(1S,4R,6R)-1-methyl-4-((R)-2-methyloxiran-2-yl)-7-oxa-bicyclo[4.1.0]heptane | 96-08-2

• 物质功能分类: 有机原料 - 烃类化合物及其衍生物
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环己烷
• 英文名称: (1S,4R,6R)-1-methyl-4-((R)-2-methyloxiran-2-yl)-7-oxa-bicyclo[4.1.0]heptane
• 英文别名: (1S,2R,4R,8R)-1,2:8,9-diepoxy-p-menthane；(1S,4R,6R)-1-methyl-4-[(2R)-2-methyloxiran-2-yl]-7-oxabicyclo[4.1.0]heptane
• CAS: 96-08-2
• 化学式: C₁₀H₁₆O₂
• 分子量: 168.236
• InChiKey: RBHIUNHSNSQJNG-IMSYWVGJSA-N

物化性质

• 沸点：
  237.18°C (rough estimate)
• 密度：
  0.9607 (rough estimate)
• LogP：
  0.663 (est)

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.1
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 危险品标志：
  Xi
• 海关编码：
  2932999099
• 包装等级：
  Z01
• 安全说明：
  S26,S36/37/39
• 危险类别码：
  R36/37/38

制备方法与用途

用途：

• 环氧树脂中间体
• 食品包装材料涂层
• 光造型，用于制作医学模型
• 电子材料中间体
• 汽车底漆
• 高压电缆

反应信息

• 作为产物：
  描述：

  甜橙提取物 在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 生成 (1S,4R,6R)-1-methyl-4-((R)-2-methyloxiran-2-yl)-7-oxa-bicyclo[4.1.0]heptane
  参考文献：
  名称：

  Carman, Raymond M.; Klika, Karel D., Australian Journal of Chemistry, 1991, vol. 44, # 12, p. 1803 - 1808

  摘要：

  DOI：

文献信息

• MONOMER COMPOSITION AND CURABLE COMPOSITION CONTAINING SAME
  申请人：Daicel Corporation

  公开号：EP3162830A1

  公开（公告）日：2017-05-03

  Provided is a monomer composition that has rapid curability and can be cured rapidly, even in the presence of oxygen and/or water, to form a cured product having excellent adhesion to a wide variety of substrates. The monomer composition according to the present invention contains a vinyl ether compound (A). The vinyl ether compound (A) includes a vinyl ether compound (a) having a cyclic ether skeleton. The monomer composition further contains at least one compound selected from the group consisting of a vinyl ether compound (a') having a chain hydrocarbon skeleton, a divinyl ether compound (a"-1) having a cyclic hydrocarbon skeleton, an oxetane compound (B), and an epoxy compound (C).

  本发明提供了一种单体组合物，该单体组合物具有快速固化性，即使在有氧气和/或水的情况下也能快速固化，从而形成对各种基材具有优异附着力的固化产品。本发明的单体组合物含有乙烯基醚化合物（A）。乙烯基醚化合物（A）包括具有环醚骨架的乙烯基醚化合物（a）。单体组合物还含有至少一种选自以下组别的化合物：具有链烃骨架的乙烯基醚化合物（a'）、具有环烃骨架的二乙烯基醚化合物（a"-1）、氧杂环丁烷化合物（B）和环氧化合物（C）。
• Limonene epoxidation with H2O2 promoted by Al2O3: Kinetic study, experimental design
  作者：Anderson J. Bonon、Yuriy N. Kozlov、Juliana O. Bahú、Rubens Maciel Filho、Dalmo Mandelli、Georgiy B. Shul’pin

  DOI：10.1016/j.jcat.2014.08.004

  日期：2014.11

  A highly efficient oxidation of limonene with hydrogen peroxide promoted by cheap aluminum oxide has been studied. The reaction is a rare example of the epoxidation promoted by a derivative of non-transition metal having a single stable non-zero oxidation state (SSOS metal), and it affords epoxides which are highly valuable products (fragrances, food additives and monomers). Typically, ethyl acetate at 80 degrees C was used as a solvent. The experimental data have been described by the proposed kinetic scheme. The optimization of the limonene epoxidation using a 2(3) experimental design has been carried out. (C) 2014 Elsevier Inc. All rights reserved.
• Carman, Raymond M.; Klika, Karel D., Australian Journal of Chemistry, 1991, vol. 44, # 12, p. 1803 - 1808
  作者：Carman, Raymond M.、Klika, Karel D.

  DOI：——

  日期：——