9-(2-(2-methoxyethoxy)ethyl)-3-(4-phenylquinolin-2-yl)-9H-carbazole | 1245723-80-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 9-(2-(2-methoxyethoxy)ethyl)-3-(4-phenylquinolin-2-yl)-9H-carbazole
• 英文别名: 9-[2-(2-Methoxyethoxy)ethyl]-3-(4-phenylquinolin-2-yl)carbazole；9-[2-(2-methoxyethoxy)ethyl]-3-(4-phenylquinolin-2-yl)carbazole
• CAS: 1245723-80-1
• 化学式: C₃₂H₂₈N₂O₂
• 分子量: 472.587
• InChiKey: XGGHJYHZFITOCD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  36
• 可旋转键数：
  8
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.16
• 拓扑面积：
  36.3
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  氯化铱(III) 水合物 、 9-(2-(2-methoxyethoxy)ethyl)-3-(4-phenylquinolin-2-yl)-9H-carbazole 以 乙二醇乙醚 、 水 为溶剂， 生成 di[bis[9-(2-(2-methoxyethoxy)ethyl)-3-(4-phenylquinolin-2-yl)-9H-carbazolato-N,C2']iridium(III) chloride]
  参考文献：
  名称：

  Solution-processed red iridium complexes based on carbazole-phenylquinoline main ligand: Synthesis, properties and their applications in phosphorescent organic light-emitting diodes

  摘要：

  New carbazole-phenylquinoline (CVz-PhQ) based iridium complexes were designed and synthesized for their application in red phosphorescence organic light-emitting diodes (PhOLEDs) and their photophysical, electrochemical and electroluminescence (EL) properties were investigated. The PhOLEDs were fabricated using bis[9-(2-(2-methoxyethoxy)ethyl)-3-(4-phenylquinolin-2-yl)-9H-carbazolato-N,C2']iridium 2-pyrazinecarboxylic acid (EO-CVz-PhQ)(2)Ir(prz) and bis[9-(2-(2-methoxyethoxy) ethyl)-3-(4-phenylquinolin-2-yl)-9H-carbazolato-N,C2']iridium 5-methyl-2-pyrazinecarboxylic acid (EO-CVz-PhQ)(2)Ir(mprz) as the emitter and PVK, co-doped with OXD-7 as the electron transport material and TPD as the hole transport material, as the polymer host. The red emissive PhOLEDs, based on the ITO/poly (3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS)/4,4',4 ''-tris(carbazole-9-yl)triphenylamine (TCTA)/poly(N-vinylcarbazole) (PVK):N,N'-diphenyl-N,N'-(bis(3-methylphenyl)-[1,1-biphenyl]-4,4'-diamine (TPD):1,3-bis[5-(4-tert-butylphenyl)-1,3,4-oxadiazole-2-yl]benzene (OXD-7):Ir complex/cathode configuration, exhibited a maximum external quantum efficiency of 3.68% and a maximum luminance efficiency of 6.69 cd/A. Furthermore, by introducing a TCTA interlayer, the PhOLEDs showed only a slight efficiency roll off of 5.4% from a low current density (1.81 mA/cm(2)) to a high current density (44.59 mA/cm(2)). Crown Copyright (C) 2010 Published by Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.11.016
• 作为产物：
  描述：

  1-溴-2-(2-甲氧基乙氧基)乙烷 在 aluminum (III) chloride 、 磷酸二苯酯 、 sodium hydride 、 间甲酚 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 生成 9-(2-(2-methoxyethoxy)ethyl)-3-(4-phenylquinolin-2-yl)-9H-carbazole
  参考文献：
  名称：

  Solution-processed red iridium complexes based on carbazole-phenylquinoline main ligand: Synthesis, properties and their applications in phosphorescent organic light-emitting diodes

  摘要：

  New carbazole-phenylquinoline (CVz-PhQ) based iridium complexes were designed and synthesized for their application in red phosphorescence organic light-emitting diodes (PhOLEDs) and their photophysical, electrochemical and electroluminescence (EL) properties were investigated. The PhOLEDs were fabricated using bis[9-(2-(2-methoxyethoxy)ethyl)-3-(4-phenylquinolin-2-yl)-9H-carbazolato-N,C2']iridium 2-pyrazinecarboxylic acid (EO-CVz-PhQ)(2)Ir(prz) and bis[9-(2-(2-methoxyethoxy) ethyl)-3-(4-phenylquinolin-2-yl)-9H-carbazolato-N,C2']iridium 5-methyl-2-pyrazinecarboxylic acid (EO-CVz-PhQ)(2)Ir(mprz) as the emitter and PVK, co-doped with OXD-7 as the electron transport material and TPD as the hole transport material, as the polymer host. The red emissive PhOLEDs, based on the ITO/poly (3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS)/4,4',4 ''-tris(carbazole-9-yl)triphenylamine (TCTA)/poly(N-vinylcarbazole) (PVK):N,N'-diphenyl-N,N'-(bis(3-methylphenyl)-[1,1-biphenyl]-4,4'-diamine (TPD):1,3-bis[5-(4-tert-butylphenyl)-1,3,4-oxadiazole-2-yl]benzene (OXD-7):Ir complex/cathode configuration, exhibited a maximum external quantum efficiency of 3.68% and a maximum luminance efficiency of 6.69 cd/A. Furthermore, by introducing a TCTA interlayer, the PhOLEDs showed only a slight efficiency roll off of 5.4% from a low current density (1.81 mA/cm(2)) to a high current density (44.59 mA/cm(2)). Crown Copyright (C) 2010 Published by Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.11.016