Dichloroindiganylmethyl(trimethyl)silane | 132080-08-1

• 分子结构分类: 有机化合物 - 有机金属化合物 - 金属烷基卤化物
• 英文名称: Dichloroindiganylmethyl(trimethyl)silane
• CAS: 132080-08-1
• 化学式: C₄H₁₁Cl₂InSi
• 分子量: 272.943
• InChiKey: JMJWFUYGTCTCGE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.83
• 重原子数：
  8
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  氘代3-氨基-5-吗啉-4-甲基-恶唑-2-啉酮 、 Dichloroindiganylmethyl(trimethyl)silane 以 正戊烷 为溶剂， 以86%的产率得到
  参考文献：
  名称：

  Binuclear pyrazolato-bridged organoplatinum(II) complexes: synthesis and characterization

  摘要：

  DOI：

  10.1016/0022-328x(93)80110-w

文献信息

• Indium compounds that contain two different organic substituents. Crystal structure of [In(CH2CMe3)(CH2SiMe3)Cl]2. An interesting case of partial ligand disorder in the solid state
  作者：O. T. Beachley、John D. Maloney、Melvyn Rowen Churchill、Charles H. Lake

  DOI：10.1021/om00056a029

  日期：1991.10

  Three new indium compounds containing two different organic substituents, In(CH2CMe3)(CH2SiMe3)Cl, In(CH2CMe3)(C6H5)Cl, and (Me3CCH2)(Me3SiCH2)InPEt2, have been prepared, purified, and characterized. All compounds were characterized by partial elemental analysis (C, H, and P as appropriate), cryoscopic molecular weight studies in benzene solution, and NMR and IR spectroscopic studies. All compounds exist as dimeric molecules in solution. NMR spectral data were consistent with the presence of mixtures of cis and trans isomers in solution. [In(CH2CMe3)(CH2SiMe3)Cl]2 crystallizes in the centrosymmetric triclinic space group P1BAR (C(i)1, No. 2) with a = 6.1000 (10) angstrom, b = 10.337 (3) angstrom, c = 12.190 (3) angstrom, alpha = 77.28 (2)-degrees, beta = 84.41 (2)-degrees, gamma = 84.50 (2)-degrees, V = 744.0 (3) angstrom 3, and Z = 1. Diffraction data (Mo K-alpha, 2-theta = 5-50-degrees) were collected on a Siemens R3m/V automated four-circle diffractometer, and the structure was solved and refined to R = 5.39% and R(w) = 7.65% for those 1752 unique data with \F(o)\ > 4-sigma(\F(o)\) (R = 8.30% for all 2629 data). Distances within the centrosymmetric dimeric molecule in the trans conformation include In-CH2CMe3 = 2.140 (13) angstrom, In-CH2SiMe3 = 2.125 (12) angstrom, and In-Cl (bridging) = 2.572 (3) and 2.659 (3) angstrom. There is some slight disorder of CH2CMe3 and CH2SiMe3 ligands (approximately 73%:27%), and there are weak intermolecular In...Cl interactions at 3.528 (3) angstrom along the a-direction. Attempts to prepare the related organogallium compounds, Ga(Me)(CH2CMe3)Cl and Ga(CH2CMe3)(CH2CMe2Ph)Cl, were unsuccessful. Ligand redistribution reactions led to the formation and subsequent isolation of mixtures of the appropriate symmetrized products.
• Merzweiler, Kurt; Brands, Ludwig; Spohn, Juergen, Zeitschrift fur Naturforschung, B: Chemical Sciences, 1993, vol. 48, # 10, p. 1315 - 1320
  作者：Merzweiler, Kurt、Brands, Ludwig、Spohn, Juergen

  DOI：——

  日期：——
• Binuclear pyrazolato-bridged organoplatinum(II) complexes: synthesis and characterization
  作者：Anshu Singhal、Vimal K. Jain、S. Kannan

  DOI：10.1016/0022-328x(93)80110-w

  日期：1993.5