N-(1,2-Dimethyl-allyl)-hydrazin-N,N'-dicarbonsaeure-diethylester | 91211-89-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物
• 英文名称: N-(1,2-Dimethyl-allyl)-hydrazin-N,N'-dicarbonsaeure-diethylester
• 英文别名: ethyl N-(ethoxycarbonylamino)-N-(3-methylbut-3-en-2-yl)carbamate
• CAS: 91211-89-1
• 化学式: C₁₁H₂₀N₂O₄
• 分子量: 244.291
• InChiKey: VPLNDFYWBJRWBF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  17
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  67.9
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N-(1,2-Dimethyl-allyl)-hydrazin-N,N'-dicarbonsaeure-diethylester 在 palladium on activated charcoal 氢气 作用下， 生成 N-(1,2-Dimethyl-propyl)-hydrazin-N,N'-dicarbonsaeure-diethylester
  参考文献：
  名称：

  The Reaction of Ethyl Azodicarboxylate with Monoolefins

  摘要：

  DOI：

  10.1021/jo01031a029
• 作为产物：
  描述：

  2-甲基-2-丁烯 、 偶氮二甲酸二乙酯 在 lithium perchlorate 作用下， 以 丙酮 为溶剂， 生成 N-(1,2-Dimethyl-allyl)-hydrazin-N,N'-dicarbonsaeure-diethylester
  参考文献：
  名称：

  Solvent effect in pericyclic reactions. IX. The ene reaction.

  摘要：

  The solvent effect on the ene reactions of diethylazodicarboxylate and triazolindione was determined in 18 and 16 solvents respectively. The first enophile gives a solvent effect that depends on solvent acidity (type a solvent effect), while in the second reaction the significant solvent effect is the result of the nucleophilic character of the solvent (type b solvent effect). These are the same solvent behaviours observed in the analogous Diels-Alder cycloadditions, and evidence of the close parallel between these two pericyclic reactions was produced by determining the effect of inorganic perchlorates on their rates.

  DOI：

  10.1016/s0040-4020(01)80854-1

文献信息

• Desimoni G., Faita G., Righetti P. P., Sfulcini A., Tsyganov D., Tetrahedron, 50 (1994) N 6, S 1821-1832
  作者：Desimoni G., Faita G., Righetti P. P., Sfulcini A., Tsyganov D.

  DOI：——

  日期：——