作者:Tushar K. Chakraborty、Rajib K. Goswami
DOI:10.1016/j.tetlet.2004.08.099
日期:2004.10
Radical-mediated opening of a chiral trisubstituted epoxy alcohol using cp(2)TiCl furnished the '2-methyl-1,3-diol' moiety with the desired stereochemistry, which led to a total synthesis of (3R,4S,5S,9S)-3,5,9-trihydroxy-4-methylundecanoic acid delta-lactone 1. (C) 2004 Elsevier Ltd. All rights reserved.