A Stereoselective Hydroamination Transform To Access Polysubstituted Indolizidines
摘要:
Stereoselective, intramolecular, formal hydroamination of dienamines via directed hydroboration is reported. Four stereocenters are set in the process. Natural and unnatural indolizidine alkaloids can be synthesized from simple unsaturated amines using the title process.
A Stereoselective Hydroamination Transform To Access Polysubstituted Indolizidines
摘要:
Stereoselective, intramolecular, formal hydroamination of dienamines via directed hydroboration is reported. Four stereocenters are set in the process. Natural and unnatural indolizidine alkaloids can be synthesized from simple unsaturated amines using the title process.