Cambridge id 5209248 | 24567-76-8

• 物质功能分类: 有机原料 - 氨基化合物 - 酰胺类化合物
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Cambridge id 5209248
• 英文别名: N-[2-(4-amino-N-ethyl-3-methylanilino)ethyl]methanesulfonamide;sulfuric acid;hydrate
• CAS: 24567-76-8；27789-88-4；74292-69-6；81608-76-6；150627-19-3
• 化学式: 2C₁₂H₂₁N₃O₂S*2H₂O*3H₂O₄S
• 分子量: 873.036
• InChiKey: QRBFSNYYMHZRGU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.52
• 重原子数：
  24
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  168
• 氢给体数：
  5
• 氢受体数：
  10

安全信息

• 危险品标志：
  Xn
• 安全说明：
  S24,S37,S60,S61
• 危险类别码：
  R22,R50/53,R43
• 危险品运输编号：
  UN 2811 6.1/PG 3

反应信息

• 作为反应物：
  描述：

  1-萘基丙二腈 、 Cambridge id 5209248 在 sodium hydroxide 、 sodium hypochlorite 作用下， 以 水 为溶剂， 反应 0.17h， 以16%的产率得到4-<4'-amino-2-methylphenylimino>-1,4-dihydronaphthylidenemalononitrile
  参考文献：
  名称：

  Kubo, Yuji; Mori, Fujio; Komatsu, Keiko, Journal of the Chemical Society. Perkin transactions I, 1988, p. 2439 - 2442

  摘要：

  DOI：

文献信息

• Photographic sensitivity increasing alkynylamine compounds and photographic elements
  申请人：EASTMAN KODAK COMPANY

  公开号：EP0665461A1

  公开（公告）日：1995-08-02

  The present invention relates to water soluble photographic sensitivity increasing alkynylamine compounds. It also relates to photographic elements containing such compounds.

  本发明涉及水溶性的增感炔胺化合物。它还涉及含有这种化合物的感光元件。
• One equivalent couplers and low pKa release dyes
  申请人：EASTMAN KODAK COMPANY

  公开号：EP0574090A1

  公开（公告）日：1993-12-15

  A photographic element containing a dye which when released from a coupler has a sufficiently low pKa, generally less than about 5, such that the dye remains substantially or fully ionized during coating of the film and in the produced film, results in an element containing a dye which has the desired hue without the use of additional additives, such as mordants, to keep the dye ionized. The dye is also useful in photographic elements without release from a coupler, for example, as a filter dye.

  一种含有染料的摄影元素，当从偶联剂中释放出来时，该染料具有足够低的pKa，一般小于约5，因此在涂布膜和生产的膜中，染料保持大部分或完全电离，从而产生一种不需要使用额外添加剂（如媒染剂）来保持染料电离的所需色调的元素。该染料在摄影元素中也可用于不从偶联剂中释放的情况，例如作为滤色镜染料。
• Photographic couplers, emulsions, materials and processes
  申请人：EASTMAN KODAK COMPANY (a New Jersey corporation)

  公开号：EP0028099A1

  公开（公告）日：1981-05-06

  Phenolic cyan dye-forming couplers of the general formula: wherein X is hydrogen or a coupling-off group and R is a ballast group, are useful in photographic emulsions, matenals and processes. The cyan dyes prepared when such couplers are reacted with oxidized aromatic primary amino colour developing agents such as p-phenylenediamines have little or no absorption in the green region of the spectrum and have relatively pure hues.

  通式为：其中 X 为氢或偶联基团，R 为镇流器基团的酚类青色染料形成耦合剂可用于感光乳剂、母料和工艺中。 当此类耦合剂与氧化芳香族伯氨基显色剂（如对苯二胺）反应时，所制备的青色染料在光谱的绿色区域几乎没有吸收，且色调相对纯正。
• Photographic elements containing novel cyan-forming colour couplers
  申请人：AGFA-GEVAERT naamloze vennootschap

  公开号：EP0037602A1

  公开（公告）日：1981-10-14

  Cyan-forming phenol type colour couplers comprising in the 2-position of the phenol a benzamido group carrying on the benzene nucleus of the benzamido group at least one -Q-Rf group wherein Q is -0-, -S-, or -S02-, and Rf is a short-chain fluorine-containing group derived from hexafluoro- propyleneortrifluorochloroethylene. These cyan-forming colour couplers can be incorporated in (a) red-sensitized silver halide emulsion layer(s) of a photographic multilayer colour element or in a non-light-sensitive colloid layer in water-permeable relationship with the red-sensitized emulsion layer(s).

  成氰型苯酚类颜色耦合剂，在苯酚的 2 位上含有一个苯甲酰胺基团，该苯甲酰胺基团的苯核上含有至少一个-Q-Rf 基团，其中 Q 是-0-、-S-或-S02-，Rf 是由六氟丙烯衍生的短链含氟基团。 这些青色形成色耦合剂可以加入摄影多层彩色元件的（a）红色感光卤化银乳剂层中，或加入与红色感光乳剂层有透水性关系的非感光胶体层中。
• 2-Equivalent yellow-forming colour couplers, their use in the production of photographic colour images, and photographic elements containing such couplers
  申请人：AGFA-GEVAERT naamloze vennootschap

  公开号：EP0030747A1

  公开（公告）日：1981-06-24

  Yellow-forming couplers of the acylacetanilide type, which carry on the methylene group between the two carbonyl groups a 1-imidazolyl coupling-off group, viz. 2-arylcarbamoyl-imidazol-1-yl, 2-alkylcarbamoyl- imidazol-1-yl, or 2-aroyl-imidazol-1-yl, more particularly colour couplers corresponding to the formula wherein Ar is phenyl or phenyl substituted by 1 to 3 substituents (same or different) such as C1-C18 alkyl, C1-C18-alkoxy, halogen, acylamido or substituted acylamido, carbamoyl or substituted carbamoyl, sulphamoyl or substituted sulphamoyl, carboxy, alkylsulphonyl, or arylsulphonyl; R' is C1-C1 a alkyl, C1-C18 alkoxy, alkoxyalkyl, cycloalkyl, heterocyclyl, oraryl, which may be substituted with alkyl, alkoxy, halogen, acyl, acylamido or substituted acylamido, carbamoyl or substituted carbamoyl, sulphamoyl or substituted sulphamoyl, sulphonamido, or carboxy; R2 and R3 are substituents used in colour coupler chemistry, which may be the same or different, or together represent the atoms necessary to complete a 5- or 6- membered unsaturated carbocyclic ring, which may be substituted; R4 is aroyl, arylcarbamoyl, or alkylcarbamoyl. These yellow-forming colour couplers can be incorporated in the blue-sensitive silver halide emulsion layer of aphotographic multilayer colour element or in a non-light-sensitive colloid layer in water-permeable relationship withthe blue-sensitive emulsion layer.

  酰基乙酰苯胺型黄色形成偶联剂，在两个羰基之间的亚甲基上带有 1-咪唑基 偶联基团，即 2-芳基氨基甲酰基-咪唑-1-基、2-烷基氨基甲酰基-咪唑-1-基 或 2-芳基-咪唑-1-基，特别是与式相应的彩色偶联剂 其中 Ar 是苯基或被 1 至 3 个取代基（相同或不同）取代的苯基，如 C1-C18 烷基、C1-C18-烷氧基、卤素、酰氨基或取代的酰氨基、氨基甲酰基或取代的氨基甲酰基、磺酰基或取代的磺酰基、羧基、烷基磺酰基或芳基磺酰基；R' 是 C1-C1 a 烷基、C1-C18 烷氧基、烷氧基烷基、环烷基、杂环烷基或芳基，可被烷基、烷氧基、卤素、酰基、酰氨基或取代的酰氨基、氨基甲酰基或取代的氨基甲酰基、磺酰基或取代的磺酰基、磺酰氨基或羧基取代；R2 和 R3 是用于颜色耦合剂化学的取代基，它们可以相同或不同，或共同代表完成 5 或 6 位不饱和碳环所需的原子，这些原子可以被取代；R4 是芳基、芳基氨基甲酰基或烷基氨基甲酰基。 这些黄色形成色耦合剂可以加入到感光多层彩色元件的蓝光卤化银乳剂层中，也可以加入到与蓝光感光乳剂层有透水性关系的非感光胶体层中。