乙烯、丁烯、丙烯的共聚物 | 25895-47-0

• 物质功能分类: 催化剂及助剂 - 聚合物
• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 中文名称: 乙烯、丁烯、丙烯的共聚物
• 英文名称: Ethene propene 1-butene
• 英文别名: but-1-ene;ethene;prop-1-ene
• CAS: 25895-47-0
• 化学式: C9H18
• 分子量: 126.24
• InChiKey: IYYGCUZHHGZXGJ-UHFFFAOYSA-N

物化性质

• 熔点：
  137 °C
• 密度：
  0.36 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  3.58
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  乙烯 、 丁烯 反应 0.17h， 生成 乙烯、丁烯、丙烯的共聚物
  参考文献：
  名称：

  Propylene based resin composition and use thereof

  摘要：

  解决问题的方法本发明的热塑性树脂组合物（X1）包括以下成分（A1），（B1），（C1）和可选的（D1）：1至90重量％的同形异构聚丙烯（A1）; 9至98重量％的丙烯/乙烯/α-烯烃共聚物（B1），其中含有45至89摩尔％的丙烯衍生结构单元，10至25摩尔％的乙烯衍生结构单元，以及可选的0至30摩尔％的C4-C20α-烯烃衍生结构单元（a1）; 1至80重量％的苯乙烯基弹性体（C1）; 以及密度在0.850至0.910 g/cm3范围内的乙烯/α-烯烃共聚物（D1），其中（A1）+（B1）+（C1）+（D1）= 100重量％。

  公开号：

  US08592674B2

文献信息

• Process for the production of crystalline propene-ethene-butene-1
  申请人：Chemische Werke Huls Aktiengesellschaft

  公开号：US03959409A1

  公开（公告）日：1976-05-25

  In a low pressure process for the production of crystalline propene-ethene-butene-1 terpolymers with 0.2 to 10% by weight of ethene and 0.2 to 5% by weight of butene-1 with the aid of mixed catalysts of TiCl.sub.3 or TiCl.sub.3 .sup.. n AlCl.sub.3 (n = 0.2 to 0.6), and chlorine-containing organoaluminum compounds, the improvement comprising conducting the polymerization in butene-2 or in a C.sub.4 -cut containing 20-99% butene-2, containing 0.1 - 2.5% of butene-1, with the addition of 0.2 to 10% of ethene, based on the amount of propene employed.

  在低压过程中，使用混合催化剂（TiCl.sub.3或TiCl.sub.3 .sup.. n AlCl.sub.3（n = 0.2至0.6）和含氯有机铝化合物）生产含0.2至10%乙烯和0.2至5%丁烯-1的晶态丙烯-乙烯-丁烯-1三元聚合物的方法中，改进包括在含有0.1-2.5%丁烯-1的丁烯-2或C.sub.4-切割中进行聚合，其中含有20-99%丁烯-2，根据使用的丙烯量添加0.2至10%乙烯。
• Process for the multi-stage polymerization of ethene
  申请人：Chemische Werke Huels, A.G.

  公开号：US04368291A1

  公开（公告）日：1983-01-11

  In a low pressure process for polymerizing ethene using a Ziegler mixed catalyst comprising (a) a titanium compound, a vanadium compound or a mixture thereof and (b) an aluminum-organic compound or a mixture thereof, an improvement is provided wherein the process is carried out in multi-stages comprising: polymerizing, in a first polymerization stage, in the liquid phase in a dispersion medium of a C.sub.3 - to C.sub.6 -hydrocarbon, and polymerizing, in a last polymerization stage, in the gas phase.

  在使用Ziegler混合催化剂（包括（a）钛化合物，钒化合物或其混合物和（b）铝有机化合物或其混合物）的低压聚合乙烯过程中，提供了一种改进方法，其中该过程在多个阶段中进行，包括：在第一聚合阶段中，在C.sub.3至C.sub.6烃的分散介质中液相聚合，并在最后一个聚合阶段中在气相中聚合。
• Propene terpolymers with a low extractable portion
  申请人：Basell Polypropylen GmbH

  公开号：US06583253B1

  公开（公告）日：2003-06-24

  Propene terpolymers consist of from 80 to 99.5 mol % of structural units derived from propene, from 0.1 to 15 mol % of structural units derived from ethene or a C4-C6-1-olefin (I) and from 0.1 to 15 mol % of structural units derived from a further C4-C12-1-olefin (II) which is different from the C4-C6-1-olefin (I), which propene terpolymers have a proportion of regioregular ′1-2′-inserted propene units corresponding to the formula (1) [ ′ ⁢ 1 - 2 ′ ] [ ′ ⁢ 1 - 2 ′ ] + [ ′ ⁢ 2 - 1 ′ ] + [ ′ ⁢ 1 - 3 ′ ] ( 1 ) of more than 0.99, have a melting point (TM), determined from the DSC peak maximum, of less than 135° C. and a weight average molecular weight (MW) of more than 80,000 g/mol and have a xylene-soluble proportion (XS) in % by weight of the propene terpolymer which obeys the following inequality (2) XS≦1411.21 exp(−0.0591 TM[° C.])−0.05  (2).

  丙烯三元聚合物由80至99.5摩尔％的丙烯结构单元，0.1至15摩尔％的乙烯或C4-C6-1-烯（I）衍生的结构单元，以及0.1至15摩尔％的来自另一种C4-C12-1-烯（II）的结构单元组成，该烯与C4-C6-1-烯（I）不同。这些丙烯三元聚合物具有与式（1）相对应的具有regioregular ′1-2′-插入丙烯单元的比例[′⁢1-2′][′⁢1-2′]+[′⁢2-1′]+[′⁢1-3′]（1）大于0.99，熔点（TM）从DSC峰值最大值确定，小于135°C，重量平均分子量（MW）大于80,000 g/mol，并且具有丙烯三元聚合物的重量百分比的二甲苯可溶部分（XS）遵守以下不等式（2）XS≦1411.21 exp(−0.0591 TM[° C.])−0.05  (2)。
• Ethylene-alpha-olefin polymers, processes and uses
  申请人：Pennzoil-Quaker State Company

  公开号：US06262324B1

  公开（公告）日：2001-07-17

  A novel series of copolymers and terpolymers, useful as base oils for synthetic lubricants, are produced by polymerization of ethylene, an alpha-olefin, and optionally a third monomer comprising an alpha-olefin of 3 to 20 carbon atoms, in the presence of a combination catalyst comprising a compound of a transition metal of Group IVb of the Periodic Table and an aluminoxane. The copolymer or terpolymer may be further processed by thermal cracking to yield novel cracked polymers, and the cracked polymers may be hydrogenated. The copolymers or terpolymers may also be hydroisomerized. All the polymers are useful as base oils for lubricating oils and consumer products.

  一系列新型共聚物和三元聚合物，用作合成润滑油的基础油，通过在过渡金属IVb族元素化合物和铝烷氧化物的催化剂作用下，聚合乙烯、α-烯烃和可选的第三种单体，该单体包括3到20个碳原子的α-烯烃。共聚物或三元聚合物可以通过热裂解进一步加工，以产生新型的裂解聚合物，裂解聚合物可以进行氢化处理。共聚物或三元聚合物还可以进行羟基异构化。所有聚合物均可用作润滑油和消费品的基础油。
• THERMOPLASTIC RESIN COMPOSITION FOR SEALING SOLAR CELL, SHEET FOR SEALING SOLAR CELL AND SOLAR CELL
  申请人：Hoya Hiroshi

  公开号：US20100000600A1

  公开（公告）日：2010-01-07

  An object of the present invention is to provide a material used for producing a sheet for sealing a solar cell which is excellent in mechanical strength, solar cell sealing property and transparency if the material is not cross-linked. The thermoplastic resin composition of the present invention for sealing a solar cell is characterized by comprising: (A) 0 to 70 parts by weight of a propylene-based polymer having a melting point of 100° C. or higher and (B) 30 to 100 parts by weight of a propylene-based copolymer satisfying the following requisite (b); (b): MFR (230° C., load: 2.16 kg) falls in a range of 0.01 to 100 g/10 minutes, and at least one of the following requisites (b-1) and (b-2) is satisfied; (b-1): an rr fraction is 60% or more and (b-2): a structural unit derived from propylene is contained in an amount of 55 to 90 mole %, and a structural unit derived from α-olefin having 2 to 20 carbon atoms (excluding propylene) is contained in an amount of 10 to 45 mole %; and an intrinsic viscosity [η] (dL/g) measured in decalin at 135° C. and MFR described above satisfy a specific relational equation.

  本发明的目的是提供一种用于制造太阳能电池密封片的材料，如果该材料未交联，则在机械强度、太阳能电池密封性和透明度方面优异。本发明的用于密封太阳能电池的热塑性树脂组合物的特征在于包括：（A）具有100°C或更高熔点的丙烯基聚合物的0至70重量部分和（B）满足以下必要条件（b）的丙烯基共聚物的30至100重量部分；（b）：MFR（230°C，负载：2.16公斤）在0.01至100克/10分钟的范围内，且满足以下至少一个必要条件（b-1）和（b-2）之一；（b-1）：rr分数为60％或更高，（b-2）：从丙烯基衍生的结构单元的含量为55至90摩尔％，从具有2至20个碳原子（不包括丙烯）的α-烯烃衍生的结构单元的含量为10至45摩尔％；并且在135°C的十二烷基中测量的固有粘度[η]（dL/g）和上述MFR满足特定的关系式。