di[bis[9-(2-(2-methoxyethoxy)ethyl)-3-(4-phenylquinolin-2-yl)-9H-carbazolato-N,C2']iridium(III) chloride] | 1245730-97-5

• 英文名称: di[bis[9-(2-(2-methoxyethoxy)ethyl)-3-(4-phenylquinolin-2-yl)-9H-carbazolato-N,C2']iridium(III) chloride]
• CAS: 1245730-97-5
• 化学式: C₁₂₈H₁₀₈Cl₂Ir₂N₈O₈
• 分子量: 2341.66
• InChiKey: GHQFXQBJPDPAKL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  2-甲酸吡嗪 、 di[bis[9-(2-(2-methoxyethoxy)ethyl)-3-(4-phenylquinolin-2-yl)-9H-carbazolato-N,C2']iridium(III) chloride] 在 Na₂CO₃ 作用下， 以 乙二醇乙醚 为溶剂， 以78%的产率得到bis[9-(2-(2-methoxyethoxy)ethyl)-3-(4-phenylquinolin-2-yl)-9H-carbazolato-N,C2']iridium(III)(2-pyridinecarboxylate)
  参考文献：
  名称：

  Solution-processed red iridium complexes based on carbazole-phenylquinoline main ligand: Synthesis, properties and their applications in phosphorescent organic light-emitting diodes

  摘要：

  New carbazole-phenylquinoline (CVz-PhQ) based iridium complexes were designed and synthesized for their application in red phosphorescence organic light-emitting diodes (PhOLEDs) and their photophysical, electrochemical and electroluminescence (EL) properties were investigated. The PhOLEDs were fabricated using bis[9-(2-(2-methoxyethoxy)ethyl)-3-(4-phenylquinolin-2-yl)-9H-carbazolato-N,C2']iridium 2-pyrazinecarboxylic acid (EO-CVz-PhQ)(2)Ir(prz) and bis[9-(2-(2-methoxyethoxy) ethyl)-3-(4-phenylquinolin-2-yl)-9H-carbazolato-N,C2']iridium 5-methyl-2-pyrazinecarboxylic acid (EO-CVz-PhQ)(2)Ir(mprz) as the emitter and PVK, co-doped with OXD-7 as the electron transport material and TPD as the hole transport material, as the polymer host. The red emissive PhOLEDs, based on the ITO/poly (3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS)/4,4',4 ''-tris(carbazole-9-yl)triphenylamine (TCTA)/poly(N-vinylcarbazole) (PVK):N,N'-diphenyl-N,N'-(bis(3-methylphenyl)-[1,1-biphenyl]-4,4'-diamine (TPD):1,3-bis[5-(4-tert-butylphenyl)-1,3,4-oxadiazole-2-yl]benzene (OXD-7):Ir complex/cathode configuration, exhibited a maximum external quantum efficiency of 3.68% and a maximum luminance efficiency of 6.69 cd/A. Furthermore, by introducing a TCTA interlayer, the PhOLEDs showed only a slight efficiency roll off of 5.4% from a low current density (1.81 mA/cm(2)) to a high current density (44.59 mA/cm(2)). Crown Copyright (C) 2010 Published by Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.11.016
• 作为产物：
  描述：

  氯化铱(III) 水合物 、 9-(2-(2-methoxyethoxy)ethyl)-3-(4-phenylquinolin-2-yl)-9H-carbazole 以 乙二醇乙醚 、 水 为溶剂， 生成 di[bis[9-(2-(2-methoxyethoxy)ethyl)-3-(4-phenylquinolin-2-yl)-9H-carbazolato-N,C2']iridium(III) chloride]
  参考文献：
  名称：

  Solution-processed red iridium complexes based on carbazole-phenylquinoline main ligand: Synthesis, properties and their applications in phosphorescent organic light-emitting diodes

  摘要：

  New carbazole-phenylquinoline (CVz-PhQ) based iridium complexes were designed and synthesized for their application in red phosphorescence organic light-emitting diodes (PhOLEDs) and their photophysical, electrochemical and electroluminescence (EL) properties were investigated. The PhOLEDs were fabricated using bis[9-(2-(2-methoxyethoxy)ethyl)-3-(4-phenylquinolin-2-yl)-9H-carbazolato-N,C2']iridium 2-pyrazinecarboxylic acid (EO-CVz-PhQ)(2)Ir(prz) and bis[9-(2-(2-methoxyethoxy) ethyl)-3-(4-phenylquinolin-2-yl)-9H-carbazolato-N,C2']iridium 5-methyl-2-pyrazinecarboxylic acid (EO-CVz-PhQ)(2)Ir(mprz) as the emitter and PVK, co-doped with OXD-7 as the electron transport material and TPD as the hole transport material, as the polymer host. The red emissive PhOLEDs, based on the ITO/poly (3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS)/4,4',4 ''-tris(carbazole-9-yl)triphenylamine (TCTA)/poly(N-vinylcarbazole) (PVK):N,N'-diphenyl-N,N'-(bis(3-methylphenyl)-[1,1-biphenyl]-4,4'-diamine (TPD):1,3-bis[5-(4-tert-butylphenyl)-1,3,4-oxadiazole-2-yl]benzene (OXD-7):Ir complex/cathode configuration, exhibited a maximum external quantum efficiency of 3.68% and a maximum luminance efficiency of 6.69 cd/A. Furthermore, by introducing a TCTA interlayer, the PhOLEDs showed only a slight efficiency roll off of 5.4% from a low current density (1.81 mA/cm(2)) to a high current density (44.59 mA/cm(2)). Crown Copyright (C) 2010 Published by Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.11.016