N,N',N''-三(间甲苯基)-1,3,5-三嗪-2,4,6-三胺 | 82504-70-9

• 物质功能分类: 有机原料 - 氨基化合物
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: N,N',N''-三(间甲苯基)-1,3,5-三嗪-2,4,6-三胺
• 中文别名: N,N',N''-三(3-甲基苯基)-1,3,5-三嗪-2,4,6-三胺
• 英文名称: 2,4,6-Tri-(m-tolyl)-melamin
• 英文别名: 2,4,6-Tris-(m-tolylamino)-s-triazine；N,N',N''-tri-m-tolyl-[1,3,5]triazine-2,4,6-triamine；1,3,5-Triazine-2,4,6-triamine, N,N',N''-tris(3-methylphenyl)-；2-N,4-N,6-N-tris(3-methylphenyl)-1,3,5-triazine-2,4,6-triamine
• CAS: 82504-70-9
• 化学式: C₂₄H₂₄N₆
• 分子量: 396.495
• InChiKey: XMOZWTZDMACVMS-UHFFFAOYSA-N

物化性质

• 熔点：
  233°C(lit.)
• 沸点：
  601.7±65.0 °C(Predicted)
• 密度：
  1.254
• 最大波长(λmax)：
  265nm(lit.)

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  30
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  74.8
• 氢给体数：
  3
• 氢受体数：
  6

安全信息

• 危险性防范说明：
  P261,P280,P301+P312,P302+P352,P305+P351+P338
• 危险性描述：
  H302,H315,H319,H335

反应信息

• 作为产物：
  描述：

  三聚氯氰 、 3-甲基苯胺 在 碳酸氢钠 作用下， 以 1,4-二氧六环 、 N,N-二甲基甲酰胺 为溶剂， 反应 0.03h， 以95%的产率得到N,N',N''-三(间甲苯基)-1,3,5-三嗪-2,4,6-三胺
  参考文献：
  名称：

  Microwave Assisted Synthesis of 2,4,6-Triarylamino-1,3,5-triazines as Potential UV Absorbent

  摘要：

  2,4,6-Triarylamino-1,3,5-triazines was synthesized in a few minutes by reaction of cyanuric chloride with aromatic amines under microwave irradiation. This method is featured with rapid reaction, convenient operation, high yield, and clean. UV-absorption was tested for each compound.

  DOI：

  10.1081/scc-120021979

文献信息

• POLYMER FILM, RETARDATION FILM, POLARIZING PLATE, LIQUID CRYSTAL DISPLAY, AND COMPOUND
  申请人：FUJIFILM Corporation

  公开号：US20160159750A1

  公开（公告）日：2016-06-09

  Provided is a polymer film containing at least one of a compound represented by formula (1) of hydrates, solvates, or salts thereof. Y is a methine group or nitrogen atom. Q a , Q b , and Q c are a single bond or a divalent linking group. R a , R b , and R c , are hydrogen atom, alkyl group, alkenyl group, alkynyl group, aryl group, cyano group, halogen group, or heterocyclic group. X 2 is a single bond or a divalent linking group. X 1 is a single bond or a predetermined divalent linking group. R 1 and R 2 are a hydrogen atom, alkyl group, alkenyl group, alkynyl group, aryl group, or heterocyclic group Formula (1)

  提供的是一种聚合物薄膜，其中至少包含一种由式（1）表示的化合物的水合物、溶剂合物或盐类。Y是一个亚甲基基团或氮原子。Qa、Qb和Qc是单键或二价连接基团。Ra、Rb和Rc是氢原子、烷基基团、烯基基团、炔基基团、芳基、氰基、卤素基或杂环基。X2是单键或二价连接基团。X1是单键或预定的二价连接基团。R1和R2是氢原子、烷基基团、烯基基团、炔基基团、芳基或杂环基。Formula (1)
• Retardation film, method for producing the same, polarizing plate and liquid crystal display
  申请人：Inagaki Shinji

  公开号：US20070134446A1

  公开（公告）日：2007-06-14

  A method of producing a long roll retardation film comprising the sequential steps of: (a) casting a film forming material on an endless support to form a long roll film; (b) stretching the long roll film in a lateral direction of the long roll film while both edges of the long roll film are held employing a plurality of clips for each of the edges in a tenter (First Process); (c) reducing distances in the lateral direction between the clips holding the both edges of the long roll film while the edges of the long roll film are held continuously from First Process with the clips (Second Process); (d) enlarging the distances in the lateral direction between the clips holding the both edges of the long roll film while the edges of the long roll film are held continuously from Second Process with the clips (Third Process).

  一种制造长卷延迟膜的方法，包括以下步骤：(a)在无限支撑上铸造成膜形成材料，形成长卷膜;(b)在张力机上用多个夹子夹住长卷膜的两个边缘，沿长卷膜的横向方向拉伸长卷膜（第一步骤）;(c)在第一步骤中，保持夹子夹住长卷膜的两个边缘，同时减小夹子之间的横向距离（第二步骤）;(d)在第二步骤中，保持夹子夹住长卷膜的两个边缘，同时增大夹子之间的横向距离（第三步骤）。
• OPTICAL FILM, RETARDATION PLATE, ELLIPTICA POLARIZING PLATE, LIQUID CRYSTAL DISPLAY DEVICE AND COMPOUND
  申请人：HAMASAKI Ryo

  公开号：US20100239788A1

  公开（公告）日：2010-09-23

  An optical film comprising at least one compound represented by formula (1) is disclosed. In the formula, Y 11 , Y 12 and Y 13 each independently represent methine or a nitrogen atom; R 11 , R 12 and R 13 each independently represent formula (A), (B) or (C) or a hydrogen atom, provided that at least two of R 11 , R 12 and R 13 each independently represent formula (A), (B) or (C). In three formulae, L 12 , L 22 and L 32 each represent a 5 -membered heterocyclic group.

  公开了一种包含至少一种由式（1）表示的化合物的光学薄膜。在该式中，Y11、Y12和Y13分别独立表示亚甲基或氮原子；R11、R12和R13分别独立表示式（A）、（B）或（C）或氢原子，但至少有两个R11、R12和R13分别独立表示式（A）、（B）或（C）。在三个式子中，L12、L22和L32各代表一个5-成员杂环基团。
• TRANSPARENT RESIN FILM, DECORATIVE SHEET, AND METHOD FOR PRODUCING DECORATIVE SHEET
  申请人：Dai Nippon Printing Co., Ltd.

  公开号：EP3865300A1

  公开（公告）日：2021-08-18

  The present invention provides a transparent resin film excellent in weather resistance even in a case where a pattern of protrusions and depressions is formed on the surface for the purpose of imparting excellent design properties, a decorative board including the transparent resin film, and a method for producing the decorative board. Provided is a transparent resin film for protecting a picture layer on one side of a substrate, including at least: a surface protective layer; and a transparent resin layer, laminated on each other, the transparent resin film having a pattern of protrusions and depressions on a surface protective layer side, the transparent resin film having a thickness at a depression of the pattern of protrusions and depressions of 100 µm or larger, the transparent resin film containing an ultraviolet absorber.

  本发明提供了一种即使在表面形成突起和凹陷图案以赋予优异的设计特性的情况下仍具有优异耐候性的透明树脂薄膜、一种包括该透明树脂薄膜的装饰板以及一种生产该装饰板的方法。本发明提供了一种用于保护基板一侧图画层的透明树脂薄膜，该薄膜至少包括：表面保护层和透明树脂层，两者相互层压，透明树脂薄膜的表面保护层一侧具有突起和凹陷图案，透明树脂薄膜在突起和凹陷图案凹陷处的厚度为 100 µm 或更大，透明树脂薄膜含有紫外线吸收剂。
• DECORATIVE SHEET, TRANSPARENT RESIN FILM, AND DECORATIVE SHEET PRODUCTION METHOD
  申请人：Dai Nippon Printing Co., Ltd.

  公开号：EP3865299A1

  公开（公告）日：2021-08-18

  The present invention provides a decorative board capable of exhibiting excellent weather resistance even in a depression of a pattern of protrusions and depressions even in a case where the pattern of protrusions and depressions is formed on the outermost surface of a transparent resin film, a transparent resin film, and a method for producing a decorative board. Provided is a decorative board including: a substrate; a picture layer; and a transparent resin film, in a stated order in a thickness direction, the transparent resin film comprising at least a thermoplastic resin layer and having a pattern of protrusions and depressions on a side opposite to a picture layer side, the decorative board further comprising at least one layer containing an ultraviolet absorber between the picture layer and the thermoplastic resin layer.

  本发明提供了一种装饰板，即使在透明树脂薄膜的最外表面形成突起和凹陷图案的情况下，也能在突起和凹陷图案的凹陷处表现出优异的耐候性，还提供了一种透明树脂薄膜和一种生产装饰板的方法。本发明提供了一种装饰板，包括：基板；图画层；透明树脂薄膜，在厚度方向上按所述顺序排列，透明树脂薄膜至少包括热塑性树脂层，并且在与图画层相对的一面上具有突起和凹陷图案，该装饰板还包括在图画层和热塑性树脂层之间的至少一层含有紫外线吸收剂的层。