氯化二乙基铟 | 14774-82-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 金属烷基卤化物
• 中文名称: 氯化二乙基铟
• 英文名称: diethylindium chloride
• CAS: 14774-82-4
• 化学式: C₄H₁₀ClIn
• 分子量: 208.396
• InChiKey: PNZJBDPBPVHSKL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.26
• 重原子数：
  6
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  氯化二乙基铟 、 2-(N,N-dimethylaminomethyl)phenyllithium 以 正戊烷 为溶剂， 以57%的产率得到(o-{(dimethylamino)methyl}phenyl)diethylindium
  参考文献：
  名称：

  Schumann, Herbert; Hartmann, Uwe; Wassermann, Wilfried, Chemische Berichte, 1990, vol. 123, p. 2093 - 2100

  摘要：

  DOI：
• 作为产物：
  描述：

  乙基氯化镁 、 氯化铟 以 乙醚 、 正己烷 为溶剂， 以100%的产率得到氯化二乙基铟
  参考文献：
  名称：

  Diethylindium(III) derivatives: Synthesis and characterization of diethylindium(III) dialkylamides and diethylindium(III) pyrrolide. X-Ray crystal structures of diethylindium(III) pyrrolide and diethylindium(III) bromide

  摘要：

  The compounds Et2InNR2 (R = Me, Et, or SiMe3) and Et2InPyrr (HPyrr = pyrrole) have been prepared by reaction of Et2InCl with the corresponding lithium amide or pyrrolide in diethylether. Their H-1 NMR, IR and mass spectra are reported and discussed. The amides are dimers in the vapour phase. Diethylindium bromide is a layer polymer. The octahedral coordination geometry of indium is characterized by four distinct In-Br distances ranging from 2,777(2) to 3.848(2) angstrom. Diethylindium pyrrolide has a chain structure as shown by the relatively short intermolecular interactions between each indium atom and the double bonds of two adjacent different pyrrole units (3.063(5) and 2.950(5) angstrom, respectively). The indium coordination geometry is then trigonal bipyramidal, with the shortest bonds in the equatorial plane (In-C(5) 2.143(5) angstrom, In-C(7) 2.141(5) angstrom, In-N 2.166(4) angstrom).

  DOI：

  10.1016/0022-328x(92)85001-d

文献信息

• Preparation of [Et2InSb(SiMe3)2]3; a trimeric single-source precursor to indium antimonide
  作者：Edward E Foos、Richard J Jouet、Richard L Wells、Peter S White

  DOI：10.1016/s0022-328x(99)00674-9

  日期：2000.3

  The 1:1 mole ratio reaction of Et2InCl with Sb(SiMe3)3 results in the formation of [Et2InSb(SiMe3)2]3 (1), a trimeric compound containing a six-membered indium–antimony ring. An X-ray crystal structure has been obtained for the compound substantiating the trimeric nature of 1 in the solid state, however variable-temperature 1H-NMR studies show a dimer/trimer equilibrium for this species in solution

  Et 2 InCl与Sb（SiMe 3）3的1：1摩尔比反应导致形成[Et 2 InSb（SiMe 3）2 ] 3（1），这是一种含有六元铟-锑环的三聚体化合物。对于固态的1的三聚体化合物，已获得X射线晶体结构，但是可变温度1 H-NMR研究表明，该物种在溶液中具有二聚体/三聚体平衡。初步的热解研究证明了其在纳米晶体InSb形成中的效用。
• Organometallic compounds
  申请人：Merck Patent Gesellschaft Beschrankter Haftung

  公开号：US05259915A1

  公开（公告）日：1993-11-09

  The invention relates to organometallic compounds of the elements aluminum, gallium and indium which are two-fold intramolecularly stabilized, and to the use thereof for the production of thin films and epitaxial layers by deposition from the liquid or solid phase.

  本发明涉及元素铝、镓和铟的有机金属化合物，这些化合物经过两倍分子内稳定，并且用于通过从液态或固态沉积来生产薄膜和外延层的制备。
• Schumann, Herbert; Hartmann, Uwe; Wassermann, Wilfried, Chemische Berichte, 1991, vol. 124, p. 1567 - 1570
  作者：Schumann, Herbert、Hartmann, Uwe、Wassermann, Wilfried

  DOI：——

  日期：——
• Zur Chemie des Tris(trimethylstannyl) amins. Die Kristallstrukturen von [Me3InN(SnMe3) 3] and [RCllnN(SnMe3) 2]2 mit R  Methyl und Ethyl
  作者：Ralf Hillwig、Klaus Harms、Kurt Dehnicke

  DOI：10.1016/0022-328x(95)05706-u

  日期：1995.10

  The trimethylmetals MMe(3) of Al, Ga, and In react with tris(trimethylstaanyl)amine in diethyl ether, forming the donor-acceptor complexes [Me(3)M-N(SnMe(3))(2)], which are characterized by IR spectroscopy. According to the crystal structure analysis of the indium compound the N atom is coordinated by the three sn atoms and by the indium atom in a distorted tetrahedral fashion. The bond lengths are Sn-N 210.2 pm and In-N 239 pm. N(SnMe(3))(3) reacts with R(2)InCl (R = Me, Et) under cleavage of SnMe(4) and formation of the centrosymmetric dimeric complexes [RClIn-N(SnMe(3))(2)](2) with In-N distances of 219.5 pm.
• Novel intramolecularly stabilized organogallium and organoindium compounds and their use in MOVPE
  作者：Herbert Schumann、Uwe Hartmann、Wilfried Wassermann

  DOI：10.1016/s0277-5387(00)80590-2

  日期：1990.1