(3R)-3,7-dimethyl-6-octenyl(dimethyl)amine | 1190601-79-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (3R)-3,7-dimethyl-6-octenyl(dimethyl)amine
• 英文别名: (3R)-N,N,3,7-tetramethyloct-6-en-1-amine
• CAS: 1190601-79-6
• 化学式: C₁₂H₂₅N
• 分子量: 183.337
• InChiKey: GNBZURGQKQIDSP-GFCCVEGCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (3R)-3,7-dimethyl-6-octenyl(dimethyl)amine 、 2-溴丙烷 以 乙腈 为溶剂， 反应 12.0h， 以40%的产率得到(3R)-3,7-dimethyl-6-octenyl(isopropyl)dimethylammonium bromide
  参考文献：
  名称：

  Terpenes to Ionic Liquids: Synthesis and Characterization of Citronellal-Based Chiral Ionic Liquids

  摘要：

  A series of new chiral ionic liquids have been prepared and characterized starting from a simple, economical, and commercially available monoterpene, citronellal. The aldehyde functionality in citronellal is converted into a Schiff base using an amine, followed by reduction with Raney nickel to give the desired quaternary amine. Most of the ionic liquids generated using this procedure are found to be liquids at room temperature.

  DOI：

  10.1080/00397910902768226
• 作为产物：
  描述：

  (+)-香茅醛 、 二甲胺 在 氢气 作用下， 以 甲醇 、 水 为溶剂， 反应 20.0h， 以70%的产率得到(3R)-3,7-dimethyl-6-octenyl(dimethyl)amine
  参考文献：
  名称：

  Terpenes to Ionic Liquids: Synthesis and Characterization of Citronellal-Based Chiral Ionic Liquids

  摘要：

  A series of new chiral ionic liquids have been prepared and characterized starting from a simple, economical, and commercially available monoterpene, citronellal. The aldehyde functionality in citronellal is converted into a Schiff base using an amine, followed by reduction with Raney nickel to give the desired quaternary amine. Most of the ionic liquids generated using this procedure are found to be liquids at room temperature.

  DOI：

  10.1080/00397910902768226

文献信息

• Terpenes to Ionic Liquids: Synthesis and Characterization of Citronellal-Based Chiral Ionic Liquids
  作者：D. Nageshwar、D. Muralimohan Rao、Palle V. R. Acharyulu

  DOI：10.1080/00397910902768226

  日期：2009.8.20

  A series of new chiral ionic liquids have been prepared and characterized starting from a simple, economical, and commercially available monoterpene, citronellal. The aldehyde functionality in citronellal is converted into a Schiff base using an amine, followed by reduction with Raney nickel to give the desired quaternary amine. Most of the ionic liquids generated using this procedure are found to be liquids at room temperature.