1,1`-二乙基-4,4`-二甲花青苷碘 | 18300-31-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 中文名称: 1,1`-二乙基-4,4`-二甲花青苷碘
• 中文别名: 1,1-二乙基-4,4-二碳花青碘
• 英文名称: 1,1'-diethyl-4,4'-dicarbocyanine iodide
• 英文别名: 1,1'-Diethyl-4,4'-pentamethinchinocyanin；1-Ethyl-4-[5-(1-ethylquinolin-1-ium-4-yl)penta-2,4-dienylidene]quinoline;iodide；1-ethyl-4-[5-(1-ethylquinolin-1-ium-4-yl)penta-2,4-dienylidene]quinoline;iodide
• CAS: 18300-31-7
• 化学式: C₂₇H₂₇N₂*I
• 分子量: 506.429
• InChiKey: XDGZLJIBGBJNTI-UHFFFAOYSA-M

物化性质

• 熔点：
  158 °C (dec.)(lit.)
• 稳定性/保质期：

  按规定使用不会分解，避免接触氧化剂和光照。

计算性质

• 辛醇/水分配系数(LogP)：
  3.16
• 重原子数：
  30
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  7.1
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• WGK Germany：
  3

反应信息

• 作为产物：
  描述：

  1-乙基-4-甲基喹啉碘 、 1-anilino-3-phenyliminopropene 在 potassium acetate 、 乙酸酐 作用下， 生成 1,1`-二乙基-4,4`-二甲花青苷碘
  参考文献：
  名称：

  Ogata, Proceedings of the Imperial Academy (Tokyo), 1932, vol. 8, p. 421

  摘要：

  DOI：

文献信息

• Heat-sensitive composition and method of making a lithographic printing form with it
  申请人：HORSELL GRAPHIC INDUSTRIES LIMITED

  公开号：EP0887182A1

  公开（公告）日：1998-12-30

  There is described coated on a lithographic base a complex of a developer-soluble phenolic resin and a compound which forms a thermally frangible complex with the phenolic resin. This complex is less soluble in the developer solution than the uncomplexed phenolic resin. However when this complex is imagewise heated the complex breaks down so allowing the non-complexed phenolic resin to be dissolved in the developing solution. Thus the solubility differential between the heated areas of the phenolic resin and the unheated areas is increased when the phenolic resin is complexed. Preferably a laser-radiation absorbing material is also present on the lithographic base. A large number of compounds which form a thermally frangible complex with the phenolic resin have been located. Examples of such compounds are quinolinium compounds, benzothiazolium compounds, pyridinium compounds and imidazoline compounds.

  在平版基底上涂布一种由可溶于显影剂的酚醛树脂和一种可与酚醛树脂形成热易碎络合物的化合物组成的复合物。这种复合物在显影液中的溶解度低于未形成复合物的酚醛树脂。然而，当这种络合物被加热成像时，络合物就会分解，从而使未络合的酚醛树脂溶解在显影液中。因此，当酚醛树脂络合时，酚醛树脂加热区域和未加热区域之间的溶解度差就会增大。平版印刷基底上最好也有激光辐射吸收材料。我们已经找到了许多能与酚醛树脂形成热易碎络合物的化合物。例如喹啉鎓化合物、苯并噻唑鎓化合物、吡啶鎓化合物和咪唑啉化合物。
• Lithographic printing forms
  申请人：——

  公开号：US20020045124A1

  公开（公告）日：2002-04-18

  Thermally imageable lithographic printing plate precursors and heat-sensitive compositions for use in these printing plate precursors are disclosed. The compositions contain an aqueous developer soluble polymer, such as a phenolic resin; a compound that reduces the aqueous developer solubility of the polymer; and optionally, and infrared absorber. Examples of compounds that reduce the aqueous developer solubility of the polymer are those that contain at least one quarternized nitrogen atom, such as quinolinium compounds, benzothiazolium compounds, pyridinium compounds, and imidazoline compounds. On thermal imaging, the irradiated areas become more soluble in the aqueous developer and can be removed to form a positive image.

  本发明公开了热成像平版印刷板原版和用于这些印刷板原版的热敏组合物。这些组合物包含水性显影剂可溶聚合物，如酚醛树脂；降低聚合物水性显影剂溶解度的化合物；以及可选的红外线吸收剂。降低聚合物水溶性显影剂溶解度的化合物包括至少含有一个四价氮原子的化合物，例如喹啉化合物、苯并噻唑化合物、吡啶化合物和咪唑啉化合物。在热成像过程中，辐照区域在水性显影液中的溶解度会增加，并可被去除以形成正像。
• Ogata; Shiozaki, Rikagaku Kenkyusho Iho, 1934, vol. 13, p. 511,517
  作者：Ogata、Shiozaki

  DOI：——

  日期：——
• HEAT-SENSITIVE COMPOSITION AND METHOD OF MAKING A LITHOGRAPHIC PRINTING FORM WITH IT
  申请人：HORSELL GRAPHIC INDUSTRIES LIMITED

  公开号：EP0825927A1

  公开（公告）日：1998-03-04
• LITHOGRAPHIC PRINTING FORM PRECURSOR AND ITS USE BY HEAT IMAGING
  申请人：Kodak Polychrome Graphics Company Ltd.

  公开号：EP0825927B1

  公开（公告）日：1999-08-11