lubimin | 35951-50-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: lubimin
• 英文别名: (3R,5S,6R,8S,10S)-8-hydroxy-6-methyl-3-prop-1-en-2-ylspiro[4.5]decane-10-carbaldehyde
• CAS: 35951-50-9
• 化学式: C₁₅H₂₄O₂
• 分子量: 236.354
• InChiKey: CEVNHRPKRNTGKO-ZSAUSMIDSA-N

物化性质

• 沸点：
  352.0±42.0 °C(Predicted)
• 密度：
  1.02±0.1 g/cm3(Predicted)
• LogP：
  3.224 (est)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  lubimin 在 platinum(IV) oxide 吡啶 、 sodium tetrahydroborate 、 氢气 作用下， 生成
  参考文献：
  名称：

  Lubimin and Oxylubimin. The Structure Elucidation

  摘要：

  The isolation and structure elucidation of lubimin (3) and oxylubimin (4), stress metabolites from diseased white potato tubers, are described.

  DOI：

  10.1246/bcsj.50.1217
• 作为产物：
  描述：

  epilubimin 在 氢氧化钾 作用下， 以 甲醇 为溶剂， 反应 0.5h， 以6 mg的产率得到lubimin
  参考文献：
  名称：

  Structure of Epilubimin, Epioxylubimin, and Isolubimin, Spirovetivane Stress Metabolites in Diseased Potato

  摘要：

  The isolation and structure elucidation of the title spirovetivane sesquiterpenes, stress metabolites produced in diseased potato tubers, are described.

  DOI：

  10.1246/bcsj.55.2424

文献信息

• OXYSOLAVETIVONE. A NEW BIOSYNTHETIC PRECURSOR OF LUBIMIN IN POTATO
  作者：Akio Murai、Yuko Yoshizawa、Nobukatsu Katsui、Shingo Sato、Tadashi Masamune

  DOI：10.1246/cl.1986.771

  日期：1986.5.5

  The title compound, isolated newly as a metabolite from solavetivone, was converted into lubimin in potato.

  该复合物是新近从索拉维酮中分离出的代谢产物，在马铃薯中转化为鲁米诺。
• Structural Confirmation of 15-Norlubiminol and 15-Norepilubiminol, Isolated from Solanum aethiopicum, by Chemical Conversion from Lubimin and Epilubimin, and their Antifungal Activity
  作者：Ayako WATANABE、Hiroaki TOSHIMA、Hiroshi NAGASE、Toshinori NAGAOKA、Teruhiko YOSHIHARA

  DOI：10.1271/bbb.65.1805

  日期：2001.1

  15-Norlubiminol and 15-norepilubiminol were obtained from Solanum aethiopicum as an inseparable 1:1 mixture in a relatively poor yield to that of the major phytoalexins, lubimin and epilubimin. Their structures were confirmed by chemical conversion starting from lubimin and epilubimin. Baeyer-Villiger oxidation of the protected lubimins with m-chloroperoxybenzoic acid provided the desired formates

  15-去甲紫罗兰醇和15-去甲紫罗兰醇从无烟茄中以不可分离的1：1混合物形式获得，其收率相对于主要植物抗毒素，鲁比敏和表柔比星的收率相对较差。通过卢比敏和表柔比明开始的化学转化证实了它们的结构。用间氯过氧苯甲酸对被保护的lubimins进行Baeyer-Villiger氧化，提供了所需的甲酸酯。用三苯基膦硒化物脱氧并随后进行甲醇分解，得到15-正氨基丁香醇，其1 H-NMR谱分别与天然15-正氨基丁香酚混合物中相应异构体的谱相同。15-去甲亚油精的抗真菌活性将比lubimins弱。
• COMPOSITIONS FOR PREVENTING PLANT DISEASE INJURY AND METHOD FOR UTILIZATION THEREOF
  申请人：Kawai, Hiroshi

  公开号：EP1120039A1

  公开（公告）日：2001-08-01

  Compositions for preventing plant disease injury which promote the formation of phytoalexin (i.e., an antibacterial substance sustained by plants per se) so as to enhance the resistance to disease injury inherent to the plants, little damage the environment and are inexpensive and highly safe. These compositions contain a mixture of at least one sulfur-containing amino acid selected from methionine, cysteine and cystine with D-glucose, These compositions are sprayed, either as such or after diluting 1 to 100,000-fold with water, onto the above-ground parts of plants. Alternatively, they are mixed directly with soil or soil is drenched with the compositions diluted 1 to 1,000,000-fold with water.

  用于预防植物病害伤害的组合物，可促进植物抗菌素（即植物本身具有的抗菌物质）的形成，从而增强植物对固有病害伤害的抵抗力，对环境破坏小，价格低廉，安全性高。这些组合物含有至少一种选自蛋氨酸、半胱氨酸和胱氨酸的含硫氨基酸与 D-葡萄糖的混合物，这些组合物可以原样或用水稀释 1 至 100,000 倍后喷洒在植物的地上部分。或者直接与土壤混合，或者用水稀释 1 至 1,000,000 倍后浸泡土壤。
• Composition for being sprayed on foliage of plant and use of the same
  申请人：Kawai, Hiroshi

  公开号：EP1216616A1

  公开（公告）日：2002-06-26

  A composition for being sprayed on the foliage of a plant, which is suspended in water so as to apply to the foliage of the plant by using a paint sprayer or the like, which provides the effects that the photodecomposition of water on the surface of the foliage is advanced, and thereby carbon dioxide assimilation in the plant can be expedited, and an oxygen free radical as produced in a process of a photodecomposition reaction of water can be used for a lipid peroxidation reaction in a plant cell membrane, and a bactericide, an insecticide, a growth regulator and/or a herbicide which are excessively left on the surface of the foliage can be decomposed; and a method of using the same can be provided. A composition for being sprayed on the foliage of a plant, comprising at least one semiconductor photocatalyst(s) as an active ingredient, wherein, if necessary, further comprises at least one carbonate(s) and/or hydrogencarbonate(s) is used. The composition is sprayed on the above-ground part of the plant.

  一种用于喷洒在植物叶片上的组合物，该组合物悬浮在水中，可使用喷漆器或类似装置喷洒在植物叶片上，其效果是促进叶片表面水的光分解反应，从而加快植物体内二氧化碳的同化作用、在水的光分解反应过程中产生的氧自由基可用于植物细胞膜的脂质过氧化反应，并可分解过量残留在叶片表面的杀菌剂、杀虫剂、生长调节剂和/或除草剂；并提供一种使用方法。一种用于喷洒在植物叶片上的组合物，包含至少一种作为活性成分的半导体光催化剂，必要时还包含至少一种碳酸盐和/或碳酸氢盐。组合物喷洒在植物的地上部分。
• GERM-RESPONSIVE PROMOTER
  申请人：Nagoya Industrial Science Research Institute

  公开号：EP1574571A1

  公开（公告）日：2005-09-14

  It is intended to provide a promoter responding specifically to germ infection ( i.e. germ-responsive promoter). Namely, a germ-responsive promoter containing DNA comprising the PVS3 promoter region (SEQ ID NO:1) of potato plant. A region (SEQ ID NO:23) being important in the promoter activity.

  其目的是提供一种对胚芽感染有特异性反应的启动子（即胚芽反应型启动子）。即含有马铃薯植物 PVS3 启动子区（SEQ ID NO:1）DNA 的芽孢反应启动子。一个区域（SEQ ID NO:23）对启动子的活性非常重要。