{(1R,3R)-3-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-2,2-dimethyl-cyclopentyl}-methanol | 189267-02-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: {(1R,3R)-3-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-2,2-dimethyl-cyclopentyl}-methanol
• CAS: 189267-02-5
• 化学式: C₂₇H₄₀O₂Si
• 分子量: 424.699
• InChiKey: PIQBQYONJJGETR-WRALFONMSA-N

反应信息

• 作为反应物：
  描述：

  {(1R,3R)-3-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-2,2-dimethyl-cyclopentyl}-methanol 在 SO₂*pyridine 、 三乙胺 作用下， 以 二氯甲烷 、 二甲基亚砜 为溶剂， 生成 (1R,3R)-3-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-2,2-dimethyl-cyclopentanecarbaldehyde
  参考文献：
  名称：

  Synthesis of CD-ring modified 1α,25-dihydroxy vitamin D analogues: Five-membered D-ring analogues

  摘要：

  Vitamin D analogues characterized by the absence of a C-ring (D-ring analogues) are described. (C) 1997 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0960-894x(97)00137-6
• 作为产物：
  描述：

  tert-Butyl-[(R)-2-((R)-2,2-dimethyl-3-methylene-cyclopentyl)-propoxy]-diphenyl-silane 在 sodium hydroxide 、 9-borabicyclo[3.3.1]nonane dimer 、 双氧水 作用下， 生成 {(1R,3R)-3-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-2,2-dimethyl-cyclopentyl}-methanol
  参考文献：
  名称：

  Synthesis of CD-ring modified 1α,25-dihydroxy vitamin D analogues: Five-membered D-ring analogues

  摘要：

  Vitamin D analogues characterized by the absence of a C-ring (D-ring analogues) are described. (C) 1997 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0960-894x(97)00137-6