C6-O-octyl-D-glucose | 210096-01-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: C6-O-octyl-D-glucose
• 英文别名: (3R,4S,5S,6R)-6-(octoxymethyl)oxane-2,3,4,5-tetrol
• CAS: 210096-01-8
• 化学式: C₁₄H₂₈O₆
• 分子量: 292.373
• InChiKey: PYAARBHPGPQQKU-RQICVUQASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  20
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  99.4
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  methyl 6-O-octyl α-D-glucopyranoside 在 甲醇 、 三氟甲磺酸酐 、 sodium methylate 、 乙酸酐 作用下， 生成 C6-O-octyl-D-glucose
  参考文献：
  名称：

  Amphiphilic and mesogenic carbohydrates - II. sysnthesis and Characterisation of mono-o-(n-alkyl)-d-glucose derivates

  摘要：

  The synthesis of various amphiphilic o-(n-alkyl)-D-glucopyranoses, having the long alkyl chain (C8H17 - C16H33) in 2-, 3-, 4- or 6-position are described. The investigations of the thermal behaviour of 6-o-(13a-e), 4-o-(14a-e), 3-o-(15a-e) and 2-o-(n-alkyl)-D-glucopyranoses (16a-e) and the corresponding methyl-alpha-D-glucosides 4a-e, 8a-e and 12a-e, respectively, are summarized in this paper.

  DOI：

  10.1016/s0040-4020(01)92248-3

文献信息

• Amphiphilic and mesogenic carbohydrates - II. sysnthesis and Characterisation of mono-o-(n-alkyl)-d-glucose derivates
  作者：Ralf Miethchen、Jens Holz、Heiko Prade、Andras Liptak

  DOI：10.1016/s0040-4020(01)92248-3

  日期：1992.4

  The synthesis of various amphiphilic o-(n-alkyl)-D-glucopyranoses, having the long alkyl chain (C8H17 - C16H33) in 2-, 3-, 4- or 6-position are described. The investigations of the thermal behaviour of 6-o-(13a-e), 4-o-(14a-e), 3-o-(15a-e) and 2-o-(n-alkyl)-D-glucopyranoses (16a-e) and the corresponding methyl-alpha-D-glucosides 4a-e, 8a-e and 12a-e, respectively, are summarized in this paper.