pentane-2,4-dione sodium salt

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: pentane-2,4-dione sodium salt
• 英文别名: sodium acetylacetonate；Na(acac)；Natrium-α-acetyl-acetonat；Sodium;4-oxopentan-2-olate
• 化学式: C₅H₉O₂*Na
• 分子量: 124.115
• InChiKey: SHBGFAYIEMNFQE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.28
• 重原子数：
  8
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  40.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  tris(triphenylphosphine)ruthenium(II) chloride 、 pentane-2,4-dione sodium salt 以 乙二醇二甲醚 为溶剂， 反应 4.0h， 以70%的产率得到cis-bis(acetylacetonato)bis(triphenylphosphine)ruthenium(II)
  参考文献：
  名称：

  The ruthenium pyrazolonate complex Ru(PMIP)2(PPh3)2: Synthesis, structure, and some properties

  摘要：

  The new ruthenium(II) complex Ru(PMIP)(2)(PPh3)(2) (HPMIP is 4-isobutyryl-3-methyl-1-phe-nylpyrazol-5-one) was obtained from RuCl2(PPh3)(3) and Na(PMIP)(DME) (DME is dimethoxyethane). The structures of the complex obtained and the starting sodium pyrazolonate were determined by X-ray diffraction. The ruthenium pyrazolonate complex initiates metathetical norbornene polymerization producing high-molecular-weight polynorbornene in low yield.

  DOI：

  10.1134/s1070328412110061
• 作为产物：
  描述：

  乙酰丙酮 在 sodium hydride 作用下， 以 乙二醇二甲醚 为溶剂， 生成 pentane-2,4-dione sodium salt
  参考文献：
  名称：

  The ruthenium pyrazolonate complex Ru(PMIP)2(PPh3)2: Synthesis, structure, and some properties

  摘要：

  The new ruthenium(II) complex Ru(PMIP)(2)(PPh3)(2) (HPMIP is 4-isobutyryl-3-methyl-1-phe-nylpyrazol-5-one) was obtained from RuCl2(PPh3)(3) and Na(PMIP)(DME) (DME is dimethoxyethane). The structures of the complex obtained and the starting sodium pyrazolonate were determined by X-ray diffraction. The ruthenium pyrazolonate complex initiates metathetical norbornene polymerization producing high-molecular-weight polynorbornene in low yield.

  DOI：

  10.1134/s1070328412110061

文献信息

• Polarised phosphorescent emission in an organoplatinum(ii)-based liquid-crystalline polymer
  作者：Álvaro Díez、Stephen J. Cowling、Duncan W. Bruce

  DOI：10.1039/c2cc35085h

  日期：——

  By combination of mesogenic rod-like cycloplatinated monomers based on 2,5-di(4-alkenyloxyphenyl)pyridine ligands with 1,1,3,3,5,5-tetramethyltrisiloxane, a phosphorescent, liquid-crystalline polymer was obtained, which showed polarised emission.

  通过基于2,5-二(4-烯氧基苯基)吡啶配体的介晶棒状环铂化单体与1,1,3,3,5,5-四甲基三硅氧烷的组合，获得了一种磷光性液晶聚合物，显示出极化发射。
• Atropisomerism in linear tetrapyrroles
  作者：Stefan E Boiadjiev、David A Lightner

  DOI：10.1016/s0040-4020(02)00827-x

  日期：2002.9

  Novel bilirubin and biliverdin congeners with propionic acids replaced by o-carboxyphenyl exhibit diastereomerism due to axial chirality about the carbon–carbon single bond linking the o-carboxyphenyl group to a pyrrole ring. Evidence for atropisomerism was found even in the monopyrrole precursor, ethyl 3,5-dimethyl-4-(o-carboxyphenyl)pyrrole-2-carboxylate. Like bilirubin, o-carboxyphenyl rubin 1a

  丙酸被邻羧基苯取代的新型胆红素和胆绿素同系物由于将邻羧基苯基与吡咯环相连的碳-碳单键的轴向手性而表现出非对映异构性。甚至在单吡咯前体3,5-二甲基-4-（邻羧基苯基）吡咯-2-羧酸乙酯中也发现了对映异构现象。像胆红素一样，邻羧基苯基红素1a在非极性溶剂中也采用分子内氢键键合的脊-瓦构象。在含有旋光胺或人血清白蛋白1a的溶液中，由于其在400 nm附近的长波长吸收，显示出强烈的双信号激子偶联型诱导的圆二色性。
• Synthesis and characterization of Pt(ii) and Au(i) complexes with N-oxy-heterocyclic carbene ligands (NOHCs)
  作者：Alice Benin、Joshua Immanuel Kollar、Tim Riesebeck、Felix Wurl、Claudia Graiff、Thomas Strassner、Cristina Tubaro

  DOI：10.1039/d4dt00996g

  日期：——

  platinum(II) cyclometalated N-alkyloxyimidazol-2-ylidene complexes with β-diketonate auxiliary ligands, [(CNOHC^C*)Pt(L∩L)] (L∩L = acetyacetonate (acac) or 1,3-bis(2,4,6-trimethylphenyl)-propane-1,3-dionato (mesacac)) were synthesized and fully characterized. In addition, a Au(I) monocarbene complex was synthesized, isolated and characterized. Solid-state structures of two cyclometalated platinum(II) NOHC

  两个N-烷氧基-N′-苯基咪唑配体和相应的铂( II )环金属化N-烷氧基咪唑-2-亚叉基配合物与β-二酮辅助配体，[(C NOHC ^C*)Pt(L∩L)] (L合成并充分表征了 ∩L = 乙酰丙酮酸酯 (acac) 或 1,3-双(2,4,6-三甲基苯基)-丙烷-1,3-二酮 (mesacac))。此外，还合成、分离并表征了 Au( I ) 单卡宾络合物。获得了两种环金属化铂( II )NOHC配合物和Au( I )NOHC配合物的固态结构，提供了结构证明。
• The Reaction of Oxymercurials with Active Methylene Compounds and the Demercuration of the Resulting Mercurials with Acid and Base
  作者：Katsuhiko Ichikawa、Osamu Itoh、Takahisa Kawamura、Mutsuzo Fujiwara、Tamotsu Ueno

  DOI：10.1021/jo01340a023

  日期：1966.2