2-(9,10-Dinaphthalen-2-ylanthracen-2-yl)benzo[h]quinoline | 1219973-77-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 2-(9,10-Dinaphthalen-2-ylanthracen-2-yl)benzo[h]quinoline
• CAS: 1219973-77-9
• 化学式: C₄₇H₂₉N
• 分子量: 607.754
• InChiKey: UHFBRTROMDDJEP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.4
• 重原子数：
  48
• 可旋转键数：
  3
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-溴-9,10-双(2-萘基)蒽 在 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 、 四(三苯基膦)钯 potassium acetate 、 potassium carbonate 作用下， 以 四氢呋喃 、 1,4-二氧六环 、 水 为溶剂， 反应 11.0h， 生成 2-(9,10-Dinaphthalen-2-ylanthracen-2-yl)benzo[h]quinoline
  参考文献：
  名称：

  NOVEL ANTHRACENE DERIVATIVES AND ORGANIC ELECTRONIC DEVICE USING SAME

  摘要：

  公开号：

  EP2327679B1

文献信息

• ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
  申请人：UNIVERSAL DISPLAY CORPORATION

  公开号：US20190051845A1

  公开（公告）日：2019-02-14

  A compound having a structure of the formula Ir(L A )(L B ), in which L A is a bidentate, tridentate, tetradentate, pentadentate, or hexadentate ligand and L B is a monodentate, bidentate, tridentate, or tetradentate ligand, or not present, and where the total denticity of L A plus L B is 6, and L A includes at least one structure of Formula I: is disclosed as a useful phosphorescent emitter compound.

  一种具有Ir(LA)(LB)分子结构的化合物被披露为一种有用的磷光发射剂，其中LA是双齿、三齿、四齿、五齿或六齿配体，LB是单齿、双齿、三齿或四齿配体，或者不存在，LA和LB的总配位数为6，LA至少包括一个I式结构。
• Organic Electroluminescent Materials and Devices
  申请人：Universal Display Corporation

  公开号：US20170324049A1

  公开（公告）日：2017-11-09

  The present invention includes a new series of heteroleptic iridium complexes that demonstrate high efficiency in OLED device.

  这项发明包括一系列新的杂环铱配合物，这些配合物在OLED器件中表现出高效率。
• HOST MATERIALS FOR ELECTROLUMINESCENT DEVICES
  申请人：Universal Display Corporation

  公开号：US20200190103A1

  公开（公告）日：2020-06-18

  A compound of Formula I wherein X 1 and X 2 are independently CR X or N, and at least one of X 1 or X 2 is CR X ; Y is selected from the group consisting of O, S, Se, NR′, BR′, CR′R″, and SiR′R″; R′, and R″ are each independently selected from the group consisting of alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, aryl, heteroaryl, and combinations thereof; R is selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; R A , and R C each independently represent mono to the maximum allowable substitution, or no substitution; and each R X , R A , and R C is independently a hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, and wherein any two substituents R X , R A , and R C may be optionally joined to form a ring, with the proviso that R does not join with R A to form a ring.

  公式I的化合物，其中X1和X2分别独立地为CRX或N，且X1或X2中至少有一个为CRX；Y选自O、S、Se、NR′、BR′、CR′R″和SiR′R″组成的群；R′和R″各自独立地选自烷基、环烷基、杂原子烷基、杂原子环烷基、芳基、杂芳基及其组合物的群；R选自氘、卤素、烷基、环烷基、杂原子烷基、杂原子环烷基、芳基烷基、烷氧基、芳氧基、氨基、硅基、烯基、环烯基、杂原子烯基、炔基、芳基、杂芳基、酰基、羧酸基、醚、酯、腈、异腈、硫基、亚硫基、砜基、膦基及其组合物的群；RA和RC各自独立地表示单取代至最大允许取代，或无取代；每个RX、RA和RC独立地为氢或选自氘、卤素、烷基、环烷基、杂原子烷基、杂原子环烷基、芳基烷基、烷氧基、芳氧基、氨基、硅基、烯基、环烯基、杂原子烯基、炔基、芳基、杂芳基、酰基、羧酸基、醚、酯、腈、异腈、硫基、亚硫基、砜基、膦基及其组合物的取代基，且任意两个取代基RX、RA和RC可选择性地结合形成环，但R不与RA结合形成环。
• Organic electroluminescent materials and devices
  申请人：Universal Display Corporation

  公开号：US10276809B2

  公开（公告）日：2019-04-30

  This invention discloses novel ligands for metal complexes. These ligands comprise a new side chain, namely silacycloalkane, which could increase the dopants efficiency, tune the emission color, and enhance the lifetime.

  这项发明揭示了金属配合物的新型配体。这些配体包括一个新的侧链，即硅环烷烃基，可以提高掺杂剂的效率，调节发射颜色，并增强寿命。
• ORGANIC HOST MATERIALS FOR ELECTROLUMINESCENT DEVICES
  申请人：UNIVERSAL DISPLAY CORPORATION

  公开号：US20190109286A1

  公开（公告）日：2019-04-11

  A compound of Formula I is disclosed where R A , R B , R C , and R D each independently represent mono to a maximum possible number of substitutions, or no substitution; where two of X 1 to X 4 are carbon, and the other two are nitrogen; where L is an organic linker, where R, R A , R B , R C , and R D are each independently a hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; where R D does not comprise a dibenzothiophene group; and where any adjacent substituents are optionally joined or fused into a ring.

  公开了一种Formula I的化合物，其中RA、RB、RC和RD分别独立地表示单个到最大可能数量的取代基，或者无取代基；其中X1到X4中的两个是碳，另外两个是氮；其中L是有机连接剂，其中R、RA、RB、RC和RD分别独立地是氢或从氘、卤素、烷基、环烷基、杂原子烷基、杂环烷基、芳基烷基、烷氧基、芳氧基、氨基、硅基、烯基、环烯基、杂原子烯基、炔基、芳基、杂芳基、酰基、羧酸、醚、酯、腈、异腈、硫基、亚硫基、砜基、磷基及其组合中选择的取代基；其中RD不包括二苯并噻吩基团；并且任何相邻的取代基可以选择性地连接或融合成环。