6-deoxycatalpol pentaacetate | 99500-00-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 6-deoxycatalpol pentaacetate
• CAS: 99500-00-2
• 化学式: C₂₅H₃₂O₁₄
• 分子量: 556.521
• InChiKey: SHFIGIBXBRYKNE-LLKKHWIQSA-N

反应信息

• 作为反应物：
  描述：

  6-deoxycatalpol pentaacetate 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 反应 10.0h， 以15 mg的产率得到(3R,4S,5S,6R)-2-((1S,4aR,7S,7aS)-7-Hydroxy-7-hydroxymethyl-1,4a,5,6,7,7a-hexahydro-cyclopenta[c]pyran-1-yloxy)-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol
  参考文献：
  名称：

  Studies on the constituents of Cistanchis Herba. VI. Isolation and structure of a new iridoid glycoside, 6-deoxycatalpol.

  摘要：

  Seven iridoid glycosides (I-VII) have been isolated from Cistanchis Herba, the whole plant of Cistanche salsa (C. A. MEY.) G. BECK (Orobanchaceae). The structure of a new compound, 6-deoxycatalpol (V), and the identity of the other glycosides have been established by chemical transformations and spectral analyses of the compounds and their derivatives. Mussaenosidic acid (I) was isolated for the first time as a natural product.

  DOI：

  10.1248/cpb.33.3645