3-(七氟异丙氧基)丙基三氯硅烷 | 15538-93-9

• 物质功能分类: 化学试剂 - 硅烷试剂
• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 3-(七氟异丙氧基)丙基三氯硅烷
• 中文别名: 3-八氟异丙氧基丙基三氯硅烷；(3-七氟异丙氧基)丙基三氯硅烷
• 英文名称: (3-heptafluoroisopropoxy)propyltrichlorosilane
• 英文别名: propylheptafluoroisobutylethertrichlorosilane；trichloro{3-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethoxy]propyl}silane；3-(heptafluoroisopropoxy)propyl-trichlorosilane；3-(Heptafluoroisopropoxy)propyltrichlorosilane；trichloro-[3-(1,1,1,2,3,3,3-heptafluoropropan-2-yloxy)propyl]silane
• CAS: 15538-93-9
• 化学式: C₆H₆Cl₃F₇OSi
• mdl: MFCD00045135
• 分子量: 361.546
• InChiKey: GATGUNJRFUIHOM-UHFFFAOYSA-N

物化性质

• 熔点：
  <0°C
• 沸点：
  85 °C
• 密度：
  1.497
• 闪点：
  81°C

计算性质

• 辛醇/水分配系数(LogP)：
  4.64
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  8

安全信息

• TSCA：
  No
• 危险等级：
  8
• 危险品标志：
  C
• 安全说明：
  S26,S27,S36/37/39,S45
• 危险类别码：
  R34
• 危险品运输编号：
  UN 2987
• 海关编码：
  2931900090
• 包装等级：
  II
• 危险类别：
  8

SDS

Name:	(3-(Heptafluoroisopropoxy)propyl)trichloro silane 97% Material Safety Data Sheet
Synonym:	None
CAS:	15538-93-9

Section 1 - Chemical Product MSDS Name:(3-(Heptafluoroisopropoxy)propyl)trichloro silane 97% Material Safety Data Sheet
Synonym:None

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
15538-93-9	(3-(Heptafluoroisopropoxy)propyl)trich	97.0	239-589-6

Hazard Symbols: C
Risk Phrases: 14 34

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Reacts violently with water. Causes burns.Water-reactive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation. Inhalation of vapors causes irritation of the mucous membranes. Causes corrosive action on the mucous membranes.
Chronic:
No information found. Chronic inhalation may cause spasm, inflammation and edema of the larynx and bronchi, chemical pneumonitis, and pulmonary edema.

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Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Antidote: None reported.

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. Use water spray to keep fire-exposed containers cool. Combustible liquid. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. May ignite or explode on contact with steam or moist air. Containers may explode when heated.
Extinguishing Media:
Use dry sand or earth to smother fire. Do NOT use water directly on fire. In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Contact professional fire-fighters immediately.

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Do not expose spill to water.

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Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Do not allow water to get into the container because of violent reaction. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Do not ingest or inhale. Use and store under nitrogen. Do not allow contact with water. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Keep from contact with moist air and steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from water. Corrosives area. Store under nitrogen.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 15538-93-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 39 deg C @ .50mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 81 deg C ( 177.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.4970g/cm3
Molecular Formula: C6H6Cl3F7OSi
Molecular Weight: 361.55

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Combines vigorously or explosively with water.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, water.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen fluoride gas, silicon dioxide.
Hazardous Polymerization: Has not been reported

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 15538-93-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(3-(Heptafluoroisopropoxy)propyl)trichlorosilane - Not listed by ACGIH, IARC, or NTP.

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Section 12 - ECOLOGICAL INFORMATION

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: WATER-REACTIVE LIQUID, CORROSIVE, N.O.S.*
Hazard Class: 4.3 (8)
UN Number: 3129
Packing Group: I
IMO
Shipping Name: WATER-REACTIVE LIQUID, CORROSIVE, N.O.S.
Hazard Class: 4.3 (8)
UN Number: 3129
Packing Group: I
RID/ADR
Shipping Name: WATER-REACTIVE LIQUID, CORROSIVE, N.O.S.
Hazard Class: 4.3 (8)
UN Number: 3129
Packing group: I

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 14 Reacts violently with water.
R 34 Causes burns.
Safety Phrases:
S 8 Keep container dry.
S 25 Avoid contact with eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 27 Take off immediately all contaminated clothing.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 15538-93-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 15538-93-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 15538-93-9 is not listed on the TSCA inventory.
It is for research and development use only.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  hepta(3,3,3-trifluoropropyl)tricycloheptasiloxane trisodium silanolate 、 3-(七氟异丙氧基)丙基三氯硅烷 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 生成 (3-heptafluoroisopropoxy)propylhepta(3,3,3-trifluoropropyl)-T8-silsesquioxane
  参考文献：
  名称：

  部分氟化的多面体低聚倍半硅氧烷的异常大分子组装体†

  摘要：

  氟化多面体低聚倍半硅氧烷（F-POSS）化合物是通过采用简便的角封顶方法制备的。使用这种模块化方法，将具有不同氟含量和结构的碳氟化合物安装在部分冷凝的POSS笼上三硅烷醇。F-POSS衍生物的熔融特性显示出通过分子间堆积组装而受到Si…F接触的各种影响。所有F-POSS化合物的特征在于1 H，13 C，19 F和29 Si NMR光谱，X射线晶体学，热和元素燃烧分析。

  DOI：

  10.1039/c2nj20922e

文献信息

• [EN] FLUORINATED SILYLETHYNYL PENTACENE COMPOUNDS AND COMPOSITIONS AND METHODS OF MAKING AND USING THE SAME<br/>[FR] COMPOSÉS ET COMPOSITIONS DE PENTACÈNE DE SILYLÉTHYNYLE FLUORÉ ET LEURS PROCÉDÉS DE PRÉPARATION ET D'UTILISATION
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2010138807A1

  公开（公告）日：2010-12-02

  Fluorinated silylethynyl pentacenes and compositions containing fluorinated silylethynyl pentacenes are disclosed. Methods of making and using fluorinated silylethynyl pentacenes and compositions containing fluorinated silylethynyl pentacenes are also disclosed.

  本文揭示了氟硅基乙炔基五环戊二烯和含有氟硅基乙炔基五环戊二烯的组合物。还公开了制备和使用氟硅基乙炔基五环戊二烯以及含有氟硅基乙炔基五环戊二烯的组合物的方法。
• [EN] SILYLETHYNYL PENTACENE COMPOUNDS AND COMPOSITIONS AND METHODS OF MAKING AND USING THE SAME<br/>[FR] COMPOSÉS DE SILYLÉTHYNYLE PENTACÈNE ET COMPOSITIONS ET PROCÉDÉS DE PRODUCTION ET D'UTILISATION DE CEUX-CI
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2009155106A1

  公开（公告）日：2009-12-23

  Silylethynyl pentacenes and compositions containing silylethynyl pentacenes are disclosed. Exemplary pentacene compounds have 6, 13 -silylethynyl substitution with one or more groups (e.g., R, R' and R") covalently bonded to each Si atom of the silylethynyl groups. Methods of making and using silylethynyl pentacenes and compositions containing silylethynyl pentacenes are also disclosed. Substrates and devices comprising the silylethynyl pentacenes and compositions are also disclosed.

  揭示了含有硅基乙炔基戊二烯和含有硅基乙炔基戊二烯的组合物。示例戊二烯化合物具有6,13-硅基乙炔基取代物，其中一个或多个基团（例如，R、R'和R"）共价键合到硅基乙炔基的每个Si原子。还公开了制备和使用硅基乙炔基戊二烯和含有硅基乙炔基戊二烯的组合物的方法。还公开了包含硅基乙炔基戊二烯和组合物的基板和器件。
• Facile synthesis of hydrophobic fluoroalkyl functionalized silsesquioxane nanostructures
  作者：Scott T. Iacono、Ashwani Vij、Wade Grabow、Dennis W. Smith, Jr.、Joseph M. Mabry

  DOI：10.1039/b712976a

  日期：——

  New fluorinated polyhedral oligomeric silsesquioxane (F-POSS) structures possessing a high degree of hydrophobicity have been prepared via a facile corner-capping methodology.

  已经通过一种简便的封角方法制备了具有高度疏水性的新型氟化多面体低聚倍半硅氧烷（F-POSS）结构。