4,7-ditolyl-1,10-phenanthroline | 95950-12-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 4,7-ditolyl-1,10-phenanthroline
• 英文别名: 4,7-bis(4-methylphenyl)-1,10-phenanthroline；4,7-Di-(p-tolyl)-1,10-phenanthrolin；4,7-di-p-tolyl-[1,10]phenanthroline
• CAS: 95950-12-2
• 化学式: C₂₆H₂₀N₂
• 分子量: 360.458
• InChiKey: NAFLLGARQIPYJM-UHFFFAOYSA-N

物化性质

• 沸点：
  557.8±50.0 °C(Predicted)
• 密度：
  1.173±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  28
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4,7-ditolyl-1,10-phenanthroline 在 硝酸 作用下， 反应 96.0h， 生成 4,7-bis(4-carbomethoxyphenyl)-1,10-phenanthroline
  参考文献：
  名称：

  fac-三羰基铼配合物的电致变色行为

  摘要：

  本文旨在研究三羰基铼配合物的电致变色性能。使用 4,7-二苯基菲咯啉(L 1 ) 和 4,7-二(4-取代)-1,10-菲咯啉 (L 2 –L 5 ) 作为双齿配体，一系列三羰基铼配合物fac -Re(CO ) 3 (L x )Cl ( x = 1–5) 合成并通过红外光谱、1 H NMR、13 C NMR 和高分辨率质谱进行表征。通过单晶 X 射线衍射研究了它们的立体化学。fac的理论最高占据分子轨道和最低未占据分子轨道电荷分布-Re(CO) 3 (L x )Cl 通过密度泛函理论计算来计算。通过循环伏安法、紫外-可见光谱法和计时电流法研究了它们的电化学和电致变色性能。所有fac -Re(CO) 3 (L x )Cl 配合物都经历了一个准可逆的还原氧化过程，并在 1.3 V与. 银/银+。基于fac -Re(CO) 3 (L x)Cl 表现出良好的电致变色性能，例如颜色从漂白黄色状态到彩

  DOI：

  10.1039/d1nj04955k
• 作为产物：
  描述：

  3-氯-4’-甲基苯丙酮 在 磷酸 、 砷酸、原砷酸 、 tin(ll) chloride 作用下， 生成 4,7-ditolyl-1,10-phenanthroline
  参考文献：
  名称：

  Alford, Peter C.; Cook, Michael J.; Lewis, Anthony P., Journal of the Chemical Society. Perkin transactions II, 1985, p. 705 - 710

  摘要：

  DOI：

文献信息

• Electronically Neutral Metal Complexes As Biological Labels
  申请人：RUBIPY SCIENTIFIC, INC.

  公开号：US20160146826A1

  公开（公告）日：2016-05-26

  The invention relates to electronically neutral metal complexes as luminescent labels. The positive charge of the metal ion in the complex is neutralized by the negatively charged groups that are covalently linked to the nitrogen-containing diimine ligands, such as 2,2-bipyridine, 1,10-phenanthroline and their derivatives. The electronic neutrality reduces the impact of the metal complexes on the biological and/or biochemical activities of the labeled biomolecules, while the intensity of luminescent emission under electrochemical excitation is enhanced. These luminescent metal complex labels are useful in bioanalytic methodology development, with luminescence as the signal modality, such as electrochemiluminescence.

  该发明涉及作为发光标记的电子中性金属配合物。该配合物中金属离子的正电荷被共价连接到含氮双亚胺配体（如2,2-联吡啶，1,10-邻菲啰啉及其衍生物）上的带负电荷基团中和。电子中性减少了金属配合物对标记生物分子的生物和/或生化活性的影响，同时在电化学激发下增强了发光发射的强度。这些发光金属配合物标记在生物分析方法学的发展中非常有用，发光作为信号模态，如电化学发光。
• Electronically neutral metal complexes as biological labels
  申请人：Rubipy Scientific, Inc.

  公开号：US10203333B2

  公开（公告）日：2019-02-12

  The invention relates to electronically neutral metal complexes as luminescent labels. The positive charge of the metal ion in the complex is neutralized by the negatively charged groups that are covalently linked to the nitrogen-containing diimine ligands, such as 2,2-bipyridine, 1,10-phenanthroline and their derivatives. The electronic neutrality reduces the impact of the metal complexes on the biological and/or biochemical activities of the labeled biomolecules, while the intensity of luminescent emission under electrochemical excitation is enhanced. These luminescent metal complex labels are useful in bioanalytic methodology development, with luminescence as the signal modality, such as electrochemiluminescence.

  本发明涉及作为发光标签的电子中性金属配合物。络合物中金属离子的正电荷被与含氮二亚胺配体（如 2,2-联吡啶、1,10-菲罗啉及其衍生物）共价连接的带负电的基团中和。电子中性降低了金属复合物对标记生物大分子的生物和/或生化活性的影响，同时增强了电化学激发下的发光强度。这些发光金属复合物标签可用于开发以发光为信号模式（如电化学发光）的生物分析方法。
• VERTICALLY PHASE-SEPARATING SEMICONDUCTING ORGANIC MATERIAL LAYERS
  申请人：Brown Christopher T.

  公开号：US20130009137A1

  公开（公告）日：2013-01-10

  Improved OLED devices and methods of making the same using vertical phase separation to simplify processing. Vertically phase separated material can include at least one lower first layer disposed on the electrode, and at least one upper second layer different from the first layer and disposed away from the electrode or optionally on one layer comprising at least one semiconducting organic material. The first layer can be enriched with at least one first semiconducting organic material (SOM 1) and the second layer can be enriched with at least one second semiconducting organic material (SOM 2) different from the SOM 1. The ink composition can be adapted so that the film vertically phase separates into the first and second layers. Compositions and devices are also embodied herein.
• US9334373B2
  申请人：——

  公开号：US9334373B2

  公开（公告）日：2016-05-10
• US9397294B2
  申请人：——

  公开号：US9397294B2

  公开（公告）日：2016-07-19