6-(4,6-Diphenylpyrimidin-2-yl)-12,12-dimethyl-6,12-dihydro-6-azaindeno[1,2-b]fluorene | 1260249-11-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 6-(4,6-Diphenylpyrimidin-2-yl)-12,12-dimethyl-6,12-dihydro-6-azaindeno[1,2-b]fluorene
• 英文别名: 5-(4,6-Diphenylpyrimidin-2-yl)-11,11-dimethylindeno[1,2-b]carbazole
• CAS: 1260249-11-3
• 化学式: C₃₇H₂₇N₃
• 分子量: 513.641
• InChiKey: VATSYGYPFWNEIJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.4
• 重原子数：
  40
• 可旋转键数：
  3
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  30.7
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  9,9-二甲基芴-2-硼酸 在 palladium diacetate NaH 、 亚磷酸三乙酯 作用下， 以 四氢呋喃 、 1,4-二氧六环 、 N-甲基乙酰胺 、 乙醇 、 水 、 N,N-二甲基甲酰胺 、 甲苯 、 mineral oil 为溶剂， 生成 6-(4,6-Diphenylpyrimidin-2-yl)-12,12-dimethyl-6,12-dihydro-6-azaindeno[1,2-b]fluorene
  参考文献：
  名称：

  MATERIALS FOR ORGANIC ELECTROLUMINESCENT DEVICES

  摘要：

  本发明描述了新颖的茚诺芴衍生物，其可优选用作磷光掺杂剂的基质材料或作为电子传输材料，特别是用于电致发光器件的发射和/或电荷传输层。此外，该发明还涉及包含这些化合物作为结构单元的聚合物，以及根据本发明制备这些化合物的方法和包含这些化合物的电子器件。

  公开号：

  US20120097899A1

文献信息

• Organic light-emitting device
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US10020459B2

  公开（公告）日：2018-07-10

  An organic light-emitting device includes: a first electrode, a second electrode facing the first electrode, and an organic layer between the first electrode and the second electrode, the organic layer including: an emission layer, an electron transport region between the second electrode and the emission layer, and a mixed layer between the emission layer and the electron transport region, the mixed layer including a first material and a second material, the first material and the second material being selected from a pyrrolidine-based compound and a C10-C30 polycyclicaromatic hydrocarbon-based compound, and a triplet energy EgT1 of at least one selected from the first material and the second material being 2.2 eV or greater.

  一种有机发光器件包括：第一电极、面向第一电极的第二电极以及位于第一电极和第二电极之间的有机层，有机层包括：发射层、位于第二电极和发射层之间的电子传输区域以及位于发射层和电子传输区域之间的混合层：发射层，第二电极和发射层之间的电子传输区，以及发射层和电子传输区之间的混合层，混合层包括第一材料和第二材料，第一材料和第二材料选自吡咯烷基化合物和 C10-C30 多环芳烃基化合物，以及选自第一材料和第二材料的至少一种材料的三重能 EgT1 为 2.2 eV 或更高。
• Organic electroluminescent element
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：US10186665B2

  公开（公告）日：2019-01-22

  An organic electroluminescence device includes an anode, a cathode and an emitting layer, in which the emitting layer includes a first compound and a second compound and each of the first compound and the second compound is a compound emitting thermally activated delayed fluorescence.

  一种有机电致发光器件包括阳极、阴极和发光层，其中发光层包括第一种化合物和第二种化合物，第一种化合物和第二种化合物中的每一种都是发出热激活延迟荧光的化合物。
• Metal complex organic electroluminescent material and organic electroluminescent device
  申请人：SHIJIAZHUANG CHENGZHI YONGHUA DISPLAY MATERIAL CO., LTD.

  公开号：US11424418B2

  公开（公告）日：2022-08-23

  The present invention relates to an organic electroluminescent material, an organic electroluminescent device, and a method for preparing the organic electroluminescent device. Due to comprising an organic compound A with 3.0 eV>ET≥2.0 eV and a compound B of M(LA)x(LB)y(LC)z, the organic electroluminescent material of the present invention has the advantages of an increased luminescence lifetime and/or a reduced operating voltage on the basis of maintaining other electronic properties at a certain level.

  本发明涉及一种有机电致发光材料、一种有机电致发光器件和一种制备有机电致发光器件的方法。由于包含 3.0 eV>ET≥2.0 eV 的有机化合物 A 和 M(LA)x(LB)y(LC)z 的化合物 B，本发明的有机电致发光材料具有在保持其他电子特性在一定水平的基础上提高发光寿命和/或降低工作电压的优点。
• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20140084270A1

  公开（公告）日：2014-03-27

  An organic electroluminescence device includes an anode, a cathode, a first organic layer and an emitting layer including a luminescent material, in which the first organic layer and the emitting layer are interposed between the anode and the cathode in this sequence from the anode. The emitting layer contains a first material represented by the following formula (1-1) and a second material. The first organic layer contains a compound represented by the following formula (4).
• ORGANIC ELECTROLUMINESCENCE ELEMENT AND MATERIAL FOR ORGANIC ELECTROLUMINESCENCE ELEMENT
  申请人：Nishimura Kazuki

  公开号：US20140299865A1

  公开（公告）日：2014-10-09

  An organic electroluminescence device includes an anode, a cathode and at least an emitting layer interposed between the anode and the cathode. The emitting layer contains a first host material, a second host material and a phosphorescent dopant material. The first host material is a compound represented by the following formula (1). The second host material is a compound represented by the following formula (3).