6-pentyl-5-undecene | 51677-36-2

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 6-pentyl-5-undecene
• 英文别名: 6-Pentylundec-5-ene
• CAS: 51677-36-2
• 化学式: C₁₆H₃₂
• 分子量: 224.43
• InChiKey: NZVMRIGBLHSHNN-UHFFFAOYSA-N

物化性质

• 沸点：
  287.4±7.0 °C(Predicted)
• 密度：
  0.784±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  16
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  6-pentyl-5-undecene 在 palladium on activated charcoal 、 溶剂黄146 作用下， 生成 6-戊基十一烷
  参考文献：
  名称：

  Mineralogy of Tagish Lake: An ungrouped type 2 carbonaceous chondrite

  摘要：

  Abstract— In this paper we describe the recovery, handling and preliminary mineralogical investigation of the Tagish Lake meteorite. Tagish Lake is a type 2 carbonaceous chondrite which bears similarities to CI1 and CM chondrite groups, but is distinct from both. Abundant phyllosilicates as well as chondrules (however sparse) and common olivine grains in the matrix preclude any other classification. The bulk density of Tagish Lake (1.67 g/cc) is far lower than CI or CM chondrites (2.2‐2.3 and 2.6‐2.9 g/cc, respectively), or any other meteorite for that matter. We have identified two lithologies: a dominant carbonate‐poor lithology and a less‐abundant carbonate‐rich lithology. The meteorite is a breccia at all scales.We have noted similarities between Tagish Lake and some clasts within the enigmatic meteorite Kaidun; possibly there are genetic relationships here worth exploring. In the paper we describe a clast of CM1 material within Tagish Lake which is very similar to a major lithology in Kaidun.

  DOI：

  10.1111/j.1945-5100.2002.tb00852.x
• 作为产物：
  描述：

  正戊基溴化镁 在 氯化亚砜 、 sodium azide 作用下， 以 氯仿 、 N,N-二甲基甲酰胺 为溶剂， 反应 60.25h， 生成 6-pentyl-5-undecene
  参考文献：
  名称：

  Thermolysis of tertiary alkyl azides

  摘要：

  DOI：

  10.1021/ja00809a025

文献信息

• Novel ring cleavage based on intermolecular aldol condensation
  作者：Shinji Nagumo、Aki Matsukuma、Hiroshi Suemune、Kiyoshi Sakai

  DOI：10.1016/s0040-4020(01)81545-3

  日期：1993.1

  Ring cleavage and reconstruction via intramolecular aldol condensation followed by Grob fragmentation under acetalization conditions (BF3/ethylene glycol) was developed into a novel ring cleavage based on intermolecular aldol condensation. On the basis of this reaction, (R,R)-3,5-dimethylcyclohexanone was converted into the chiral straight-chain compound with syndiotactic methyl function. The ring

  通过分子内羟醛缩合的环裂解和重构，然后在乙缩醛化条件下（BF 3 /乙二醇）的Grob断裂，被开发成基于分子间羟醛缩合的新型环裂解。在该反应的基础上，将（R，R）-3，5-二甲基环己酮转化为具有间规甲基功能的手性直链化合物。还研究了基于交叉的分子间羟醛缩合的开环反应，并讨论了反应途径。
• Oxidative decarboxylation and decarbonylation of 3,3-dialkyl-2-oxo carboxylic acids and esters
  作者：Norman Rabjohn、R. M. Schwarz

  DOI：10.1021/jo00159a038

  日期：1983.6
• Church; Whitmore; McGrew, Journal of the American Chemical Society, 1934, vol. 56, p. 180,183
  作者：Church、Whitmore、McGrew

  DOI：——

  日期：——
• Synthesis of trialkylacetic acids by the anodic oxidation of 3,3-disubstituted-2-oxo carboxylic acids
  作者：Norman Rabjohn、W. L. Cranor、C. M. Schofield

  DOI：10.1021/jo00184a013

  日期：1984.5