chiratenyl acetate | 124899-39-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: chiratenyl acetate
• 英文别名: 3β-Acetoxy-gammacer-16-ene
• CAS: 124899-39-4
• 化学式: C₃₂H₅₂O₂
• 分子量: 468.764
• InChiKey: XWFTZUFAYGHVEI-XITHCLGBSA-N

反应信息

• 作为反应物：
  描述：

  chiratenyl acetate 在 三氟化硼乙醚 作用下， 生成 Acetic acid (3S,6aR,6bS,8aR,14bR)-4,4,6a,6b,8a,9,9,14b-octamethyl-1,2,3,4,4a,5,6,6a,6b,7,8,8a,9,10,11,12,13,14,14a,14b-icosahydro-picen-3-yl ester
  参考文献：
  名称：

  Kairatenol, yet another novel migrated gammacerane triterpenoid from

  摘要：

  The structure of kairatenol (1a), the first representative of a new class of migrated gammacerane triterpenoid, has been established on the basis of spectral evidence and chemical correlations.

  DOI：

  10.1016/s0040-4039(00)77692-1
• 作为产物：
  描述：

  乙酸酐 、 chiratenol 在 吡啶 作用下， 反应 16.0h， 生成 chiratenyl acetate
  参考文献：
  名称：

  Swertane triterpenoids from Swertia chirata

  摘要：

  Two novel triterpenes belonging to swertane skeleton, besides gammacer-16-en-3-beta-ol and 21-alpha-H-hop-22(29)-en-3-beta-ol, of rare occurrence have been isolated from Swertia chirata, along with some common triterpenoids. Their structures were established on the basis of spectral and chemical evidence.

  DOI：

  10.1016/0031-9422(91)83473-x