benzyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1->4)-O-(3-O-benzyl-α-D-xylopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside | 132628-08-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: benzyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1->4)-O-(3-O-benzyl-α-D-xylopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside
• CAS: 132628-08-1
• 化学式: C₈₀H₈₄O₁₅
• 分子量: 1285.54
• InChiKey: SFHJRIKPCLXVLG-NHQGWNQHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.09
• 重原子数：
  95.0
• 可旋转键数：
  33.0
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  149.45
• 氢给体数：
  1.0
• 氢受体数：
  15.0

反应信息

• 作为反应物：
  描述：

  benzyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1->4)-O-(3-O-benzyl-α-D-xylopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside 在 palladium on activated charcoal 氢气 作用下， 以 乙二醇甲醚 为溶剂， 以85%的产率得到O-α-D-glucopyranosyl-(1->4)-O-α-D-glucopyranosyl-(1->4)-D-glucopyranose
  参考文献：
  名称：

  Synthesis of the oligosaccharides α-d-Glcp(1→4)-d-Xylp, α-d-Xylp-(1→4)-d-Glcp, α-d-Glcp-(1→4)-α-d-Glcp-(1→4)-d-Xylp, α-d-Glcp-(1→4)-α-d-Xylp-(1→4)-d-Glcp, and α-d-Xylp-(1→4)-α-d-Glcp-(1→4)-d-Glcp

  摘要：

  Syntheses are described of the disaccharides, alpha-D-Glcp-( -->4) -D-Xylp, alpha-D-Xylp-(1 --> 4)-D-Glcp, and alpha-D-Xylp-(1 --> 4)-D-Xylp, and trisaccharides, alpha-D-Glcp-(1 --> 4)-alpha-D-Glcp-(1 --> 4)-D-Xylp, alpha-D-Glcp-( --> 4)-alpha-D-Xylp-(1 --> 4)-D-Gep, and alpha-D-Xylp-(1 --> 4)-alpha-D-Glcp-(1 --> 4)-D-Glcp as analogues of glucoamylase and soybean beta-amylases substrates.

  DOI：

  10.1016/0008-6215(91)80154-f
• 作为产物：
  描述：

  氯 2,3,4,6-四-O-苄基-|á-D-吡喃葡萄糖苷 在 2,4,6-三甲基吡啶 、 silver perchlorate 、 sodium hydride 作用下， 以 乙二醇二甲醚 、 乙醚 为溶剂， 反应 5.0h， 生成 benzyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1->4)-O-(3-O-benzyl-α-D-xylopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside
  参考文献：
  名称：

  Synthesis of the oligosaccharides α-d-Glcp(1→4)-d-Xylp, α-d-Xylp-(1→4)-d-Glcp, α-d-Glcp-(1→4)-α-d-Glcp-(1→4)-d-Xylp, α-d-Glcp-(1→4)-α-d-Xylp-(1→4)-d-Glcp, and α-d-Xylp-(1→4)-α-d-Glcp-(1→4)-d-Glcp

  摘要：

  Syntheses are described of the disaccharides, alpha-D-Glcp-( -->4) -D-Xylp, alpha-D-Xylp-(1 --> 4)-D-Glcp, and alpha-D-Xylp-(1 --> 4)-D-Xylp, and trisaccharides, alpha-D-Glcp-(1 --> 4)-alpha-D-Glcp-(1 --> 4)-D-Xylp, alpha-D-Glcp-( --> 4)-alpha-D-Xylp-(1 --> 4)-D-Gep, and alpha-D-Xylp-(1 --> 4)-alpha-D-Glcp-(1 --> 4)-D-Glcp as analogues of glucoamylase and soybean beta-amylases substrates.

  DOI：

  10.1016/0008-6215(91)80154-f