magireol-A | 107041-00-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: magireol-A
• 英文别名: (2S,5S,6R)-2-[(2R,4aS,6R,8aR)-2-[(2S,5R)-5-bromo-2,6,6-trimethyloxan-2-yl]-4a-methyl-3,4,6,7,8,8a-hexahydro-2H-pyrano[3,2-b]pyran-6-yl]-6,10-dimethylundec-9-ene-2,5,6-triol
• CAS: 107041-00-9；109063-83-4
• 化学式: C₃₀H₅₃BrO₆
• 分子量: 589.651
• InChiKey: KZSISDVLCPXFBE-KMJZPMASSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  37
• 可旋转键数：
  9
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  88.4
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  magireol-A 在 对甲苯磺酸 、 间氯过氧苯甲酸 作用下， 生成 (+)-Thyrsiferol
  参考文献：
  名称：

  来自海洋红藻Laurencia obtusa(Hudson) Lamouroux 的细胞毒性角鲨烯衍生聚醚

  摘要：

  已从标题藻类中分离出五种具有角鲨烯碳骨架的新型细胞毒性三萜类化合物。15(28)-脱水thyrsiferyl diacetate、15-anhydrothyrsiferyl diacetate 和magireol-A 的结构通过光谱和化学方法得到证实。从光谱数据推导出magireol-B和-C的结构。

  DOI：

  10.1246/cl.1987.361

文献信息

• AGENTS FOR PREVENTING ATTACHMENT OF BARNACLE CONSISTING OF ORGANIC SOLVENT EXTRACTS OF RED ALGA LAURENCIA SP. AND COMPOUNDS ISOLATED THEREFROM
  申请人：Okino Tatsufumi

  公开号：US20100204315A1

  公开（公告）日：2010-08-12

  An object of the present invention is to provide organic solvent extracts of red algae laurencia sp., compounds isolated and identified therefrom, and an agent for preventing attachment of barnacles comprising them. The present invention relates to a barnacle attachment preventive agent consisting of at least one selected from the group consisting of Laurencin, Thyrsiferol, Magireol A, Omaezallene, Hachijojimallene A and organic solvent extracts of red algae laurencia sp.
• US8258178B2
  申请人：——

  公开号：US8258178B2

  公开（公告）日：2012-09-04
• Cytotoxic Squalene-Derived Polyethers from the Marine Red Alga<i>Laurencia obtusa</i>(Hudson) Lamouroux
  作者：Teruaki Suzuki、Satoshi Takeda、Minoru Suzuki、Etsuro Kurosawa、Arata Kato、Yoshihiko Imanaka

  DOI：10.1246/cl.1987.361

  日期：1987.2.5

  Five new cytotoxic triterpenoids with squalene carbon skeleton have been isolated from the title alga. The structures of 15(28)-anhydrothyrsiferyl diacetate, 15-anhydrothyrsiferyl diacetate, and magireol-A were confirmed by the spectral and chemical methods. The structures of magireol-B and -C were deduced from the spectral data.

  已从标题藻类中分离出五种具有角鲨烯碳骨架的新型细胞毒性三萜类化合物。15(28)-脱水thyrsiferyl diacetate、15-anhydrothyrsiferyl diacetate 和magireol-A 的结构通过光谱和化学方法得到证实。从光谱数据推导出magireol-B和-C的结构。