(RS)-(E)-4-methylgeraniol | 127116-08-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (RS)-(E)-4-methylgeraniol
• 英文别名: 4-Methylgeraniol；3,4,7-Trimethyl-2E,6-octadien-1-ol；(2E)-3,4,7-trimethylocta-2,6-dien-1-ol
• CAS: 127116-08-9
• 化学式: C₁₁H₂₀O
• 分子量: 168.279
• InChiKey: ZPIKDJYPRJOHLN-YRNVUSSQSA-N

物化性质

• 沸点：
  239.3±9.0 °C(Predicted)
• 密度：
  0.863±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (RS)-(E)-4-methylgeraniol 以90%的产率得到(RS)-(E)-4-methylgeranyl diphosphate
  参考文献：
  名称：

  Undecaprenyl diphosphate synthase reaction with artificial substrate homologues — novel behavior in the termination of prenyl chain elongation

  摘要：

  DOI：

  10.1016/s0040-4020(01)85127-9
• 作为产物：
  描述：

  ethyl 2-acetyl-2,5-dimethylhex-4-enoate 在 lithium aluminium tetrahydride 、 sodium chloride 作用下， 以 乙醚 、 水 、 二甲基亚砜 、 苯 为溶剂， 反应 6.0h， 生成 (RS)-(E)-4-methylgeraniol
  参考文献：
  名称：

  Undecaprenyl diphosphate synthase reaction with artificial substrate homologues — novel behavior in the termination of prenyl chain elongation

  摘要：

  DOI：

  10.1016/s0040-4020(01)85127-9

文献信息

• METHOD FOR THE PRODUCTION OF ISOPRENOIDS BY HETEROLOGOUS EXPRESSION OF A PROTEIN IN A MICROORGANISM
  申请人：DECHEMA -Forschungsinstitut

  公开号：EP3425051A1

  公开（公告）日：2019-01-09

  The present disclosure relates to a method for the production of isoprenoids by heterologous expression of a protein in a microorganism. The present disclosure relates to an alkyl transferase capable of catalyzing one or more alkylation(s) of isopentenyl-pyrophosphate. The present disclosure also relates to an alkyl transferase capable of catalyzing the one or more methylation(s) of isopentenyl-pyrophosphate and optionally the one or more isomerization(s) of isopentenyl-pyrophosphate or alkylated isopentenyl-pyrophosphate. The methyltransferase was obtained from Streptomyces monomycini.

  本公开涉及一种通过在微生物中异源表达蛋白质来生产异戊烯的方法。 本公开涉及一种能够催化异戊烯基-焦磷酸的一种或多种烷基化反应的烷基转移酶。 本公开还涉及一种烷基转移酶，它能够催化异戊烯基-焦磷酸的一种或多种甲基化反应，并可选择催化异戊烯基-焦磷酸或烷基化异戊烯基-焦磷酸的一种或多种异构化反应。 甲基转移酶是从单酵母链霉菌（Streptomyces monomycini）中获得的。
• OHNUMA, SHIN-ICHI;ITO, MICHIO;KOYAMA, TANETOSHI;OGURA, KYOZO, TETRAHEDRON, 45,(1989) N9, C. 6145-6160
  作者：OHNUMA, SHIN-ICHI、ITO, MICHIO、KOYAMA, TANETOSHI、OGURA, KYOZO

  DOI：——

  日期：——
• OGURA, KYOZO;KOYAMA, TANETOSHI;OHNUMA, SHIN-ICHI;ITO, MICHIO;JIANYU, SONG, ASAXI GARASU GIDZYUTSU KOGE SEREHJKAJ KEHNKYU XOKOKU, 55,(1989) S. 27-36
  作者：OGURA, KYOZO、KOYAMA, TANETOSHI、OHNUMA, SHIN-ICHI、ITO, MICHIO、JIANYU, SONG

  DOI：——

  日期：——
• PHEROMONDISPENSER
  申请人：BASF SE

  公开号：EP2384111A1

  公开（公告）日：2011-11-09
• PHEROMONE DISPENSER
  申请人：Harmsen Sven

  公开号：US20110266361A1

  公开（公告）日：2011-11-03

  The present invention relates to a pheromone dispenser, filled with pheromone or a pheromone-comprising liquid and comprising (a) a deep-drawn plastic film made of a thermoplastic film material and featuring at least one dish-shaped zone for receiving a pheromone, and a planar plastic film made of a thermoplastic film material and which is connected with the deep-drawn plastic film, the planar plastic film together with the at least one dish-shaped zone of the deep-drawn plastic film forming a durably sealed chamber which comprises the pheromone or the pheromone-comprising liquid, and (c) a recess in the zone of the interconnected plastic films, the planar plastic film being permeable to the pheromone. The invention also relates to a process for producing such a pheromone dispenser.