1-[3-溴-5-(三氟甲基)苯基]-2,2,2-三氟乙酮 | 1132701-00-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 1-[3-溴-5-(三氟甲基)苯基]-2,2,2-三氟乙酮
• 英文名称: 1-[3-bromo-5-(trifluoromethyl)phenyl]-2,2,2-trifluoroethanone
• 英文别名: 3'-Bromo-2,2,2-trifluoro-5'-(trifluoromethyl)acetophenone
• CAS: 1132701-00-8
• 化学式: C₉H₃BrF₆O
• 分子量: 321.017
• InChiKey: QRJHPNQWXZHJLT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  1-[3-溴-5-(三氟甲基)苯基]-2,2,2-三氟乙酮 、 1-(3-氯-4-甲基苯基)乙酮 在 三乙胺 作用下， 以 正庚烷 为溶剂， 反应 5.0h， 生成 3-[3-bromo-5-(trifluoromethyl) phenyl]-1-(3-chloro-4-methylphenyl)-4,4,4-trifluoro-3-hydroxybutane-1-one
  参考文献：
  名称：

  EP2199287

  摘要：

  公开号：
• 作为产物：
  描述：

  3-三氟甲基-A,A,A-三氟苯乙酮 在 1,3-二溴-5,5-二甲基海因 、 硫酸 作用下， 以 溶剂黄146 为溶剂， 反应 3.5h， 生成 1-[3-溴-5-(三氟甲基)苯基]-2,2,2-三氟乙酮
  参考文献：
  名称：

  EP2199287

  摘要：

  公开号：

文献信息

• [EN] METHODS OF CONTROLLING INSECTS<br/>[FR] PROCÉDÉS DE CONTRÔLE DES INSECTES
  申请人：SYNGENTA PARTICIPATIONS AG

  公开号：WO2014029708A1

  公开（公告）日：2014-02-27

  The present invention provides provides a method for controlling and/or preventing insects from the genus of Plutella in useful plants, comprising applying to a crop of useful plants, the locus thereof, or propagation material thereof, a compound of formula (I), wherein -B1-Β2-Β3- is -C=N-O-, -C=N-CH2-, or -N-CH2-CH2-; R1 is trifluoromethyl, difluoromethyl or chlorodifluoromethyl; R2 is group X X2 is C-X6 or nitrogen; X1, X3 and X6 are independently hydrogen, halogen or trihalomethyl, wherein at least one of X1, X3 and X6 is not hydrogen; A is selected from A1 to A5 Y1 is C-R6, CH or nitrogen; Y2 and Y3 are independently CH or nitrogen; wherein no more than two of Y1, Y2 and Y3 are nitrogen and wherein Y2 and Y3 are not both nitrogen; R5 is hydrogen, halogen, cyano, nitro, NH2, C1-C4alkyl, C1C4aloalkyl, C3-C5cycloalkyl, C3- C5halocycloalkyl, C1-C2alkoxy, or C1-C2haloalkoxy, preferably provided that when A is A3 or A4 R5 is not hydrogen; R6 when present together with R5 forms a -CH=CH-CH=CH- bridge; R7 is C1C4alkyl; R8 is C1-C4alkyl, C1-C4haloalkyl, C1-C4alkoxy(C1-C4)alkyl, C1-C4alkylthio(C1-C4)alkyl, C1- C4alkylsulfinyl(C1-C4)alkyl, C1-C4alkylsulfonyl(C1-C4)alkyl, C3-C6cycloalkyl, C3-C6cycloalkyl(C1-C4)alkyl-, or tetrahydrofuranyl; R9 is C1-C4alkyl, C1-C4haloalkyl, C1-C4alkyl-O-CH2-, C1-C4haloalkyl-O-CH2-,C3-C6cycloalkyl, C3-C6cycloalkyl-CH2-, C1-C4alkyl-S-CH2-, C1-C4alkyl-S(O)-CH2-, or C1-C4alkyl-S(O2)-CH2; each Z is independently halogen, C1-C12alkyl or C1-C12alkyl substituted by one to five R12, nitro, C1-C12alkoxy or C1-C12alkoxy substituted by one to five R12 cyano, C1-C12alkylsulfinyl, C1-C12alkylsulfonyl, C1-C12haloalkylsulfinyl, C1-C12haloalkylsulfonyl, hydroxyl or thiol; each R12 is halogen, cyano, nitro, hydroxy, C1-C8alkoxy-, C1-C8haloalkoxy-, mercapto, C1-C8alkylthio-, or C1-C8haloalkylthio; and k is 0, 1,2 or 3.

  本发明提供了一种用于控制和/或预防有用植物中十字花科昆虫属的昆虫的方法，包括将式(I)的化合物施用于有用植物的作物、其位点或繁殖材料，其中-B1-Β2-Β3-为-C=N-O-，-C=N-CH2-或-N-CH2-CH2-；R1为三氟甲基、二氟甲基或氯二氟甲基；R2为X的基团，X2为C-X6或氮；X1、X3和X6独立地为氢、卤素或三卤甲基，其中X1、X3和X6中至少有一个不是氢；A从A1到A5中选择，Y1为C-R6、CH或氮；Y2和Y3独立地为CH或氮；其中Y1、Y2和Y3中不超过两个是氮，且Y2和Y3不同时为氮；R5为氢、卤素、氰基、硝基、NH2、C1-C4烷基、C1-C4烷氧基、C3-C5环烷基、C3-C5卤代环烷基、C1-C2烷氧基或C1-C2卤代烷氧基，优选当A为A3或A4时R5不是氢；R6与R5一起形成一个-CH=CH-CH=CH-桥；R7为C1C4烷基；R8为C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧(C1-C4)烷基、C1-C4烷硫基(C1-C4)烷基、C1-C4烷基亚砜基(C1-C4)烷基、C1-C4烷基砜基(C1-C4)烷基、C3-C6环烷基、C3-C6环烷基(C1-C4)烷基或四氢呋喃基；R9为C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧-CH2-、C1-C4卤代烷氧-CH2-、C3-C6环烷基、C3-C6环烷基-CH2-、C1-C4烷硫-CH2-、C1-C4烷硫氧-CH2-或C1-C4烷硫氧2-CH2；每个Z独立地为卤素、C1-C12烷基或被1至5个R12取代的C1-C12烷基，硝基，C1-C12烷氧基或被1至5个R12取代的C1-C12烷氧基，氰基，C1-C12烷基亚砜基，C1-C12烷基砜基，C1-C12卤代烷基亚砜基，C1-C12卤代烷基砜基，羟基或硫醇；每个R12为卤素，氰基，硝基，羟基，C1-C8烷氧基，C1-C8卤代烷氧基，巯基，C1-C8烷硫基或C1-C8卤代烷硫基；k为0、1、2或3。
• [EN] ISOTHIAZOLINE COMPOUNDS SUBSTITUTED WITH A CARBOBICYCLIC GROUP<br/>[FR] COMPOSÉS ISOTHIAZOLINE SUBSTITUÉS PAR UN GROUPE CARBOBICYCLIQUE
  申请人：BASF SE

  公开号：WO2014206908A1

  公开（公告）日：2014-12-31

  The present invention relates to isothiazoline compounds substituted with a carbobicyclic group of formula (I) wherein the variables are as defined in the claims and description. The compounds are useful for combating or controlling invertebrate pests, in particular arthropod pests and nematodes. The invention also relates to a method for controlling invertebrate pests by using these compounds and to plant propagation material and to an agricultural and a veterinary composition comprising said compounds.

  本发明涉及一种具有化学式（I）的含有碳环族取代基的异噻唑啉化合物，其中变量如权利要求和描述中所定义。这些化合物对抗或控制无脊椎动物害虫，特别是节肢动物害虫和线虫具有用处。本发明还涉及一种利用这些化合物控制无脊椎动物害虫的方法，以及包含该化合物的植物繁殖材料、农业和兽医组合物。
• [EN] NAPHTHYL- OR ISOQUINOLINYL-SUBSTITUTED ISOTHIAZOLINE COMPOUNDS<br/>[FR] COMPOSÉS ISOTHIAZOLINE SUBSTITUÉS PAR UN GROUPE NAPHTYLE OU ISOQUINOLÉINYLE
  申请人：BASF SE

  公开号：WO2014206907A1

  公开（公告）日：2014-12-31

  The present invention relates to naphthyl-or isoquinolinyl-substituted isothiazoline compounds of formula (I) wherein the variables are as defined in the claims and description. The compounds are useful for combating or controlling invertebrate pests, in particular arthropod pests and nematodes. The invention also relates to a method for controlling invertebrate pests by using these compounds and to plant propagation material and to an agricultural and a veterinary composition comprising said compounds.

  本发明涉及公式（I）中变量如权利要求和描述中所定义的萘基或异喹啉基取代的异噻唑啉化合物。该化合物用于对抗或控制无脊椎动物害虫，特别是节肢动物害虫和线虫。本发明还涉及一种使用这些化合物来控制无脊椎动物害虫的方法，以及植物繁殖材料和包含该化合物的农业和兽医组合物。
• Isoxazoline compound and pesticide
  申请人：Nissan Chemical Industries, Ltd.

  公开号：US07947715B2

  公开（公告）日：2011-05-24

  There is provided a novel pesticide, particularly an insecticide or an acaricide. A substituted isoxazoline compound of formula (1) or a salt thereof: wherein A1, A2 and A3 independently of one another are carbon atom or nitrogen atom, G is benzene ring, etc., L is —CH2—, —C(CH3)—, —CH(CN)—, etc., X is halogen atom, C1-C6haloalkyl, etc., Y is halogen atom, C1-C6alkyl, etc., R1 is —C(O)R1a, —C(O)OR1a, —C(O)NHR1a, etc., R2 is hydrogen atom, C1-C6haloalkyl, —C1-C4alkoxy C1-C4alkyl, cyano C1-C6alkyl, C3-C6alkenyl, C3-C6alkynyl, —C(O)R15, —C(O)OR15, etc., R3 is C1-C6haloalkyl, etc., m is an integer of 0 to 5, n is an integer of 0 to 4. The pesticide containing these compounds.

  提供了一种新型杀虫剂，特别是一种杀虫剂或螨虫剂。化合物式（1）的取代异噁唑啉化合物或其盐：其中，A1、A2和A3彼此独立地是碳原子或氮原子，G是苯环等，L是-CH2-、-C(CH3)-、-CH(CN)-等，X是卤原子、C1-C6卤代烷基等，Y是卤原子、C1-C6烷基等，R1是-C（O）R1a、-C（O）OR1a、-C（O）NHR1a等，R2是氢原子、C1-C6卤代烷基、-C1-C4烷氧基C1-C4烷基、氰基C1-C6烷基、C3-C6烯基、C3-C6炔基、-C（O）R15、-C（O）OR15等，R3是C1-C6卤代烷基等，m是0至5的整数，n是0至4的整数。包含这些化合物的杀虫剂。
• ISOXAZOLINE COMPOUND AND PESTICIDE
  申请人：MITA Takeshi

  公开号：US20110172414A1

  公开（公告）日：2011-07-14

  A pesticide, particularly an insecticide or an acaricide, including a substituted isoxazoline compound of formula (1) or a salt thereof: wherein A 1 , A 2 and A 3 independently of one another are carbon atom or nitrogen atom, G is benzene ring, etc., L is —N(R 2c )—, or —CH(R 2a )N(R 2c )—, etc., X is halogen atom, C 1 -C 6 haloalkyl, etc., Y is halogen atom, C 1 -C 6 alkyl, etc., R 1 is —C(O)R 1a , —C(O)OR 1a , —C(O)NHR 1a , etc., R 2 is hydrogen atom, C 1 -C 6 haloalkyl, —C 1 -C 4 alkoxy C 1 -C 4 alkyl, cyano C 1 -C 6 alkyl, C 3 -C 6 alkenyl, C 3 -C 6 alkynyl, —C(O)R 15 , —C(O)OR 15 , etc., R 3 is C 1 -C 6 haloalkyl, etc., m is an integer of 0 to 5, n is an integer of 0 to 4. The pesticide containing these compounds.

  一种杀虫剂，特别是一种杀虫剂或杀螨剂，包括式（1）的取代异噁唑啉化合物或其盐： 其中，A1，A2和A3相互独立地是碳原子或氮原子，G是苯环等，L是—N（R2c）—或—CH（R2a）N（R2c）—等，X是卤素原子，C1-C6卤代烷基等，Y是卤素原子，C1-C6烷基等，R1是—C（O）R1a，—C（O）OR1a，—C（O）NHR1a等，R2是氢原子，C1-C6卤代烷基，—C1-C4烷氧基C1-C4烷基，氰基C1-C6烷基，C3-C6烯基，C3-C6炔基，—C（O）R15，—C（O）OR15等，R3是C1-C6卤代烷基等，m是0到5的整数，n是0到4的整数。含有这些化合物的杀虫剂。