dimethyl <6aR-(6aα,7β,10aβ)>-7-,10a-dimethyl-6,6a,7,8,9,10,10a-octahydro-4H-acephenanthrylene-5,7-dicarboxylate | 142452-93-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: dimethyl <6aR-(6aα,7β,10aβ)>-7-,10a-dimethyl-6,6a,7,8,9,10,10a-octahydro-4H-acephenanthrylene-5,7-dicarboxylate
• CAS: 142452-93-5
• 化学式: C₂₂H₂₆O₄
• 分子量: 354.446
• InChiKey: TYGVTJQIEANFHR-YHYVQYDKSA-N

反应信息

• 作为产物：
  描述：

  丙烯酸甲酯（MA） 、 alkaline earth salt of/the/ methylsulfuric acid 在 盐酸 、 十二/十四烷基二甲基氧化胺 作用下， 生成 dimethyl <6aR-(6aα,7β,10aβ)>-7-,10a-dimethyl-6,6a,7,8,9,10,10a-octahydro-4H-acephenanthrylene-5,7-dicarboxylate 、 methyl 2RS-<14-methylene-(methyl 7-oxopodocarpa-8,11,13-trien-19-oate)>-3-oxobutanoate
  参考文献：
  名称：

  Reactions with alkenes of η2-7-oxotetracarbonylmanganese complexes derived from diterpenoids

  摘要：

  A number of activated 7-oxotetracarbonylmanganese(I) complexes derived from podocarpic acid (1) and from dehydroabietic acid have been coupled with alkenes to give C(14) functionalised derivatives in high yields. Some coupling reactions resulted in cyclization to C(7), forming 4H-acephenanthrylene derivatives in moderate yields. Several modes of activating these manganese complexes towards coupling reactions were investigated; these included oxidative decarbonylation at room temperature, thermal promotion, and palladium-mediation.

  DOI：

  10.1016/0022-328x(92)83318-c