3-(4-methylcyclohex-3-enyl)butanal | 199445-85-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 3-(4-methylcyclohex-3-enyl)butanal
• 英文别名: (Ξ)-3-((R)-4-methyl-cyclohex-3-enyl)-butyraldehyde；(Ξ)-3-((R)-4-Methyl-cyclohex-3-enyl)-butyraldehyd；3-[(1R)-4-methylcyclohex-3-en-1-yl]butanal
• CAS: 199445-85-7
• 化学式: C₁₁H₁₈O
• 分子量: 166.263
• InChiKey: VJYFMQREUJXCQV-DTIOYNMSSA-N

物化性质

• 沸点：
  234.2-242.6℃ at 102.4-102.6kPa
• 密度：
  0.933 at 20℃
• LogP：
  3.7-4 at 35℃ and pH7

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3-(4-methylcyclohex-3-enyl)butanal 在 铂 作用下， 生成 beta,4-二甲基-环己烷丙醛
  参考文献：
  名称：

  Perfume composition

  摘要：

  公开号：

  US02710825A1
• 作为产物：
  描述：

  一氧化碳 、 甜橙提取物 在 1,3-二甲基吡唑 、 di(rhodium)tetracarbonyl dichloride 、 氢气 作用下， 70.0 ℃ 、20.27 MPa 条件下， 反应 7.0h， 生成 3-(4-methylcyclohex-3-enyl)butanal
  参考文献：
  名称：

  吡唑作为配体用于超临界二氧化碳中的 Rh 催化烯烃加氢甲酰化

  摘要：

  研究了吡唑配体在 Rh 催化剂存在下在超临界二氧化碳 (scCO2) 中许多不饱和末端底物的加氢甲酰化中的活性。发现在吡唑环的 1 位没有游离 NH 基团的配体是有活性的。与甲苯相比，使用 scCO2 作为反应介质有助于达到更高的加氢甲酰化转化率和区域选择性。

  DOI：

  10.1007/s11172-012-0331-z

文献信息

• [EN] PHOTOLABILE ACETAL AND KETAL COMPOUNDS FOR THE CONTROLLED RELEASE OF ACTIVE VOLATILE CARBONYL COMPOUNDS<br/>[FR] COMPOSÉS ACÉTALS ET CÉTALS PHOTOLABILES POUR LA LIBÉRATION CONTRÔLÉE DE COMPOSÉS DE CARBONYLE VOLATILS ACTIFS
  申请人：FIRMENICH & CIE

  公开号：WO2016116420A1

  公开（公告）日：2016-07-28

  The present invention relates to a delivery system based on photosensitive acetal or ketal compounds capable of liberating upon exposure to light an active volatile carbonyl compound in a controlled manner from a surface into the surrounding. The delivery system can be used to release active substances such as flavors, fragrances, malodor counteractants, insect attractants or insect repellents. The invention also relates to the use of said acetal or ketal compounds in perfumery, as well as in perfuming compositions or perfumed consumer articles.

  本发明涉及一种基于光敏缩醛或缩酮化合物的递送系统，该系统能够在光照下以可控方式从表面释放出活性挥发性羰基化合物进入周围环境。该递送系统可用于释放活性物质，如香料、香味、恶臭中和剂、昆虫引诱剂或昆虫驱避剂。本发明还涉及所述缩醛或缩酮化合物在香水制造中的应用，以及在香精组合物或香氛消费品中的应用。
• [EN] DIVINYL ETHER DERIVATIVES CAPABLE OF RELEASING ACTIVE ALDEHYDES AND KETONES AND METHODS OF USE FOR PERFUMING SURFACES<br/>[FR] DÉRIVÉS DE DIVINYL ÉTHER CAPABLES DE LIBÉRER DES ALDÉHYDES ACTIFS ET DES CÉTONES ET PROCÉDÉS D'UTILISATION POUR PARFUMER DES SURFACES
  申请人：FIRMENICH & CIE

  公开号：WO2010029462A1

  公开（公告）日：2010-03-18

  The present invention provides divinyl ether derivatives capable of releasing in a controlled manner at least one active aldehyde and/or ketone into the surrounding environment. The invention relates to the use of these divinyl ether derivatives as perfuming or flavoring ingredients, as well as to the perfuming compositions and consumer articles containing them.

  本发明提供了一种二烯基醚衍生物，能够以受控方式释放至少一种活性醛和/或酮进入周围环境。该发明涉及将这些二烯基醚衍生物用作香料或调味成分，以及含有它们的香水组合物和消费品。
• [EN] COMPOUNDS FOR THE CONTROLLED RELEASE OF ACTIVE ALDEHYDES<br/>[FR] COMPOSES DESTINES A LA LIBERATION CONTROLEE D'ALDEHYDES ACTIFS
  申请人：FIRMENICH & CIE

  公开号：WO2003082850A1

  公开（公告）日：2003-10-09

  The present invention relates to the field of perfumery. More particularly, it concerns an aldoxane derivative of Formula (I) capable of protecting an active aldehyde R1CHO, for example a perfumery or flavor aldehyde, from a chemically aggressive medium into which they have to be added, and then of releasing said active aldehyde at the desired moment. The present invention concerns also the use of said compound in perfumery or in the flavor industry as well as the compositions or articles associated with said aldoxanes.

  本发明涉及香料领域。更具体地，涉及一种具有式（I）的aldoxane衍生物，能够保护活性醛R1CHO，例如香料或风味醛，免受化学侵蚀性介质的影响，然后在所需时释放该活性醛。本发明还涉及在香料或风味行业中使用该化合物以及与该aldoxanes相关的组合物或物品。
• [EN] PRO-PERFUME COMPOSITIONS<br/>[FR] COMPOSITIONS DE PROPARFUM
  申请人：FIRMENICH & CIE

  公开号：WO2021123144A1

  公开（公告）日：2021-06-24

  The present invention relates to a perfuming composition comprising at least two properfume compounds selected from the group consisting of a pro-perfume compound releasing a perfume compound upon exposure to light, a pro-perfume compound releasing a perfume compound upon exposure to air/oxygen, a pro-perfume compound releasing a perfume compound upon exposure to heat, a pro-perfume compound releasing a perfume compound upon exposure to moisture and a pro-perfume compound releasing a perfume compound upon exposure to enzymes. The present invention further concerns a perfumed consumer product comprising the inventive perfuming composition, as well as the use of the inventive perfuming composition for improving, enhancing, conferring and/or modifying the fragrance impression and/or fragrance intensity of a consumer product.

  本发明涉及一种香水组合物，包括至少两种从以下组成的适当香气化合物中选择的香气化合物：一种在光照下释放香水化合物的前香水化合物，一种在空气/氧气暴露下释放香水化合物的前香水化合物，一种在热暴露下释放香水化合物的前香水化合物，一种在湿气暴露下释放香水化合物的前香水化合物以及一种在酶暴露下释放香水化合物的前香水化合物。本发明进一步涉及一种含有创新香水组合物的香水消费产品，以及使用创新香水组合物来改善、增强、赋予和/或修改消费产品的香气印象和/或香气强度。
• [EN] USE OF DYNAMIC MIXTURES FOR A CONTROLLED RELEASE OF FRAGRANCES<br/>[FR] UTILISATION DE MELANGES DYNAMIQUES POUR LIBERATION CONTROLEE DE FRAGRANCES
  申请人：FIRMENICH & CIE

  公开号：WO2006016248A1

  公开（公告）日：2006-02-16

  The present invention relates to a delivery system in the form of a dynamic mixture obtained by reacting together, in the presence of water, at least one hydrazine derivative with at least one perfuming, flavoring, insect repellent or attractant, bactericide and/or fungicide aldehyde or ketone. The invention's mixture is capable of releasing in a controlled and prolonged manner said aldehyde or ketone in the surrounding environment. Furthermore, the present invention concerns also the use of said dynamic mixtures as perfuming ingredients as well as the perfuming compositions or perfumed articles comprising the invention's mixtures.

  本发明涉及一种交互反应得到的动态混合物形式的递送系统，所述动态混合物是通过在水的存在下，将至少一种肼衍生物与至少一种香料、调味剂、驱虫剂或诱引剂、杀菌剂和/或杀菌醛或酮一起反应而获得的。本发明的混合物能够在周围环境中以受控和持久的方式释放所述的醛或酮。此外，本发明还涉及将所述动态混合物用作香料成分，以及包含本发明混合物的香水组合物或香水制品的用途。