三苯基硅烷基叠氮化物 | 5599-34-8

• 物质功能分类: 化学试剂 - 有机试剂 - 硅烷
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 三苯基硅烷基叠氮化物
• 英文名称: triphenylsilyl azide
• 英文别名: Triphenylsilylazid；Azidotriphenylsilan；Triphenyl-azido-silan；azido(triphenyl)silane
• CAS: 5599-34-8
• 化学式: C₁₈H₁₅N₃Si
• 分子量: 301.423
• InChiKey: CUCDHIYTCSBMGZ-UHFFFAOYSA-N

物化性质

• 熔点：
  81 °C
• 沸点：
  100-105 °C(Press: 0.001 Torr)
• 密度：
  1.2 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.96
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  14.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  三苯基硅烷基叠氮化物 在 苯乙酮 作用下， 生成 六苯基环三硅氧烷
  参考文献：
  名称：

  甲硅烷基叠氮化物的热解。不饱和硅氮中间体的产生和反应[R 2 SiNR]

  摘要：

  描述了由相应的甲硅烷基叠氮化物进行热气相生成[R 2 Si = NR]（R = Ph，Me）以及随后的反应中间体与拟态维蒂希（Vittig）方式与醛和酮的反应。反应性中间体也插入（Me 2 SiO）3和（Me 2 SiNMe）2中以形成扩环产物。后面的反应是第一个报道的插入SiNσ键的不饱和硅中间体的例子。

  DOI：

  10.1016/s0022-328x(00)90167-0
• 作为产物：
  描述：

  三苯基氯硅烷 在 sodium azide 作用下， 以 四氢呋喃 为溶剂， 生成 三苯基硅烷基叠氮化物
  参考文献：
  名称：

  一系列甲硅烷基氮烯结构的ESR研究

  摘要：

  通过ESR研究了由叠氮化硅形成的一系列甲硅烷基氮烯的结构。甚至对于分子中具有两个或三个Si–N 3基团的那些，所有甲硅烷基叠氮化物的γ辐照和光照射也会导致形成三重态。甲硅烷基氮烯的ESR光谱在820 mT附近显示出部分精细结构。所有研究过的甲硅烷基叠氮化物都给出了几乎相同的D值（ca. ），并且比苯硝烯中的D值大得多。结果表明，电子自旋在很大程度上位于氮p轨道上，并根据腈–Si–N的单硅烷键来解释，即中断自旋离域。

  DOI：

  10.1016/s0009-2614(01)01112-5

文献信息

• Compound oxidized styrylphosphine
  申请人：——

  公开号：US04168287A1

  公开（公告）日：1979-09-18

  Homopolymers, copolymers and terpolymers of a styrene based monomer are prepared by: (1) polymerizing at least one oxidized styrylphosphine monomer selected from the group of: (C.sub.6 H.sub.5).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2, (c.sub.6 h.sub.5 o).sub.2 p(o)n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2, (c.sub.6 h.sub.5).sub.2 c.sub.3 n.sub.3 n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2 and (C.sub.6 H.sub.5)C.sub.3 N.sub.3 [N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2 ].sub.2 ; or (2) polymerizing p-diphenylphosphinestyrene and then oxidizing said polymerized p-diphenylphosphinestyrene monomer with an organoazide selected from the group of (C.sub.6 H.sub.5).sub.2 P(O)N.sub.3, (C.sub.6 H.sub.5 O).sub.2 P(O)N.sub.3, (C.sub.6 H.sub.5).sub.2 C.sub.3 N.sub.3 (N.sub.3) and C.sub.6 H.sub.5 C.sub.3 N.sub.3 (N.sub.3).sub.2. Copolymers can also be prepared by copolymerizing styrene with at least one oxidized styrylphosphine monomer selected from the group of: (C.sub.6 H.sub.5).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2, (c.sub.6 h.sub.5 o).sub.2 p(o)n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2, (c.sub.6 h.sub.5 ).sub.2 c.sub.3 n.sub.3 n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2 and (C.sub.6 H.sub.5)C.sub.3 N.sub.3 [N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2 ].sub.2

  聚合物、共聚物和三元共聚物是通过以下方法制备的：（1）聚合至少选择自以下组的氧化苯基膦烯单体之一：(C.sub.6 H.sub.5).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2，(c.sub.6 h.sub.5 o).sub.2 p(o)n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2，(c.sub.6 h.sub.5).sub.2 c.sub.3 n.sub.3 n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2和(C.sub.6 H.sub.5)C.sub.3 N.sub.3 [N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2 ].sub.2；或（2）聚合对二苯基膦苯乙烯，然后用选择自以下组的有机叠氮化合物氧化所聚合的对二苯基膦苯乙烯单体：(C.sub.6 H.sub.5).sub.2 P(O)N.sub.3，(C.sub.6 H.sub.5 O).sub.2 P(O)N.sub.3，(C.sub.6 H.sub.5).sub.2 C.sub.3 N.sub.3 (N.sub.3)和C.sub.6 H.sub.5 C.sub.3 N.sub.3 (N.sub.3).sub.2。共聚物也可以通过共聚苯乙烯和至少选择自以下组的氧化苯基膦烯单体之一来制备：(C.sub.6 H.sub.5).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2，(c.sub.6 h.sub.5 o).sub.2 p(o)n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2，(c.sub.6 h.sub.5 ).sub.2 c.sub.3 n.sub.3 n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2和(C.sub.6 H.sub.5)C.sub.3 N.sub.3 [N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2 ].sub.2
• Stable Silaimines with Three- and Four-Coordinate Silicon Atoms
  作者：Prinson P. Samuel、Ramachandran Azhakar、Rajendra S. Ghadwal、Sakya S. Sen、Herbert W. Roesky、Markus Granitzka、Julia Matussek、Regine Herbst-Irmer、Dietmar Stalke

  DOI：10.1021/ic301543y

  日期：2012.10.15

  The reactions of silylenes with organic azides are quite diverse, depending on the substituents of the silylene center and on the nature of the azide employed. Elusive silaimine with three-coordinate silicon atom L1SiN(2,6-Triip2-C6H3) (5) L1 = CH[(C═CH2)(CMe)(2,6-iPr2C6H3N)2] and Triip = 2,4,6-triisopropylphenyl} was synthesized by treatment of the silylene L1Si (1) with a sterically demanding 2

  甲硅烷基与有机叠氮化物的反应非常多样，这取决于甲硅烷基中心的取代基和所用叠氮化物的性质。难以捉摸silaimine具有三个坐标硅原子大号1的SiN（2,6- Triip 2 -C 6 H ^ 3）（5）L 1 = CH [（C = CH 2）（CME）（2,6-我镨2通过用空间上需要的2,6-双（2,4,6-三异丙基苯基）处理甲硅烷基L 1 Si（1），合成了C 6 H 3 N）2 ]和Triip = 2,4,6-三异丙基苯基}叠氮化苯（2,6-Triip 2 C6 H 3 N 3）。Lewis碱稳定的二氯甲硅烷基L 2 SiCl 2（2）L 2 = 1,3-双（2,6- i Pr 2 C 6 H 3）咪唑-2-亚甲基}与Ph 3 SiN 3的反应得到四-配位的硅亚胺L 2（Cl 2）SiNSiPh 3（6）。2,6- Triip的治疗2 ç 6 ħ 3 Ñ 3为L 3的SiCl（3）（L
• Facile Synthesis of Cyclopropene Analogues of Aluminum and an Aluminum Pinacolate, and the Reactivity of LAl[<i>η</i>²-C₂(SiMe₃)₂] toward Unsaturated Molecules (L = HC[(CMe)(NAr)]₂, Ar = 2,6-<i>i-</i>Pr₂C₆H₃)
  作者：Chunming Cui、Sinje Köpke、Regine Herbst-Irmer、Herbert W. Roesky、Mathias Noltemeyer、Hans-Georg Schmidt、Bernd Wrackmeyer

  DOI：10.1021/ja003185i

  日期：2001.9.1

  of LAlI(2) (1) (L = HC[(CMe)(NAr)](2), Ar = 2,6-i-Pr(2)C(6)H(3)) with potassium in the presence of alkynes C(2)(SiMe(3))(2), C(2)Ph(2), and C(2)Ph(SiMe(3)) yielded the first neutral cyclopropene analogues of aluminum LAl[eta(2)-C(2)(SiMe(3))(2)] (3), LAl(eta(2)-C(2)Ph(2)) (4), and LAl[eta(2)-C(2)Ph(SiMe(3))] (5), respectively, whereas reduction of 1 in the presence of Ph(2)CO gave an aluminum pinacolate

  LAlI(2) (1) (L = HC[(CMe)(NAr)](2), Ar = 2,6-i-Pr(2)C(6)H(3))炔烃 C(2)(SiMe(3))(2)、C(2)Ph(2) 和 C(2)Ph(SiMe(3)) 的存在产生了铝 LAl[eta(3) 的第一个中性环丙烯类似物2)-C(2)(SiMe(3))(2)] (3), LAl(eta(2)-C(2)Ph(2)) (4) 和 LAl[eta(2)-C (2)Ph(SiMe(3))] (5)，而在 Ph(2)CO 存在下还原 1 得到频哪酸铝 LAl[O(2)(CPh(2))(2)] (6)，与使用的 Ph(2)CO 量无关。不饱和分子 CO(2)、Ph(2)CO 和 PhCN 插入到 3 的 Al-C 键之一中导致环扩大，得到新型铝五元杂环系统 LAl[OC(O)C(2) (SiMe(3))(2)] (7), LAl[OC(Ph)
• Syntheses and Structural Characterization of a LAl(N₃)N[μ-Si(N₃)(<i>t</i>Bu)]₂NAl(N₃)L and a Monomeric Aluminum Hydride Amide LAlH(NHAr) (L = HC[(CMe)(NAr)]₂, Ar = 2,6-<i>i</i>Pr₂C₆H₃)
  作者：Hongping Zhu、Zhi Yang、Jörg Magull、Herbert W. Roesky、Hans-Georg Schmidt、Mathias Noltemeyer

  DOI：10.1021/om050698v

  日期：2005.12.1

  between the aluminum(I) monomer LAl (L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3) and organic azides (RN3, R = C10H15 (adamantyl), Ph3Si; tBuSi(N3)3) are reported. LAl reacted with the bulky azide RN3 in toluene in a temperature range of −50 to 25 °C, resulting in the compound LAl[(NR)2N2] (R = C10H15 (1), Ph3Si (2)) instead of the expected AlN multiple bond species, while the reaction with tBuSi(N3)3 gave L

  铝（I）单体LAl（L = HC [（CMe）（NAr）] 2，Ar = 2,6- i Pr 2 C 6 H 3）与有机叠氮化物（RN 3，R = C 10 H 15（金刚烷基），Ph 3 Si；t BuSi（N 3）3）被报道。LAl在-50至25°C的温度范围内与块状叠氮化物RN 3在甲苯中反应，生成化合物LAl [（NR）2 N 2 ]（R = C 10 H 15（1），Ph 3 Si（2个））而不是预期的Al N多键物种，而与t BuSi（N 3）3反应得到LAl（N 3）N [（μ-Si（N 3）（t Bu）] 2 NAl（N 3） L（3）。化合物13已被充分表征通过质谱和IR和多核NMR谱（1 H，13 C，和29的Si），以及通过单晶X射线晶体学。的结构分析1和2揭示的AlN 4平面五元环化合物，表明尽管L和R取代基的空间体积较大，Al N多键物种与RN 3分子的[2 + 3]环加成反应。化合物3显示出N
• Heat resistant polymers of oxidized styrylphosphine
  申请人：——

  公开号：US04200721A1

  公开（公告）日：1980-04-29

  Homopolymers, copolymers and terpolymers of a styrene based monomer are prepared by: (1) polymerizing at least one oxidized styrylphosphine monomer selected from the group of: (C.sub.6 H.sub.5).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2, (C.sub.6 H.sub.5 O).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2, (C.sub.6 H.sub.5).sub.2 C.sub.3 N.sub.3 N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2 and (C.sub.6 H.sub.5)C.sub.3 N.sub.3 [N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2 ].sub.2 ; or (2) polymerizing p-diphenylphosphinestyrene and then oxidizing said polymerized p-diphenylphosphinestyrene monomer with an organoazide selected from the group of (C.sub.6 H.sub.5).sub.2 P(O)N.sub.3,(C.sub.6 H.sub.5 O).sub.2 P(O)N.sub.3,(C.sub.6 H.sub.5).sub.2 C.sub.3 N.sub.3 (N.sub.3) and C.sub.6 H.sub.5 C.sub.3 N.sub.3 (N.sub.3).sub.2. Copolymers can also be prepared by copolymerizing styrene with at least one oxidized styrylphosphine monomer selected from the group of: (C.sub.6 H.sub.5).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2, (C.sub.6 H.sub.5 O).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2, (C.sub.6 H.sub.5).sub.2 C.sub.3 N.sub.3 N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2 and (C.sub.6 H.sub.5)C.sub.3 N.sub.3 [N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2 ].sub.2.

  基于苯乙烯单体的同聚物，共聚物和三聚物通过以下方法制备：（1）聚合至少一种氧化的苯乙烯基磷酰胺单体，所选单体来自以下组合：（C.sub.6 H.sub.5).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2，（C.sub.6 H.sub.5 O).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2，（C.sub.6 H.sub.5).sub.2 C.sub.3 N.sub.3 N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2和（C.sub.6 H.sub.5)C.sub.3 N.sub.3 [N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2].sub.2；或（2）聚合对二苯基膦基苯乙烯，然后用有机偶氮化物氧化聚合的对二苯基膦基苯乙烯单体，所选有机偶氮化物来自以下组合：（C.sub.6 H.sub.5).sub.2 P(O)N.sub.3，（C.sub.6 H.sub.5 O).sub.2 P(O)N.sub.3，（C.sub.6 H.sub.5).sub.2 C.sub.3 N.sub.3（N.sub.3）和C.sub.6 H.sub.5C.sub.3 N.sub.3（N.sub.3）.sub.2。共聚物也可以通过与至少一种氧化的苯乙烯基磷酰胺单体共聚合而制备，所选单体来自以下组合：（C.sub.6 H.sub.5).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2，（C.sub.6 H.sub.5 O).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2，（C.sub.6 H.sub.5).sub.2 C.sub.3 N.sub.3 N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2和（C.sub.6 H.sub.5)C.sub.3 N.sub.3 [N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2].sub.2。