1-methyl-2-isopropyl-cyclohexanol-(2) | 6129-90-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 1-methyl-2-isopropyl-cyclohexanol-(2)
• 英文别名: 1-Methyl-2-methoaethyl-cyclohexanol-(2)；2-Methyl-1-isopropylcyclohexanol；o-Menthan-3-ol；2-Methyl-1-(propan-2-yl)cyclohexan-1-ol；2-methyl-1-propan-2-ylcyclohexan-1-ol
• CAS: 6129-90-4
• 化学式: C₁₀H₂₀O
• 分子量: 156.268
• InChiKey: UKBWXNXBIGLPIY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-methyl-2-isopropyl-cyclohexanol-(2) 在 potassium hydrogensulfate 作用下， 生成 甲基(1-甲基乙基)-环己烯
  参考文献：
  名称：

  Kay; Perkin, Journal of the Chemical Society, 1905, vol. 87, p. 1077

  摘要：

  DOI：
• 作为产物：
  描述：

  (R,S)-1-羟基-2-甲基环己烷羧酸 在 乙醚 、 硫酸 作用下， 生成 1-methyl-2-isopropyl-cyclohexanol-(2)
  参考文献：
  名称：

  Kay; Perkin, Journal of the Chemical Society, 1905, vol. 87, p. 1077

  摘要：

  DOI：

文献信息

• The chemistry of terpenes. Part II. The physical properties of some cis–trans substituted cyclohexanes
  作者：W. Cocker、P. V. R. Shannon、P. A. Staniland

  DOI：10.1039/j39660000946

  日期：——

  The preparation of the six racemic forms of menthane is described and their n.m.r. spectra discussed. Specific chemical routes to (–)-cis- and (+)-trans-carane are described; the properties of these isomers can be explained by their stereochemistry.

  描述了六种外消旋形式的薄荷烷的制备，并讨论了其核磁共振光谱。描述了生成（-）-顺式-和（+）-反式-烷的具体化学路线；这些异构体的性质可以通过其立体化学来解释。
• A PROCESS FOR THE PRODUCTION OF A MIXTURE COMPRISING CYCLOHEXANOL AND CYCLOHEXANONE
  申请人：CAP III B.V.

  公开号：EP3115350A1

  公开（公告）日：2017-01-11

  A continuous process for the production of a mixture comprising cyclohexanone and cyclohexanol by hydrogenation of phenol, which process is performed in a multi-tubular reactor, characterised in that said multi-tubular reactor has been used for the dehydrogenation of cyclohexanol; a chemical plant suitable for the hydrogenation of phenol comprising a multi-tubular reactor; cyclohexanone prepared in a chemical plant comprising a multi-tubular reactor; and a process for constructing such a plant.

  一种通过苯酚氢化生产由环己酮和环己醇组成的混合物的连续工艺，该工艺在多管式反应器中进行，其特征在于所述多管式反应器用于环己醇的脱氢；一种适用于苯酚氢化的化工装置，包括一个多管式反应器；在包括一个多管式反应器的化工装置中制备的环己酮；以及建造这种装置的工艺。
• A PROCESS FOR THE PRODUCTION OF A MIXTURE COMPRISING CYCLOHEXANONE AND CYCLOHEXANOL
  申请人：CAP III B.V.

  公开号：EP3095774A1

  公开（公告）日：2016-11-23

  A continuous process for the production of a mixture comprising cyclohexanone and cyclohexanol by hydrogenation of phenol, which process is performed in a chemical plant comprising a multi-tubular reactor characterised in that said multi-tubular reactor has been used for the hydrogenation of benzene; a chemical plant suitable for the hydrogenation of phenol comprising a multi-tubular reactor; cyclohexanone prepared in a chemical plant comprising a multi-tubular reactor; and a process for constructing such a plant.

  一种通过苯酚氢化生产由环己酮和环己醇组成的混合物的连续工艺，该工艺在一个包括多管式反应器的化工装置中进行，其特征在于所述多管式反应器曾用于苯的氢化；一种适用于苯酚氢化的化工装置，包括一个多管式反应器；在一个包括多管式反应器的化工装置中制备环己酮；以及一种建造这种装置的工艺。
• Process for revamping a plant for the production of cyclohexanone
  申请人：CAP III B.V.

  公开号：US10130895B2

  公开（公告）日：2018-11-20

  A process for the construction of a second chemical plant, which second chemical plant is suitable for the separation of cyclohexanone from a second mixture, which second mixture comprises reaction products from the hydrogenation of phenol. The process comprises providing a first chemical plant, which first chemical plant is suitable for the separation of cyclohexanone from a first mixture, and a second chemical plant comprising a distillation column suitable for distilling overhead cyclohexanone reused from the first chemical plant.

  一种建造第二化工厂的工艺，该第二化工厂适用于从第二混合物中分离环己酮，该第二混合物包括苯酚氢化反应产物。该工艺包括提供一个第一化学工厂，该第一化学工厂适用于从第一混合物中分离环己酮；以及一个第二化学工厂，该第二化学工厂包括一个蒸馏塔，该蒸馏塔适用于蒸馏从第一化学工厂重复使用的架空环己酮。
• Peters,J.A.; van Bekkum,H., Recueil des Travaux Chimiques des Pays-Bas, 1971, vol. 90, p. 65 - 80
  作者：Peters,J.A.、van Bekkum,H.

  DOI：——

  日期：——