环系取代基取代的邻 喹啉环所需的原子，以及 R'和 R'（相同或不同）各自代表氢或（取代的）烃基，R'、R'和喹啉环上的取代基中至少有一个是或带有压载基。