1,1-bis[4-carboxyphenyl]ethene | 83210-85-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 1,1-bis[4-carboxyphenyl]ethene
• 英文别名: 4,4'-vinylidene-di-benzoic acid；4,4'-Vinyliden-di-benzoesaeure；4,4'-(Ethene-1,1-diyl)dibenzoic acid；4-[1-(4-carboxyphenyl)ethenyl]benzoic acid
• CAS: 83210-85-9
• 化学式: C₁₆H₁₂O₄
• 分子量: 268.269
• InChiKey: LVFLRPDXMINWBT-UHFFFAOYSA-N

物化性质

• 熔点：
  287-288 °C
• 沸点：
  506.2±43.0 °C(Predicted)
• 密度：
  1.296±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,1-bis[4-carboxyphenyl]ethene 在 乙醇 、 铂 作用下， 生成 1.1-Di-(4-carboxyphenyl)-ethan
  参考文献：
  名称：

  Kariyone; Kawano, Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan, 1951, vol. 71, p. 924

  摘要：

  DOI：
• 作为产物：
  描述：

  2,2-bis-(4-carboxy-phenyl)-propionic acid 在 potassium permanganate 、 硫酸 作用下， 生成 1,1-bis[4-carboxyphenyl]ethene
  参考文献：
  名称：

  Kariyone; Kawano, Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan, 1951, vol. 71, p. 924

  摘要：

  DOI：

文献信息

• Consecutive palladium-catalyzed Hiyama–Heck reactions in aqueous media under ligand-free conditions
  作者：Álvaro Gordillo、Ernesto de Jesús、Carmen López-Mardomingo

  DOI：10.1039/b707583a

  日期：——

  Symmetric and asymmetric (E)-1,2-diarylethenes are synthesized from aryl bromides by consecutive one-pot Hiyama–Heck reactions carried out in water and under air; the only additives required are sodium hydroxide, palladium acetate and poly(ethylene glycol), and the products are isolable in many cases by simple filtration of the water solution.

  通过在水和空气条件下进行的一锅法Hiyama-Heck反应，从芳基溴合成对称和非对称（E）-1,2-二芳基乙烯。唯一所需的添加剂是氢氧化钠、乙酸钯和聚乙二醇，并且在许多情况下，产品可以通过简单地过滤水溶液来分离。
• Process for refining 1,3-dimethyl-2-imidazolidinone and a process for preparing an aromatic polyamide by use of the refined product
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0332425A1

  公开（公告）日：1989-09-13

  A refining process for removing impurities from 1,3-dimethyl-2-imidazolidinone (DMI) employs a composite salt containing MgO and/or SiO₂ composition moieties and the DMI to be refined is brought into contact with the salt at a temperature in the range of 5 - 180°C. A process for preparing an aromatic polyamide having a high polymerization degree from an aromatic diisocyanate and an aromatic dicarboxylic acid by using as a reaction solvent, DMI purified by the above-mentioned process.

  一种从 1,3-二甲基-2-咪唑烷酮（DMI）中去除杂质的精制工艺采用了一种含有 MgO 和/或 SiO₂组成分子的复合盐，并在 5 - 180°C 的温度范围内将待精制的 DMI 与该盐接触。用上述工艺提纯的 DMI 作为反应溶剂，用芳香族二异氰酸酯和芳香族二羧酸制备具有高聚合度的芳香族聚酰胺的工艺。
• DOROFEEV, V. T.;VOLKOV, I. V.;FEDORKOVA, O. P.;SHUGUROVA, L. N., VOPR. XIMII I XIM. TEXNOL., XARKOV, 1985, N 77, 90-93
  作者：DOROFEEV, V. T.、VOLKOV, I. V.、FEDORKOVA, O. P.、SHUGUROVA, L. N.

  DOI：——

  日期：——
• LIQUID CRYSTALLINE POLYESTER COMPOSITION
  申请人：FUKUHARA Yoshiyuki

  公开号：US20120135228A1

  公开（公告）日：2012-05-31

  Disclosed is a liquid crystalline polyester composition which contains a liquid crystalline polyester and mica and which provides a molded article hard to form blisters therein under a high temperature condition, even when it is molded at a high temperature. The liquid crystalline polyester composition is prepared by incorporating the mica and a fluorocarbon polymer whose flow start temperature is 330° C. or lower into the liquid crystalline polyester. The content of the mica in the liquid crystalline polyester composition is preferably from 15 to 100 parts by mass per 100 parts by mass of the liquid crystalline polyester, and the content of the fluorocarbon polymer in the liquid crystalline polyester composition is preferably from 0.2 to 10 parts by mass per 100 parts by mass of the liquid crystalline polyester.
• US4795795A
  申请人：——

  公开号：US4795795A

  公开（公告）日：1989-01-03