phenanthridin-1-ylamine | 947-63-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: phenanthridin-1-ylamine
• 英文别名: Phenanthridin-1-ylamin；1-Aminophenanthridin；Aminophenanthridine；phenanthridin-1-amine
• CAS: 947-63-7
• 化学式: C₁₃H₁₀N₂
• 分子量: 194.236
• InChiKey: PLOCPSZUSGEEMU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38.9
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  phenanthridine; nitrate 在 硫酸 、 铁粉 、 溶剂黄146 作用下， 生成 phenanthridin-1-ylamine
  参考文献：
  名称：

  Caldwell; Walls, Journal of the Chemical Society, 1952, p. 2156,2161

  摘要：

  DOI：

文献信息

• Method for Producing Aromatic and Heteroaromatic Carboxylic Acids, Carboxylic Acid Esters and Carboxylic Acid Amides
  申请人：Challand Nina

  公开号：US20110172456A1

  公开（公告）日：2011-07-14

  Process for the preparation of aromatic and heteroaromatic carboxylic acids, carboxylic acid esters and carboxamides by the reaction of aromatic or heteroaromatic halides R—X n , in which n=integer from 1 to 6, R=substituted or unsubstituted and aromatic or heteroaromatic radical and X=chlorine, bromine or iodine atom, with carbon monoxide and water, ammonia, alcohols or amines in the presence of bases and zero-valent or divalent palladium compounds and bidentate diphosphanes or complexes of zero-valent or divalent palladium with bidentate diphosphanes, in which use is made of bidentate diphosphanes (R 1 —)(R 2 —)P—Y—P(—R 3 )(—R 4 ) in which R 1 to R 4 =unsubstituted aryl radicals or aryl radicals substituted with at least one radical exhibiting a positive resonance effect or a positive inductive effect, or unsubstituted or substituted cycloalkyl radicals, and Y=hydrocarbon group with a total of 2 to 20 carbon atoms, in which at least one of the carbon atoms carries only one or no hydrogen atom as substituent; except for the reaction of 4-bromo-3-difluoromethyl-1-methylpyrazole with 2-(3,4,5-trifluorophenyl)aniline and carbon monoxide to give N-[2-(3,4,5-trifluorophenyl)phenyl]-3-difluoromethyl-1-methylpyrazole-4-carboxamide.

  用芳香或杂芳卤代烃R—Xn（其中n=1到6的整数，R=取代或未取代的芳香或杂芳基团，X=氯、溴或碘原子）与一氧化碳和水、氨、醇或胺在碱存在下，以及零价或二价钯化合物和双膦或零价或二价钯与双膦的配合物反应，制备芳香和杂芳羧酸、羧酸酯和羧酰胺的方法的过程，其中使用双膦(R1—)(R2—)P—Y—P(—R3)(—R4)，其中R1到R4=未取代芳基基团或带有至少一个正共振效应或正归纳效应的基团的取代芳基基团，或未取代或取代的环烷基基团，Y=含有2到20个碳原子的碳氢基团，其中至少一个碳原子只携带一个或没有氢原子作为取代基；但不包括4-溴-3-二氟甲基-1-甲基吡唑与2-(3,4,5-三氟苯基)苯胺和一氧化碳反应形成N-[2-(3,4,5-三氟苯基)苯基]-3-二氟甲基-1-甲基吡唑-4-羧酰胺。
• BLUE PHOSPHORESCENT IMIDAZOPHENANTHRIDINE MATERIALS
  申请人：KNOWLES David B.

  公开号：US20080297033A1

  公开（公告）日：2008-12-04

  Compounds comprising phosphorescent metal complexes comprising cyclometallated imidazo[1,2-f]phenanthridine and diimidazo[1,2-a:1′,2′-c]quinazoline ligands, or isoelectronic or benzannulated analogs thereof, are described. Organic light emitting devices comprising these compounds are also described.

  本发明涉及包含环金属化咪唑[1,2-f]菲咯啉和二咪唑[1,2-a:1′,2′-c]喹嗪配体，或其同电子或苯并环类似物的磷光金属络合物的化合物。还描述了包含这些化合物的有机发光器件。
• Process for production of vinyl chloride polymer
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP0172427A2

  公开（公告）日：1986-02-26

  This process is a process for production of a vinyl chloride polymer by suspension polymerization or emulsion polymerization of vinyl chloride monomer or a mixture of vinyl chloride monomer with a vinyl monomer copolymerizable with said vinyl chloride monomer in an aqueous medium, characterized in that the polymerization is carried out in a polymerizer, the inner wall surface and portions of the auxiliary equipment thereof which may come into contact with the monomer during polymerization being previously coated with a scaling preventive comprising at least one selected from dyes, pigments and aromatic or heterocyclic compounds having at least 5 conjugated π bonds, while controlling the chloride ion concentration in the reaction mixture to not higher than 100 ppm. According to said process, scaling onto the inner wall surface of a polymerizer, etc. during polymerization can be prevented effectively and surely.

  该工艺是通过氯乙烯单体或氯乙烯单体与可与所述氯乙烯单体共聚的乙烯基单体混合物在水介质中进行悬浮聚合或乳液聚合来生产氯乙烯聚合物的工艺，其特征在于聚合是在聚合器中进行的、内壁表面及其辅助设备中可能在聚合过程中与单体接触的部分事先涂上一层防垢剂，该防垢剂至少包括一种选自染料、颜料和至少有 5 个共轭 π 键的芳香族或杂环化合物的防垢剂，同时控制反应混合物中的氯离子浓度不高于 100 ppm。根据上述工艺，可有效、可靠地防止聚合过程中聚合器等内壁表面结垢。
• Ultrasonic apparatus and method for treating obesity or fat-deposits or for delivering cosmetic or other bodily therapy
  申请人：Tosaya A. Carol

  公开号：US20060094988A1

  公开（公告）日：2006-05-04

  Obesity or fat deposits are treated with ultrasound. In one embodiment, a waveguide-based apparatus and method are disclosed for applying ultrasound to a treatment-subject for the purpose of providing treatment or therapy for obesity, fat-deposits, cosmetic benefit or other bodily therapy tasks. In another embodiment, a novel apparatus and method are disclosed for providing at least one such treatment or therapy using a liquid-based waveguide. In yet another embodiment, a wearable apparatus is disclosed that incorporates a waveguide of the invention. Any of the embodiments has application to hospital use, clinical use or home use, for example, and the place of use will likely be determined by which treatment mechanism is employed and at what power-level.

  用超声波治疗肥胖症或脂肪沉积。在一个实施方案中，公开了一种基于波导的设备和方法，用于对治疗对象施加超声波，以治疗肥胖症、脂肪沉积、美容或其他身体治疗任务。在另一个实施方案中，公开了一种新型设备和方法，用于使用液基波导提供至少一种此类治疗或疗法。在另一个实施方案中，公开了一种包含本发明波导的可穿戴设备。任何一个实施方案都适用于医院、临床或家庭使用，例如，使用地点可能取决于采用哪种治疗机制和哪种功率水平。
• VERFAHREN ZUR HERSTELLUNG VON AROMATISCHEN UND HETEROAROMATISCHEN CARBONSÄUREN, CARBONSÄUREESTERN UND CARBONSÄUREAMIDEN
  申请人：BASF SE

  公开号：EP2282986A1

  公开（公告）日：2011-02-16