4,8,12-trimethyltridecanal | 76760-44-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 4,8,12-trimethyltridecanal
• CAS: 76760-44-6
• 化学式: C₁₆H₃₂O
• 分子量: 240.429
• InChiKey: AMRDPZILMVNORS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  17
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4,8,12-trimethyltridecanal 在 Nickel on Kieselguhr 氢气 作用下， 以 四氢呋喃 为溶剂， 125.0 ℃ 、6.31 MPa 条件下， 生成 4,8,12-trimethyltridecan-1-ol
  参考文献：
  名称：

  [EN] SPECIFIC POLYBRANCHED ALDEHYDES, ALCOHOLS SURFACTANTS AND CONSUMER PRODUCTS BASED THEREON
  [FR] ALDÉHYDES RAMIFIÉS SPÉCIFIQUES ALCOOLS, TENSIOACTIFS ET PRODUITS DE CONSOMMATION À BASE DE CEUX-CI

  摘要：

  公开号：

  WO2010033976A3
• 作为产物：
  描述：

  3,7,11-三甲基-1-十二碳烯 、 一氧化碳 在 三(三苯基膦)羰基氢化铑 、 4,5-双二苯基膦-9,9-二甲基氧杂蒽 氢气 作用下， 以 甲苯 为溶剂， 45.0 ℃ 、1.52 MPa 条件下， 生成 4,8,12-trimethyltridecanal
  参考文献：
  名称：

  [EN] SPECIFIC POLYBRANCHED ALDEHYDES, ALCOHOLS SURFACTANTS AND CONSUMER PRODUCTS BASED THEREON
  [FR] ALDÉHYDES RAMIFIÉS SPÉCIFIQUES ALCOOLS, TENSIOACTIFS ET PRODUITS DE CONSOMMATION À BASE DE CEUX-CI

  摘要：

  公开号：

  WO2010033976A3

文献信息

• POLYHYDRIC PHENOL COMPOUND AND METHOD OF PRODUCING SAME
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：US20190210947A1

  公开（公告）日：2019-07-11

  The present invention provides a polyhydric phenol compound which has an excellent alkali resistance and which does not cause a deterioration in color even when used as a resin raw material or a color developer. The polyhydric phenol compound includes: a bisphenol compound (A) represented by the following Formula (1) and a trisphenol compound (B) represented by the following Formula (2): [wherein R 1 represents a monovalent aliphatic hydrocarbon group having from 6 to 24 carbon atoms; each of R 2 , R 3 , R 4 , R 5 and R 6 represents a monovalent hydrocarbon group having from 1 to 15 carbon atoms; and each of a, b, c, d and e represents an integer from 0 to 4]; wherein the trisphenol compound (B) is contained in an amount, in terms of absorption intensity ratio at 254 nm, of less than 1.6% by area with respect to the amount of the bisphenol compound (A).

  本发明提供了一种聚羟基酚化合物，具有优异的耐碱性能，并且即使用作树脂原料或颜料开发剂也不会导致颜色恶化。该聚羟基酚化合物包括：由以下公式（1）表示的双酚化合物（A）和由以下公式（2）表示的三酚化合物（B）：[其中R1表示具有6至24个碳原子的单价脂肪烃基；R2、R3、R4、R5和R6中的每一个表示具有1至15个碳原子的单价烃基；a、b、c、d和e中的每一个表示0至4的整数]；其中，以吸收强度比值（在254 nm处）计算，三酚化合物（B）的含量在面积上小于双酚化合物（A）的含量的1.6％。
• Specific polybranched surfactants and consumer products based thereon
  申请人：The Procter & Gamble Company

  公开号：EP2650280A1

  公开（公告）日：2013-10-16

  A process for preparing a detergent alcohol mixture comprising the steps of providing one or more poly-branched poly-olefins, wherein the poly-branched poly-olefins must contain one non-branched terminal olefin and one or more additional branched olefins in the molecule; hydroformylating said poly-branched poly-olefins to produce a poly-branched olefin containing aldehyde product with one or more olefins or mixture thereof; reducing the aldehyde product of step (b) in the presence of hydrogen and a hydrogenation catalyst to form a poly-branched detergent alcohol mixture; and removing said poly-branched alcohol mixture from said catalyst and branched aldehydes, alcohols and surfactants produced from the products of this process.

  一种制备洗涤剂醇混合物的工艺，包括以下步骤 提供一种或多种多支链聚烯烃，其中多支链聚烯烃分子中必须含有一种非支链末端烯烃和一种或多种额外的支链烯烃； 使所述多支链聚烯烃加氢甲酰化，生成含有一种或多种烯烃或其混合物的多支链烯烃醛产物；在氢气和氢化催化剂存在下还原步骤(b)的醛产物，形成多支链洗涤剂醇混合物；从所述催化剂和由该工艺产物产生的支链醛、醇和表面活性剂中除去所述多支链醇混合物。
• Specific polybranched alcohols and consumer products based thereon
  申请人：The Procter & Gamble Company

  公开号：EP2650275A1

  公开（公告）日：2013-10-16

  A detergent alcohol composition comprising at least one acyclic alcohol having 11, 16, or 21 carbon atoms, also comprising at least three branches wherein the branches are methyl, ethyl or mixtures thereof wherein the alcohol is obtainable from a starting polybranched polyolefin selected from the group consisting of: a. natural derived famesene extracted from pre-existing plants and organisms; b. famesene obtained via genetically modified organisms; c. synthetically derived trimers of isoprene; and d. mixtures thereof.

  一种洗涤醇组合物，包含至少一种具有 11、16 或 21 个碳原子的无环醇，还包含至少三个分支 其中支链为甲基、乙基或其混合物 其中，该醇可从选自以下组别的起始多支链聚烯烃中获得 a. 从现有植物和生物中提取的天然法墨烯； b. 通过转基因生物获得的法墨烯 c. 人工合成的异戊二烯三聚体；以及 d. 它们的混合物。
• POLYVALENT PHENOL COMPOUND AND METHOD OF PRODUCING SAME
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3514193A1

  公开（公告）日：2019-07-24

  The present invention provides a polyhydric phenol compound which has an excellent alkali resistance and which does not cause a deterioration in color even when used as a resin raw material or a color developer. The polyhydric phenol compound includes: a bisphenol compound (A) represented by the following Formula (1) and a trisphenol compound (B) represented by the following Formula (2): [wherein R1 represents a monovalent aliphatic hydrocarbon group having from 6 to 24 carbon atoms; each of R2, R3, R4, R5 and R6 represents a monovalent hydrocarbon group having from 1 to 15 carbon atoms; and each of a, b, c, d and e represents an integer from 0 to 4] ; wherein the trisphenol compound (B) is contained in an amount, in terms of absorption intensity ratio at 254 nm, of less than 1.6% by area with respect to the amount of the bisphenol compound (A).

  本发明提供了一种多羟基酚化合物，它具有优异的耐碱性，即使用作树脂原料或显 色剂也不会导致颜色变差。该多羟基酚化合物包括：由下式（1）表示的双酚化合物（A）和由下式（2）表示的三酚化合物（B）： [其中 R1 代表具有 6 至 24 个碳原子的单价脂族烃基；R2、R3、R4、R5 和 R6 各代表具有 1 至 15 个碳原子的单价烃基；a、b、c、d 和 e 各代表 0 至 4 的整数] ； 其中三苯酚化合物（B）的含量（以 254 纳米波长处的吸收强度比计）小于双苯酚化合物（A）含量的 1.6%（以面积计）。
• Polyhydric phenol compound and method of producing same
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：US10851039B2

  公开（公告）日：2020-12-01

  The present invention provides a polyhydric phenol compound which has an excellent alkali resistance and which does not cause a deterioration in color even when used as a resin raw material or a color developer. The polyhydric phenol compound includes: a bisphenol compound (A) represented by the following Formula (1) and a trisphenol compound (B) represented by the following Formula (2): [wherein R1 represents a monovalent aliphatic hydrocarbon group having from 6 to 24 carbon atoms; each of R2, R3, R4, R5 and R6 represents a monovalent hydrocarbon group having from 1 to 15 carbon atoms; and each of a, b, c, d and e represents an integer from 0 to 4]; wherein the trisphenol compound (B) is contained in an amount, in terms of absorption intensity ratio at 254 nm, of less than 1.6% by area with respect to the amount of the bisphenol compound (A).

  本发明提供了一种多羟基酚化合物，它具有优异的耐碱性，即使用作树脂原料或显 色剂也不会导致颜色变差。该多羟基酚化合物包括：由下式（1）表示的双酚化合物（A）和由下式（2）表示的三酚化合物（B）： [其中 R1 代表具有 6 至 24 个碳原子的单价脂族烃基；R2、R3、R4、R5 和 R6 各代表具有 1 至 15 个碳原子的单价烃基；a、b、c、d 和 e 各代表 0 至 4 的整数]； 其中三苯酚化合物（B）的含量（以 254 纳米波长处的吸收强度比计）小于双苯酚化合物（A）含量的 1.6%（以面积计）。