1,3-diphenylhexane | 73476-00-3

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物
• 英文名称: 1,3-diphenylhexane
• 英文别名: 1-n-Propyl-1,3-diphenyl-propan；1,1'-(Hexane-1,3-diyl)dibenzene；1-phenylhexan-3-ylbenzene
• CAS: 73476-00-3
• 化学式: C₁₈H₂₂
• 分子量: 238.373
• InChiKey: AFOYJWZLSSXZNG-UHFFFAOYSA-N

物化性质

• 沸点：
  197 °C(Press: 17 Torr)
• 密度：
  0.954±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  苯乙烯 、 magnesium-cyclopentane 在 盐酸 、 二氯二茂锆 作用下， 生成 丁苯 、 1,3-diphenylhexane
  参考文献：
  名称：

  Catalytic synthesis and transformations of magnesium-cycloalkanes. 1. New catalytic transformations in the series of magnesium-cyclopentanes

  摘要：

  The reactions of magnesium-cyclopentane with styrene and of 2,4-diphenylmagnesium-cyclopentane with ethylene in the presence of catalytic amounts of Cp2ZrCl2 leading to the formation of 2-phenylmagnesium-cyclopentane and 2,4-diphenylmagnesium-cycloheptane, were studied for the first time. It was found that ziroconocyclopentanes, are intermediates in this reaction, which are formed both from magnesium-cycloalkanes and from alpha-olefins and Cp2ZrCl2. A possible mechanism of the reactions studied has been proposed.

  DOI：

  10.1007/bf00961303

文献信息

• DZHEMILEV, U. M.;SULTANOV, R. M.;GAJMALDINOV, R. G.;TOLSTIKOV, G. A., IZV. AN CCCP. CEP. XIM.,(1991) N, S. 1388-1393
  作者：DZHEMILEV, U. M.、SULTANOV, R. M.、GAJMALDINOV, R. G.、TOLSTIKOV, G. A.

  DOI：——

  日期：——
• Catalytic synthesis and transformations of magnesium-cycloalkanes. 1. New catalytic transformations in the series of magnesium-cyclopentanes
  作者：U. M. Dzhemilev、R. M. Sultanov、R. G. Gaimaldinov、G. A. Tolstikov

  DOI：10.1007/bf00961303

  日期：1991.6

  The reactions of magnesium-cyclopentane with styrene and of 2,4-diphenylmagnesium-cyclopentane with ethylene in the presence of catalytic amounts of Cp2ZrCl2 leading to the formation of 2-phenylmagnesium-cyclopentane and 2,4-diphenylmagnesium-cycloheptane, were studied for the first time. It was found that ziroconocyclopentanes, are intermediates in this reaction, which are formed both from magnesium-cycloalkanes and from alpha-olefins and Cp2ZrCl2. A possible mechanism of the reactions studied has been proposed.