acrylic acid silver salt | 5651-26-3

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: acrylic acid silver salt
• 英文别名: silver acrylate；acrylic acid ; silver (I)-compound；Acrylsaeure; Silber(I)-Verbindung；silver(1+) acrylate；silver;prop-2-enoate
• CAS: 5651-26-3
• 化学式: Ag*C₃H₃O₂
• 分子量: 178.924
• InChiKey: CIKKJIBYRMZFNO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.08
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.1
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• TSCA：
  No
• 危险类别码：
  R20/21/22
• 海关编码：
  2916129000
• 安全说明：
  S36/37/39

反应信息

• 作为反应物：
  描述：

  4-bromocyclopent-2-enone 、 acrylic acid silver salt 以 1,4-二氧六环 为溶剂， 反应 24.0h， 以25%的产率得到4-hydroxycyclopent-2-en-1-one acrylate
  参考文献：
  名称：

  Existence and reactivity of bicyclic annulenones. 2. Bicyclo[3.3.0]octa-1(5),3,7-triene-2,6-dione

  摘要：

  DOI：

  10.1021/jo00390a009
• 作为产物：
  描述：

  sodium 2-propenoate 、 silver nitrate 以 水 为溶剂， 生成 acrylic acid silver salt
  参考文献：
  名称：

  Intramolecularly coordinated organoantimony(III) carboxylates

  摘要：

  The reactions of organoantimony chlorides (LSbCl2)-Sb-1,2 1 and 2 ([2,6-(ROCH2)(2)C6H3](-), R = Me; L-1 and R = t-Bu; L-2) with silver salts of selected carboxylic acids resulted to corresponding organoantimony carboxylates L-1,L-2 Sb(OOCR')(2), 1a-c (for L-1) and 2a-c (for L-2), where R'= CH3 for la, 2a; R' = CH=CH2 for 1b, 2b and R'= CF3 for 1c, 2c. All compounds were characterized by the help of elemental analysis, ESI-MS, H-1 and C-13 NMR spectroscopy. The solid state structure investigation using single crystal X-ray diffraction techniques (2a, c) and IR spectroscopy revealed significant differences in coordination mode of both O,C,O chelating ligand and carboxylic groups in this set of compounds. The structure of all compounds in solution of non-coordinating solvent (CDCl3) was determined by means of variable temperature H-1, C-13, F-19 NMR spectroscopy and IR spectroscopy. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.06.005

文献信息

• Process for preparing fluorinated alkyl carboxylate esters
  申请人：Andrews Allen Mark

  公开号：US20070123731A1

  公开（公告）日：2007-05-31

  A process for preparing fluorinated alkyl carboxylate esters comprises reaction of a silver carboxylate or silver carboxylate precursor, such as silver (I) iodide with a fluorinated alkyl iodide and a carboxylic acid. Preferably the fluorinated alkyl iodide has the general formula CF 3 (CF 2 ) n CH 2 CH 2 I, wherein n is an integer in the range of from 1 to 29 and the carboxylic acid is acetic acid, acrylic acid or methacrylic acid.

  制备氟代烷基羧酸酯的过程包括将银羧酸盐或银羧酸盐前体（例如碘化银（I））与氟代烷基碘化物和羧酸反应。最好的情况是，氟代烷基碘化物具有一般式CF3(CF2)nCH2CH2I，其中n是1至29范围内的整数，而羧酸是乙酸、丙烯酸或甲基丙烯酸。
• Functionalization of Carbon Dioxide with Ethylene at Molybdenum Hydride Complexes
  作者：Yuanyuan Zhang、Brian S. Hanna、Andrew Dineen、Paul G. Williard、Wesley H. Bernskoetter

  DOI：10.1021/om400448m

  日期：2013.7.22

  molybdenum(II) dihydride complex. Addition of dihydrogen to the dismuation product mixture affords a nearly quantitative yield of (Triphos)MoH4PPh3. The molybdenum tetrahydride species facilitates CO2 insertion into a metal hydride to produce a formate complex, (Triphos)Mo(H)(κ2-CHO2)(PPh3), with an observed rate constant of [2.9(2)] × 10–4 s–1 (25 °C), which is independent of CO2 pressure. Selective formation

  发现将三乙基硼氢化钠加到（Triphos）MoCl 3中生成的四氢化钼物种（Triphos）MoH 4 PPh 3（Triphos = PhP（CH 2 CH 2 PPh 2）2）可以促进CO 2官能化，从而提供丙烯酸酯，丙酸酯和有甲的物种。（Triphos）MoH 4 PPh 3的形成是通过（Triphos）Mo（H）Cl（PPh 3）中间体发生的，然后使未观察到的六配位二氢钼（II）配合物发生歧化。将二氢添加到分散产物混合物中可得到几乎定量的（Triphos）MoH 4 PPh3。钼物种四氢化促进CO 2插入金属氢化物以产生甲酸盐复合物，（三膦）沫（H）（κ 2 -CHO 2）（PPH 3）中，用的观察速率常数[2.9（2）]× 10 –4 s –1（25°C），与CO 2压力无关。选择性形成的丙烯酸酯和丙二氧化碳-乙烯偶联产物，（三膦）沫（H）（κ 2 -C 3 ħ 3 ö 2）（PPH
• Formation of carbon–carbon bonds by ring closure of β-phenylselenocrotonates
  作者：Derrick L. J. Clive、Pierre L. Beaulieu

  DOI：10.1039/c39830000307

  日期：——

  Successive treatment of olefins with PhSeCl and silver crotonate affords β-phenylselenocrotonates which, on reaction with triphenyltin hydride in the presence of azobisisobutyronitrile, are converted into γ-lactones by a process that introduces a new carbon–carbon bond.

  用PhSeCl和巴豆酸银对烯烃进行连续处理，得到β-苯基硒代巴豆酸根，在偶氮二异丁腈存在下与氢化三苯锡反应后，通过引入新的碳-碳键的过程将其转化为γ-内酯。
• Synthesis of Mono- and Diunsaturated Esters of TADDOL
  作者：Liliana Koll、Julio Podestá、Darío Gerbino、Sandra Mandolesi

  DOI：10.1055/s-2005-872123

  日期：——

  higher yield, and to justthe diesters, depending on the structure of the starting acids. These reactions take place in most cases in good to excellent overall yields (57-95%). The reaction between a dichloro derivative of TADDOL and the silver salts of α,β-unsaturated acids also gives the corresponding unsaturated diesters of TADDOL in good yields.

  报道了(4R,5R)-2,2-二甲基-a,a,a',a'-四苯基-1,3-二氧戊环-4,5-二甲醇(TADDOL)的十四种新型单酯和二酯的合成. 该研究表明，在正丁基锂 (BuLi) 的存在下，TADDOL (1) 与酰氯（衍生自正常和 α,β-不饱和羧酸）的酯化反应可以生成相应的单酯和二酯的混合物，即后者的产率更高，并且仅是二酯，这取决于起始酸的结构。这些反应在大多数情况下以良好至极好的总产率 (57-95%) 发生。TADDOL 的二氯衍生物与 α,β-不饱和酸的银盐之间的反应也以良好的收率产生了相应的 TADDOL 不饱和二酯。
• Ancillary Ligand Effects on Carbon Dioxide-Ethylene Coupling at Zerovalent Molybdenum
  作者：Brian S. Hanna、Alex D. MacIntosh、Steven Ahn、Brian T. Tyler、G. Tayhas R. Palmore、Paul G. Williard、Wesley H. Bernskoetter

  DOI：10.1021/om500324h

  日期：2014.7.14

  A series of zerovalent molybdenum complexes bearing triphosphine ligands, [Ar2PCH2CH2](2)PPh, have been synthesized and evaluated for reductive functionalization of CO2 with ethylene. The ability to form dimeric triphosphine molybdenum(U) acrylate hydride species from CO2-ethylene coupling was found to be highly sensitive to steric encumbrance on the phosphine aryl substituents. Trapping of triphosphine molybdenum(II) acrylate hydride species using triphenylphosphine afforded isolable monomeric CO2 functionalization products with all ancillary ligands studied. Kinetic analysis of the acrylate formation reaction revealed a first-order dependence on molybdenum, but no influence from CO2 pressure or the triphenylphosphine trap. Systematic attenuation of steric and electronic features of the triphosphine ligands showed a strong CO2 functionalization rate influence for ligand size with [(3,5-Bu-t-C6H3)(2)PCH2CH2](2)PPh coupling nearly four times slower than with [(3,5-Me-C6H3)(2)PCH2CH2](2)PPh. A considerably milder electronic effect was observed with complexes bearing [(4-F-C6H4)(2)PCH2CH2](2)PPh reducing CO2 at approximately half the rate as with [Ph2PCH2CH2](2)PPh.