1,3,5-Triphenyl-penta-2,4-dienon | 4735-00-6

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物
• 英文名称: 1,3,5-Triphenyl-penta-2,4-dienon
• 英文别名: 1,3,5-triphenylpent-2,4-dien-1-one；1,3,5-Triphenylpenta-2,4-dien-1-one；1,3,5-triphenylpenta-2,4-dien-1-one
• CAS: 4735-00-6
• 化学式: C₂₃H₁₈O
• 分子量: 310.395
• InChiKey: XGFJEMBKDVEEMB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  24
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  碘苯二乙酸 、 2,4,6-triphenylpyranyl 、 异丙醇 生成 碘苯 、 1,3,5-三苯基-3-戊烯-1,5-二酮 、 2,4,6-triphenylpyrylium acetate 、 1,3,5-Triphenyl-penta-2,4-dienon 、 (3,5-diphenyl-2-furyl)(phenyl)methanone 、 溶剂黄146 、 丙酮
  参考文献：
  名称：

  Free radicals: XXVIII. Reaction of 2,4,6-triphenylpyranyl with (diacetoxy-λ3-iodanyl)benzene

  摘要：

  The major product of the reaction of 2,4,6-triphenylpyranyl with (diacetoxy-lambda(3)-iodanyl) benzene in acetonitrile and acetone was 2,4,6-triphenylpyrylium acetate. Analogous reaction in isopropyl alcohol resulted in the formation of methane, carbon dioxide, 1,3,5-triphenylpent-2-ene-1,5-dione, 2-benzoyl-3,5-diphenylfuran, 1,3,5-triphenylpenta-2,4-dien-1-one, and a small amount of 2,4,6-triphenylpyrilium acetate.

  DOI：

  10.1134/s1070428011030201

文献信息

• Free radicals: XXVIII. Reaction of 2,4,6-triphenylpyranyl with (diacetoxy-λ3-iodanyl)benzene
  作者：B. S. Tanaseichuk、M. K. Pryanichnikova、A. A. Burtasov、A. I. Lisina、A. V. Dolganov

  DOI：10.1134/s1070428011030201

  日期：2011.3

  The major product of the reaction of 2,4,6-triphenylpyranyl with (diacetoxy-lambda(3)-iodanyl) benzene in acetonitrile and acetone was 2,4,6-triphenylpyrylium acetate. Analogous reaction in isopropyl alcohol resulted in the formation of methane, carbon dioxide, 1,3,5-triphenylpent-2-ene-1,5-dione, 2-benzoyl-3,5-diphenylfuran, 1,3,5-triphenylpenta-2,4-dien-1-one, and a small amount of 2,4,6-triphenylpyrilium acetate.