2-methyl-1,3,5-triphenyl-pentane-1,5-dione | 10226-00-3

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物
• 英文名称: 2-methyl-1,3,5-triphenyl-pentane-1,5-dione
• 英文别名: α.ε-Dioxo-β-methyl-α.γ.ε-triphenyl-pentan；β-Phenyl-α.γ-dibenzoyl-butan；2-Methyl-1,3,5-triphenyl-pentan-1,5-dion；2-Methyl-1.3.5-triphenyl-pentandion-(1.5)；1,3,5-Triphenyl-2-methylpentandion-(1,5)；1,3,5-Triphenyl-2-methylpentan-1,5-dion；2-Methyl-1,3,5-triphenyl-1,5-pentanedione；2-methyl-1,3,5-triphenylpentane-1,5-dione
• CAS: 10226-00-3
• 化学式: C₂₄H₂₂O₂
• 分子量: 342.437
• InChiKey: XCVBREXJNRYOBA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  26
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-methyl-1,3,5-triphenyl-pentane-1,5-dione 在 90% alcohol 、 盐酸羟胺 作用下， 生成 3-甲基-2,4,6-三苯基吡啶
  参考文献：
  名称：

  Abell, Journal of the Chemical Society, 1903, vol. 83, p. 362

  摘要：

  DOI：
• 作为产物：
  描述：

  phenylmagnesium bromide 、 5-methyl-6-phenyl-(2H)-pyran-2-one 生成 2-methyl-1,3,5-triphenyl-pentane-1,5-dione
  参考文献：
  名称：

  Montillier,J.-P.; Dreux,J., Bulletin de la Societe Chimique de France, 1969, p. 3638 - 3647

  摘要：

  DOI：

文献信息

• Lithium Acetate-catalyzed Michael Reaction between Trimethylsilyl Enolate and α,β-Unsaturated Carbonyl Compound
  作者：Takashi Nakagawa、Hidehiko Fujisawa、Yuzo Nagata、Teruaki Mukaiyama

  DOI：10.1246/cl.2004.1016

  日期：2004.8

  Lithium acetate-catalyzed Michael reaction between trimethylsilyl enolates and α,β-unsaturated carbonyl compounds in DMF proceeded smoothly to afford the corresponding Michael-adducts in good to hi...

  乙酸锂催化三甲基甲硅烷基烯醇化物与DMF中的α,β-不饱和羰基化合物之间的迈克尔反应顺利进行，得到相应的迈克尔加合物。
• Sur un nouveau procede de synthese de dicetones-1,5
  作者：Yvette Maroni-Barnaud、Liliane Gorrichon-Guigon、Pierre Maroni、Jacques Bertrand

  DOI：10.1016/s0040-4039(00)72408-7

  日期：1966.1
• Synthesis of 4H-pyrans by O-cyclization of 1,5-diketones
  作者：A. F. Blinokhvatov、O. V. Markovtseva、M. N. Nikolaeva

  DOI：10.1007/bf00529364

  日期：1992.3
• Kharchenko, V. G.; Chalaya, S. N.; Litvinov, O. V., Journal of Organic Chemistry USSR (English Translation), 1984, vol. 20, # 6, p. 1098 - 1101
  作者：Kharchenko, V. G.、Chalaya, S. N.、Litvinov, O. V.、Yudovich, L. M.、Promonenkov, V. K.

  DOI：——

  日期：——
• Study of the state of rhodium in the potassium rhodiumundecatungstosilicate/alumina system by diffuse-reflectance IR spectroscopy
  作者：P. A. Korovchenko、R. A. Gazarov、L. M. Kustov

  DOI：10.1007/bf02495757

  日期：2000.7

  Adsorption of CO on the catalytic system K-5[SiW11RhO39]/Al2O3 was studied by diffuse-reflectance IR spectroscopy. The electronic state of rhodium and thermal stability of the system in the redox cycles were studied. The oxidized heteropolycompound (HPC) contains the charged forms Rh+, Rh2+, and Rh3+. Their ratio strongly depends on the pre-treatment temperature of the sample. In the reduced HPC two main forms of rhodium exist: the ionic Rh+ and metallic Rh-0. The supported HPC structure is stable in an oxidative medium at temperatures below -900 K. The properties of the K-5[SiW1 1RhO39]/Al2O3 system are retained in the redox cycles up to -670 K, and the highly dispersed state of rhodium is observed up to 900 K.