5-ethyl-dec-5-ene | 52812-64-3

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 5-ethyl-dec-5-ene
• 英文别名: 5-Aethyl-dec-5-en；5-Ethyl-5-decene；5-ethyldec-5-ene
• CAS: 52812-64-3
• 化学式: C₁₂H₂₄
• 分子量: 168.323
• InChiKey: HWHFFGOWJHTAMX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  5-ethyl-dec-5-ene 、 alkaline earth salt of/the/ methylsulfuric acid 生成 5-ethyldecane
  参考文献：
  名称：

  Ziegler; Grimm; Willer, Justus Liebigs Annalen der Chemie, 1939, vol. 542, p. 113

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 磷酸 作用下， 生成 5-ethyl-dec-5-ene
  参考文献：
  名称：

  Ziegler; Grimm; Willer, Justus Liebigs Annalen der Chemie, 1939, vol. 542, p. 113

  摘要：

  DOI：

文献信息

• Joint cycloalumination of ethylene and other unsaturated compounds with EtAlCl2 in the presence of Cp2ZrCl2. Synthesis of aluminacarbocycles
  作者：A. G. Ibragimov、L. O. Khafizova、L. I. Khusainova、T. V. Tyumkina、U. M. Dzhemilev

  DOI：10.1134/s1070428010040032

  日期：2010.4

  A procedure has been developed for the selective synthesis of five-membered aluminum-containing heterocycles, 2,3-dialkyl-1-ethylaluminacyclopent-2-enes, 3-alkyl-1-ethylaluminacyclopentanes, 2-alkylidene-1-ethylaluminacyclopentanes, and 3-alkyl-1-ethyl-2-methylidenealuminacyclopentanes, via joint cycloalumination of ethylene and other unsaturated compounds (acetylenes, olefins, and allenes) with EtAlCl2 in the presence of Cp2ZrCl2 as catalyst.
• Synthesis of substituted 2,3-dihydro-1H-boroles by transmetalation of aluminacyclopent-2-enes with BF3·Et2O
  作者：L. O. Khafizova、L. I. Khusainova、T. V. Tyumkina、U. M. Dzhemilev

  DOI：10.1134/s1070428012060024

  日期：2012.6

  A procedure was developed for selective synthesis of 4,5-dialkyl-1-fluoro-2,3-dihydro-1H-boroles via transmetalation of the corresponding aluminacyclopent-2-enes with BF3 center dot Et2O. 4,5-Dialkyl-1-fluoro-2,3-dihydro-1H-boroles were isolated as complexes with BEtF2. 4-Alkyl-5-dimethylaminomethyl-1-fluoro-2,3-dihydro-1H-boroles were synthesized for the first time.
• Ziegler; Grimm; Willer, Justus Liebigs Annalen der Chemie, 1939, vol. 542, p. 113
  作者：Ziegler、Grimm、Willer

  DOI：——

  日期：——